Exam 17: Phase Equilibrium and Solutions

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An ice skater exerts a pressure of 3.1 MPa. Calculate the change in the melting point of the ice under the skate, given that the densities of liquid water and ice are 0.998 and 0.920 g cm-3 respectively and the enthalpy of fusion of water is +6.01 kJ mol-1.

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B

What is the osmotic pressure generated at 25°C by a solution of 1.26 g of sucrose, C12H22O11, in 250 cm3 of water?

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B

Determine the vapour pressure of diethyl ether, C4H10O, at a temperature of 298 K, given that the normal boiling temperature is 308 K and enthalpy of vaporization is 25.9 kJ mol-1.

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D

The vapour pressure of pure benzene is 0.146 bar and of pure toluene is 0.185 bar at 298 K. Determine the mole fraction of toluene in an ideal liquid mixture of benzene and toluene for which the total vapour pressure is 0.160 bar at this temperature.

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The vapour pressure of methanol, CH4O, is 27.5 kPa at 308 K. Determine the normal boiling temperature of ethanol if the enthalpy of vaporization is 37.6 kJ mol-1.

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Trichloromethane, CHCl3, and propanone, C3H6O, form liquid-vapour mixtures with a maximum-boiling azeotrope. What does this imply about the nature of the interactions between the molecules in the mixture?

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The vapour pressure of pure aniline is 1314 Pa at 350 K and 13372 Pa at 400 K. Determine the enthalpy of vaporization of aniline.

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Estimate the increase in the vapour pressure of octane, C8H18, from when the temperature is 298 K to when the temperature is 308 K. The normal boiling temperature is 329 K and enthalpy of vaporization is 31.3 kJ mol-1.

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Determine the mass of sodium chloride, NaCl, that must be added to water to create an aqueous solution of volume 0.50 dm3 with an osmotic pressure of 1.0 atm at 298 K.

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0.10 g of a protein is added to 250 cm3 water at 298 K and the osmotic pressure is measured as 255 Pa. Estimate the relative molecular mass of the protein.

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Determine the vapour pressure of n-hexane, C6H14, at a temperature of 298 K, given that the normal boiling temperature is 342 K and enthalpy of vaporization is 30.9 kJ mol-1.

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The vapour pressure of pure 1-propanol is 2792 Pa at 25°C and 11995 Pa at 50°C. Determine the enthalpy of vaporization of 1-propanol.

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The vapour pressure of pyridine, C5H5N, is 2.25 kPa at 25°C. Determine the normal boiling temperature of pyridine if the enthalpy of vaporization is 40.3 kJ mol-1.

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The Henry's law constant for carbon dioxide dissolved in water at 298 K is 0.163 109 Pa. Determine the mole fraction of carbon dioxide in water in equilibrium with air at a pressure of 1 atm and temperature of 298 K, assuming the proportion of carbon dioxide in dry air is 0.04%.

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0.25 g of a protein is added to 250 cm3 water at 298 K and the osmotic pressure is measured as 320 Pa. Estimate the relative molecular mass of the protein.

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What is the osmotic pressure generated at 25°C by a solution of 2.50 g of glucose, C6H12O6, in 500 cm3 of water at 298 K?

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The Henry's law constant for nitrogen dissolved in water at 298 K is 8.68 109 Pa. Determine the mole fraction of nitrogen in water in equilibrium with air at a pressure of 1 atm and temperature of 298 K.

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Determine the vapour pressure of acetone, C3H6O, at a temperature of 298 K, given that the normal boiling temperature is 329 K and enthalpy of vaporization is 31.3 kJ mol-1.

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Estimate the change in the vapour pressure of -pinene, C10H16, from when the temperature is 323 K to when the temperature is 273 K. The normal boiling temperature is 430 K and enthalpy of vaporization is 45.4 kJ mol-1.

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Determine the mass of potassium chloride, KCl, that must be added to water to create an aqueous solution of volume 25 dm3 with an osmotic pressure of 1.0 bar.

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