Exam 18: Solubility and Complex-Ion Equilibria

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When 100 mL each of 2.0 × 10-6 M Ag+ and 2.0 × 10-3 M Br- are mixed, what is the remaining Ag+ ion concentration and is precipitation complete? The solubility product constant of AgBr is 5.0 × 10-13.

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The solubility of copper(II) iodate Cu(IO3)2 is reported as 0.12 g per 100 mL. What is the solubility product constant for this salt?

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The following table lists five compounds and their Ksp value. Which is least soluble? ZnS 2 × 10-25 TlBr 3.4 × 10-6 AgCl 1.8 × 10-10 FeS 6 × 10-19 CuI 1.1 × 10-12

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Consider an aqueous solution which is 0.020 M in Pb2+ and 0.20 M in Ag+. Concentrated potassium iodide solution (so that volume changes may be neglected) is added gradually with good stirring to this solution. Eventually the iodide ion concentration should increase enough to cause precipitation of the second ion. What will be the concentration of the ion that precipitates first when the second ion just begins to precipitate?

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The solubility product constant of Li3PO4 is 3.2 × 10-9. What is the molar solubility of Li3PO4 in water?

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To a concentrated buffer of pH 9.0 was added an equal volume of a solution that was 0.20 M in each of the ions Ca2+, Cd2+, and Cu2+. The expected precipitate would consist of: salt: calcium hydroxide cadmium hydroxide copper(II) hydroxide Ksp: 4.0 × 10-6   2.0 × 10-14   1.8 × 10-19

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What is the approximate concentration of free Fe3+ ion in a solution prepared by mixing equal volumes of 0.06 M Fe3+ and 4.0 M F- solutions? [The net formation constant for FeF5(H2O)2- is 2.0 × 1015.]

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Write the solubility product constant expression for the following salt: Ca3(PO4)2.

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A saturated solution of magnesium fluoride has a concentration of 1.17 × 10-3 M. For this compound, Ksp =

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To a saturated solution of barium carbonate is added just enough sodium sulfate to achieve a maximum sulfate concentration without precipitation of barium sulfate. If no complexes form and the "salt effect" is negligible, what is the concentration of the sulfate ion in this solution? [Ksp for barium carbonate is 1.6 × 10-9; Ksp for barium sulfate is 7.9 × 10-11]

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Write the solubility product constant expression for the following salt: Na2CO3.

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Qualitative cation analysis has been replaced in recent years by instrumental analysis.

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Equal volumes of 0.020 M Ag+ solution and 2.0 M NH3 solution are mixed. Kf for [Ag(NH3)2]+ is 1.6 × 107. If trisodium arsenate is added so that the arsenate ion concentration is 0.10 M, will silver arsenate precipitate? What is Q? Ksp for silver arsenate is 1.0 × 10-22.

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Write the solubility product constant for KAl(SO4)2(s)?

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Concentrated solutions of copper (I) nitrate, sodium sulfate and silver acetate are mixed together. The precipitate which forms is ________.

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