Exam 17: Additional Aspects of Acid-Base Equilibria

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The buffer capacity of a solution may be defined as the number of moles of H+ that will change the pH of 1.00 L of the buffer by 1.00 pH units. What is the buffer capacity of a solution which is 0.10 M in acetic acid (Ka = 1.8 × 10-5) and 0.30 M in sodium acetate, in units of mol (H+) per liter?

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A

Which of the pH indicators from the list above would be most appropriate for the titration of 0.30 M acetic acid (Ka = 1.8 × 10-5) with 0.15 M sodium hydroxide?

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C

In the titration of a solution of HCN(aq) with NaOH(aq), the equivalence point occurs at a pH greater than 7.

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Why do we avoid titrating ammonia with acetic acid?

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An acid has a Ka = 1 × 10-6. At what pH would this acid and its corresponding salt make a good buffer?

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How will addition of sodium acetate to an acetic acid solution affect the pH?

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Twenty-five milliliters of 0.10 M HCl is titrated with 0.10 M NaOH. What is the pH before any NaOH is added?

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What is the [H3O+] of a solution measured to be 0.20 M in sodium acetate and 0.40 M in acetic acid? [Ka = 1.8 × 10-5]

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How many mL of 0.200 M acetic acid are mixed with 13.2 mL of 0.200 M sodium acetate to give a buffer with pH = 4.2?

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25 mL of 0.10 M acetic acid is titrated with 0.10 M NaOH. What is the pH after 30 ml of NaOH have been added? Ka for acetic acid = 1.8 × 10-5.

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What is the pH of a 1.0 M solution of Na2SO3? Ka1 = 1.3 × 10-2, Ka2 = 6.2 × 10-8 ?

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Which among the following pairs is inefficient as buffer pair?

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For the following titration, determine whether the solution at the equivalence point is acidic, basic or neutral and why: HCl is titrated with NH3(aq)

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Choose the expression that gives the molar concentration of a H2SO4 solution if 24.3 mL of a 0.105 M NaOH solution is required to titrate 60 mL of the acid.

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Acid-base indicators have two forms: an acid of one color and a base of another color.

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Determine the pH of the following solution. Initial concentrations are given. [HC2H3O2] = 0.250 M, [HCl] = 0.120 M [Ka = 1.8 × 10-5]

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Calculate the pH of a 1.00 L solution of 0.100 M NH3(aq) after the addition of 0.010 mol HCl(g). For NH3, pKb = 4.74.

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The pH of a buffer depends mainly on the pKa of the weak acid component of the buffer.

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Phenol red indicator changes from yellow to red in the pH range from 6.6 to 8.0. State what color the indicator will assume in the following solution: 0.1 M NaCl

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The pH of a buffer solution changes only slightly with addition of a small amount of acid or base.

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