Exam 16: Reactions Between Acids and Bases
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Consider titrating a triprotic acid with standard NaOH as shown in the titration curve below.
What is the relationship between the first equivalence point and the third equivalence point in this titration curve?

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(Multiple Choice)
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Correct Answer:
C
Which of the following salts, each having very limited solubility in water, would dissolve to a greater extent upon acidifying the solution?
I. Fe(OH)3
II. AgCN
III. PbI2
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(Multiple Choice)
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Correct Answer:
D
What is the pH of a solution that consists of 0.25 M HC2H3O2 and 0.35 M NaC2H3O2?
K a(HC2H3O2) = 1.8×10 - 5
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(Multiple Choice)
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Correct Answer:
C
What is the pH of a solution that is 0.100 M methylamine (CH3NH2) and 0.200 M methyl ammonium chloride (CH3NH3Cl)?
The K b of methylamine is 3.70×10 - 4.
(Multiple Choice)
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Calculate the volume of 0.100 M HCl required to neutralize 1.00 g of Ba(OH)2 (molar mass = 171.3 g/mol).
(Multiple Choice)
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Consider the buffer pair, HF/F - . What can be stated about the relative proportions of this buffer pair if the pH of an aqueous solution of this pair is adjusted tO4.00 and the p K a for HF equals 3.17?
(Multiple Choice)
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A 20.0 mL sample of lactic acid (monoprotic with K a = 1.37×10 - 4) requires 30.0 mL of 0.200 M NaOH for titration to the equivalence point. What is the concentration of the lactic acid solution?
(Multiple Choice)
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A buffer solution maintains a constant pH level to a certain extent when a strong acid such as HCl is added. Which of the following buffer solutions has the greatest buffering capacity to consume added HCl?
(Multiple Choice)
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In the titration of 50.0 mL of a 0.100 M HCl solution with 0.100 M NaOH, what is the pH of the solution after the addition of 20.0 mL of the NaOH solution?
(Multiple Choice)
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Which of the following titration curves listed below best represents a curve for the complete titration of oxalic acid, H2C2O4 (a diprotic acid), with a strong base such as NaOH?
(Multiple Choice)
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Exhibit 16-2 Consider titrating CH3COOH with standard NaOH (delivered from the burette) to answer the following question(s).
-Refer to Exhibit 16-2. What compound(s) is(are) present in the region after the titration has begun but before the equivalence point?
I. CH3COOH
II. NaOH
III. CH3COO - Na+
(Multiple Choice)
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A 350 mL volume of 0.150 M Ba(OH)2 was completely neutralized by 35.0 mL of HCl. What is the molarity of the HCl solution?
(Multiple Choice)
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A buffer is made by dissolving 0.10 mol of NaF in 1.00 L of 0.20 M HF. What is the pH of this buffer?
K a(HF) = 6.3×10 - 4
(Multiple Choice)
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In the titration of 0.100 M HCl with the titrant 0.100 M NaOH, what species are present at any point after NaOH has been added but before the equivalence point?
(Multiple Choice)
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Which of the following titration curves listed below best represents a curve for the complete titration of the weakly basic dianion, sulfide, S2 - , with a strong acid such as HCl as shown below in the net ionic equation?
S2 - (aq) + 2 HCl (aq)→H2S (g) + 2 Cl -
(Multiple Choice)
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Calculate the number of moles of sodium acetate (CH3COONa) that must be added to 1.00 L of 0.100 M CH3COOH ( K a = 1.8×10 - 5) to give a buffer with pH5.00.
(Multiple Choice)
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Calculate the pH of a solution after 10.0 mL of 0.100 M NaOH is added tO40.0 mL of 0.250 M HBr.
(Multiple Choice)
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What is the pH of a buffer solution that consists of 0.25 M HClO2 and 0.75 M KClO2?
K a(HClO2) = 1.1×10 - 2
(Multiple Choice)
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Which pair(s) of substances would make a suitable buffer pair ?
I. HCl and NaCl
II. HF and NaF
III. NH4Cl and NH3
(Multiple Choice)
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What is the pH of a solution prepared by mixing 0.250 mol of hydrazoic acid, HN3, and 0.500 mol of sodium azide, NaN3, to make 1.00 liter of solution?
( K a = 1.9×10 - 5)
(Multiple Choice)
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