Exam 1: Structure and Bonding:acids and Bases

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Instructions: Propose a structure for a molecule that meets the following description. Refer to instructions. Contains only two sp3 hybridized carbons and two sp hybridized carbons.

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CH3CCCH3 or CH3CH2CCH\mathrm { CH } _ { 3 } - \mathrm { C } \equiv \mathrm { C } - \mathrm { CH } _ { 3 } \quad \text { or } \quad \mathrm { CH } _ { 3 } - \mathrm { CH } _ { 2 } - \mathrm { C } \equiv \mathrm { CH }

Draw all the lone pairs (nonbonding valence electrons) on the structure of phosgene, a poisonous gas once used as a chemical warfare agent. Draw all the lone pairs (nonbonding valence electrons) on the structure of phosgene, a poisonous gas once used as a chemical warfare agent.

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Instructions: Consider the reaction below to answer the following question. Instructions: Consider the reaction below to answer the following question.   Refer to instructions. Using the curved arrow formalism, show the flow of electrons for this reaction. Refer to instructions. Using the curved arrow formalism, show the flow of electrons for this reaction.

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Instructions: Indole is pleasant smelling in highly dilute solutions and has been used in perfumery. Use the structure of indole, below, to answer the following question(s). Instructions: Indole is pleasant smelling in highly dilute solutions and has been used in perfumery. Use the structure of indole, below, to answer the following question(s).   Refer to instructions. Indole can function as a Brønsted-Lowry acid in the presence of strong bases. Formulate a reaction, using a generic base (:B<sup>-</sup>), showing electron flow with arrows, that demonstrates this reactivity of indole. Refer to instructions. Indole can function as a Brønsted-Lowry acid in the presence of strong bases. Formulate a reaction, using a generic base (:B-), showing electron flow with arrows, that demonstrates this reactivity of indole.

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Instructions: Write valid Lewis (electron-dot) structures for each formula below. Show all electrons as dots and show all nonbonding electrons. Write: CH3CH2OH ethanol

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Instructions: Determine the hybridization for the indicated atoms in each structure below. Instructions: Determine the hybridization for the indicated atoms in each structure below.     Refer to instructions. The hybridization of carbon atom A is _____. Instructions: Determine the hybridization for the indicated atoms in each structure below.     Refer to instructions. The hybridization of carbon atom A is _____. Refer to instructions. The hybridization of carbon atom A is _____.

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Which of the following best represents the shape of a 2p atomic orbital of carbon? Which of the following best represents the shape of a 2p atomic orbital of carbon?

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Draw a Lewis structure for each of the following.  a) hydroxylammonium ion: +NH3OH\text { a) hydroxylammonium ion: } \mathrm{^+NH}_{3} \mathrm{OH} b) azide ion: ( N3)N_{3^-})

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Instructions: Use the convention d-/d+ and the crossed arrow ( Instructions: Use the convention d-/d+ and the crossed arrow (   ) to show the direction of the expected polarity of the indicated bonds in the following compound(s). Refer to instructions. The C-F bond in fluorobenzene,  ) to show the direction of the expected polarity of the indicated bonds in the following compound(s). Refer to instructions. The C-F bond in fluorobenzene, Instructions: Use the convention d-/d+ and the crossed arrow (   ) to show the direction of the expected polarity of the indicated bonds in the following compound(s). Refer to instructions. The C-F bond in fluorobenzene,

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Consider the formation of an sp2 hybrid orbital. Which of the following is true?

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Use the curved arrow method to show the electron movement, and label the acid, base, conjugate acid, and conjugate base. CH3OH+Na+  CCHCH3ONa++HCCH\mathrm { CH } _ { 3 } \mathrm { OH } + \mathrm { Na } ^ { + }~~{}^{ - }\mathrm { C } \equiv \mathrm { CH } \longrightarrow \mathrm { CH } _ { 3 } \mathrm { O } ^ { - } \mathrm { Na } ^ { + } + \mathrm { HC } \equiv \mathrm { CH }

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Instructions: Refer to the following equation to answer the question(s) below. Instructions: Refer to the following equation to answer the question(s) below.   Refer to instructions. The strongest Brønsted-Lowry acid in the equation is indicated by letter _____. Refer to instructions. The strongest Brønsted-Lowry acid in the equation is indicated by letter _____.

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Instructions: Determine the hybridization for the indicated atoms in each structure below. Instructions: Determine the hybridization for the indicated atoms in each structure below.     Refer to instructions. The hybridization of carbon atom B is _____. Instructions: Determine the hybridization for the indicated atoms in each structure below.     Refer to instructions. The hybridization of carbon atom B is _____. Refer to instructions. The hybridization of carbon atom B is _____.

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The molecular formula C2H4O can be converted into three-line bond (Kekulé) structures that are consistent with valence rules. Which one of the following Kekulé structures is not consistent with valence rules?

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Write an equation for the reaction of boron trifluoride, an important reagent in organic chemistry, with trimethylamine. Represent the movement of electrons with a curved arrow, and show the formal charges on the atoms in the product. Write an equation for the reaction of boron trifluoride, an important reagent in organic chemistry, with trimethylamine. Represent the movement of electrons with a curved arrow, and show the formal charges on the atoms in the product.

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The following shows an intermediate used in a Grignard synthesis. Which atom will inductively donate electrons in this species? The following shows an intermediate used in a Grignard synthesis. Which atom will inductively donate electrons in this species?

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Specify the hybridization of each carbon atom of limonene, a natural product present in citrus fruits, and thujone, which is derived from wormwood, a traditional component of the notorious liquor, Absinthe. Specify the hybridization of each carbon atom of limonene, a natural product present in citrus fruits, and thujone, which is derived from wormwood, a traditional component of the notorious liquor, Absinthe.

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Instructions: Refer to the following equation to answer the question(s) below. Instructions: Refer to the following equation to answer the question(s) below.   Refer to instructions. The strongest Brønsted-Lowry base in the equation is indicated by letter _____. Refer to instructions. The strongest Brønsted-Lowry base in the equation is indicated by letter _____.

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Covalent bonding

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Which of the following statements is not true?

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