Exam 11: Solutions: Properties and Behavior

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Use the following data to calculate the lattice energy of lithium chloride, LiCl. Quantity Magnitude (/) Ionization energy of (g) 519 Electron affinity of (g) -349 Vaporization energy of (s) 147 Bond energy of (g) 240 Reaction enthalpy: (s)+(g)\rightarrow(s) -409

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Use the following data to calculate the lattice energy of lithium chloride, LiCl. Quantity Magnitude (/) Ionization energy of (g) 519 Electron affinity of (g) -349 Vaporization energy of (s) 147 Bond energy of (g) 240 Reaction enthalpy: (s)+(g)\rightarrow(s) -409

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A solution of 5.00 g of lithium chloride in 1.00 kg of water has a freezing point of -0.410°C. What is the actual van 't Hoff factor for this salt at this concentration? Kf (water) = 1.86°C/m

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Predict the relationship between the lattice energies (U) of NaCl and MgO.

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Use the following data to calculate the enthalpy change for the following reaction. 2(s)+(g)\rightarrow(s) Quantity Magnitude (/) Ionization energy of () 495 Electron affinity of (g) for 2 603 Vaporization energy of (s) 109 Bond energy of (g) 499 Lattice energy for (s) -2,477

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Which has the higher vapor pressure at a given temperature, pure water or salty seawater? Explain.

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Identify the following statement as true or false and choose the correct explanation. "For solutions with the same reverse osmotic pressure at the same temperature, the molarity of a sodium chloride solution will always be less than the molarity of a calcium chloride solution."

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A solution is prepared by adding 1.50 mol glucose, which is not volatile, to 3.50 mol water. What is the vapor pressure of this solution at 25°C given that the vapor pressure of pure water is 23)8 torr?

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Magnesium chloride is often used to melt ice on sidewalks. Considering that the solubility of magnesium chloride (95.21 g/mol) in water is 54.3 g per 100.0 g of water, what is the lowest temperature that you would expect to be able to melt ice with magnesium chloride? Assume ideal behavior. Kf (water) = 1.86°C/m

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The concentration unit of molality is symbolized as

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Calculate the molality of a solution containing 0.355 mol sodium hydrogen carbonate (baking soda) and 245 g of water.

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Predict the relationship between the lattice energies (U) of KBr and CaO.

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Molecular nitrogen (N2) interacts with water and is sparingly soluble in water due to ________

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Which of the following is a colligative property? I. osmotic pressure II. vapor pressure lowering III. freezing point depression IV. boiling point elevation

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Which arrangement below orders the cations from smallest to largest hydration energy? Smallest to largest means least negative hydration energy to most negative hydration energy.

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A saline solution is administered intravenously to patients who cannot take fluid orally and are in danger of dehydration. The osmotic pressure of this solution must match that of blood to prevent hemolysis or crenation of blood cells. What mass of sodium chloride (58.44 g/mol) is needed to produce 100.0 mL of saline solution with an osmotic pressure of 7.83 atm at a body temperature of 37°C?

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The carbon dioxide pressure in a bottle of champagne is about 6 atm. At this pressure about 0.45 g of carbon dioxide dissolves in 100 mL of champagne. How much carbon dioxide remains dissolved in 100 mL after the bottle is opened? The partial pressure of carbon dioxide then is 6.0 *10-4 atm.

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Which statement about the vapor pressure of a liquid is not correct?

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Air (consisting mostly of nitrogen (N2), oxygen (O2), and argon (Ar)) dissolves in water due to ________

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The freezing point of a 0.060 m solution of magnesium sulfate (MgSO4) is -0.18°C. What is the value of the van 't Hoff factor for this nonideal solution? Kf for water is 1.86°C/m.

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