Exam 23: Aldehydes and Ketones: Nucleophilic Addition and Α-Substitution Reactions

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For the following reaction, match the given products to the corresponding amines from which they were derived: For the following reaction, match the given products to the corresponding amines from which they were derived:    -Et<sub>2</sub>NH -Et2NH

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B

For the following reaction, match the given products to the corresponding amines from which they were derived: For the following reaction, match the given products to the corresponding amines from which they were derived:    -EtNH<sub>2</sub> -EtNH2

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A

Match the given number of acidic hydrogen atoms to the following molecules A-E: Match the given number of acidic hydrogen atoms to the following molecules A-E:    -Two acidic hydrogen atoms -Two acidic hydrogen atoms

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C

Match the given number of acidic hydrogen atoms to the following molecules A-E: Match the given number of acidic hydrogen atoms to the following molecules A-E:    -One acidic hydrogen atom -One acidic hydrogen atom

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Match the given number of acidic hydrogen atoms to the following molecules A-E: Match the given number of acidic hydrogen atoms to the following molecules A-E:    -No mildly acidic hydrogen atoms -No mildly acidic hydrogen atoms

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From the following sequence of reactions, match the reagents to steps 1-3: From the following sequence of reactions, match the reagents to steps 1-3:    -BuBr + Mg, then HCl/H<sub>2</sub>O -BuBr + Mg, then HCl/H2O

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From the following reactions, A-D, pick out those which lead to the formation of 1-phenylethanol. Please select all that apply. From the following reactions, A-D, pick out those which lead to the formation of 1-phenylethanol. Please select all that apply.

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For the following reaction, pick out the most suitable reagents: For the following reaction, pick out the most suitable reagents:

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For the following reaction, pick out the major product: For the following reaction, pick out the major product:

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Which of the following reagents, A-E, are suitable reagents for the following transformation? Please select all that apply. Which of the following reagents, A-E, are suitable reagents for the following transformation? Please select all that apply.

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Which of the following carbonyl compounds, A-E, forms the least amount of hydrate in water? Which of the following carbonyl compounds, A-E, forms the least amount of hydrate in water?

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Select the major product from the reaction shown. Select the major product from the reaction shown.

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From the following carbonyl-containing molecules, A-E, pick out the one which has the greatest enol content: From the following carbonyl-containing molecules, A-E, pick out the one which has the greatest enol content:

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Select suitable reagents for this reaction. Select suitable reagents for this reaction.

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What is the major product of the following reaction? What is the major product of the following reaction?

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What is the major product of the following reaction? What is the major product of the following reaction?

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Select all of the following carbonyls will form an enolate ion on addition of base. Select all of the following carbonyls will form an enolate ion on addition of base.

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A-C have varying electrophilicities at their carbonyl carbon. Select which will be the most electrophilic. A-C have varying electrophilicities at their carbonyl carbon. Select which will be the most electrophilic.

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For the following reaction, match the given products to the corresponding amines from which they were derived: For the following reaction, match the given products to the corresponding amines from which they were derived:    -Et<sub>3</sub>N -Et3N

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Which of the following enols, A-D, is the most stable? Which of the following enols, A-D, is the most stable?

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