Exam 17: Additional Aspects of Acid-Base Equilibria

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Phenol red indicator changes from yellow to red in the pH range from 6.6 to 8.0. State what color the indicator will assume in the following solution: 0.10 M NH4NO3

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Twenty-five milliliters of 0.10 M HCl is titrated with 0.10 M NaOH. What is the pH at equivalence?

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What is the pH of a 1.0 M solution of Na3AsO4?( Ka1 = 6 × 10-3, Ka2 = 1 × 10-7, Ka3 = 3 × 10-12 )

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What is the pH at the equivalence point for the titration of 0.20 M nitrous acid by 0.20 M sodium hydroxide? [Ka for nitrous acid is 4.5 × 10-4]

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Twenty-five milliliters of 0.10 M HCl is titrated with 0.10 M NaOH. What is the pH when 30 ml of NaOH have been added?

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For an accurate titration, the end point needs to match the equivalence point.

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25 ml of 0.10 M acetic acid is titrated with 0.10 M NaOH. What is the pH at the equivalence point? Ka for acetic acid = 1.8 × 10-5.

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1.80 grams of an impure mixture containing sodium carbonate required 84.0 ml of 0.125 M H2SO4 for complete neutralization. What percent of the mixture is sodium carbonate?

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If some NH4Cl is added to an aqueous solution of NH3:

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What will the pH at the neutralization point of 0.00812 M Ba(OH)2 be when titrated with HCl?

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Determine the pH of the following solution. Initial concentrations are given. [HF] = 1.296 M, [HCl] = 1.045 M, Ka for HF is 6.6 × 10-4

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What is the pH of a 1.0 M solution of trisodium phosphate? Ka1 = 7.1 × 10-3, Ka2 = 6.3 × 10-8, Ka3 = 4.2 × 10-13

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Determine the pH of the following solution. Initial concentrations are given. [NaCHO2] = 0.815 M, [HBr] = 0.105 M, Ka (HCHO2) = 1.8 × 10-4

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Determine the pH of the following solution. Initial concentrations are given. [HC2H3O2] = 0.250 M, [NaC2H3O2] = 0.120 M [Ka = 1.8 × 10-5]

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What volume in ml of 0.05 M NaOH would have to be added to 50.0 ml of 0.10 M H2SO4 in order to affect complete neutralization of the acid?

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For the following titration, determine whether the solution at the equivalence point is acidic, basic, or neutral and why: NaHCO3(aq) titrated with NaOH(aq)

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Choose the correct statement.

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Phenolphthalein may be used as an indicator for the titration of:

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A solution of sodium carbonate is easier to calculate the pH than sodium hydrogen carbonate because there is only one hydrolysis reaction instead of two.

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The titration curve for 10.0 mL of 0.100 M H3PO4(aq) with 0.100 M NaOH(aq) is given below. The titration curve for 10.0 mL of 0.100 M H<sub>3</sub>PO<sub>4</sub>(aq) with 0.100 M NaOH(aq) is given below.   Estimate the pKa<sub>2 </sub>of H<sub>3</sub>PO<sub>4</sub>. Estimate the pKa2 of H3PO4.

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