Exam 17: Additional Aspects of Acid-Base Equilibria

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A solution has [HC7H5O2] = 0.100 M and [Ca(C7H5O2)2] = 0.200 M. Ka = 6.3 × 10-5 for HC7H5O2. The solution volume is 5.00 L. What is the pH of the solution after 10.00 ml of 5.00 M NaOH is added?

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25 ml of 0.10 M acetic acid is titrated with 0.10 M NaOH. What is the pH before any NaOH is added? Ka for acetic acid = 1.8 × 10-5.

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A weak acid has Ka = 1.00 × 10-3. If [HA] = 1.00 M what must be [A-] for the pH to be 2.7?

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What factor governs the selection of an indicator for a neutralization titration?

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A pH 9.56 buffer was prepared by mixing 2.00 moles of ammonia (Kb for ammonia is 1.8 × 10-5) and 1.00 mol of ammonium chloride in water to form a solution with a volume of 1.00 L. To a 200.0 mL aliquot of this solution was added 10.0 mL of 10.0 M sodium hydroxide. What was the resulting pH?

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A handbook states that to prepare a particular buffer solution mix 39.0 mL of 0.20 M NaH2PO4 with 61.0 mL of 0.20 M Na2HPO4. What will be the pH of this buffer?

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Twenty-five milliliters of 0.10 M HCl is titrated with 0.10 M NaOH. What is the pH after 15 ml of NaOH has been added?

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In the neutralization of 50.0 mL of 0.1 M BOH (a weak base with Kb = 1.6 × 10-7) with 0.10 M H2SO4, the most correct description of the solution at the mid-point of the titration, i.e., half neutralized, is:

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How will addition of sodium chloride affect the pH of a HCl solution?

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Phenol red indicator changes from yellow to red in the pH range from 6.6 to 8.0. State what color the indicator will assume in the following solution: 0.20 M KOH

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Determine the [C2H3O2-] of the following solution. Initial concentrations are given. [HC2H3O2] = 0.250 M, [HI] = 0.120 M [Ka = 1.8 × 10-5]

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A buffer was prepared by adding 2.4 g of ammonium nitrate to 100.0 mL of 0.30 M ammonia (Kb = 1.8 × 10-5). To this solution was then added 10.0 mL of 0.30 M sodium hydroxide, which caused a pH change of ________.

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The Henderson-Hasselbach equation, used to calculate the pH of simple conjugate-pair buffer systems, would be expressed for an ammonia/ammonium chloride buffer, for which Kb(NH3) is 1.8 × 10-5, as:

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The color change range of most acid-base indicators is 1 pH unit.

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If 30.0 mmol HCl(g) is added to 1.00 L of a buffer that is 0.340 M NH3(aq) and 0.290 M NH4Cl(aq), what are the final concentrations of NH3(aq) and NH4Cl(aq), respectively? Assume no volume change.

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What is the pH of a solution prepared by mixing equal volumes of 0.10 M hydrochloric and 0.1 M hydrofluoric acid? [Ka for HF is 6.6 × 10-4]

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Which of the following statements correctly describe a typical titration curve for the titration of a strong acid by a strong base? I. The beginning pH is low. II. The pH change is slow until near the equivalence point. III. At the equivalence point, pH changes by a large value. IV. Beyond the equivalence point, pH rises rapidly. V. The equivalence point would be at a pH less than 3.5.

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The common ion in a mixture of a weak base and a strong base is the hydronium ion.

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Determine the pH of the following solution. Initial concentrations are given. [NH3] = 1.20 M, [KOH] = 0.320 M, Kb (NH3) = 1.8 × 10-5

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