Exam 21: The Kinetic Theory of Gases

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The air in an automobile engine at 20°C is compressed from an initial pressure of 1.0 atm and a volume of 200 cm3 to a volume of 20 cm3.Find the temperature if the air behaves like an ideal gas (γ = 1.4)and the compression is adiabatic.

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B

During an adiabatic compression,a volume of air decreases to 1/4 its original size.Calculate its final pressure if its original pressure was 1 atm.(Assume the air behaves like an ideal gas with γ = 1.4. )

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Two tanks of gas,one of hydrogen,H2,and one of helium,He,contain equal numbers of moles of gas.The gram-molecular mass of He is twice that of H2.Both tanks of gas are at the same temperature,293 K.Which statement(s)below is(are)correct when we ignore vibrational motion?

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D

The root mean square speed of a gas molecule is greater than the average speed,because the former gives a greater weight to

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The molar specific heat at constant volume at 0°C of an ideal diatomic gas is

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One mole of helium gas expands adiabatically from 2 atm pressure to 1 atm pressure.If the original temperature of the gas is 20°C,what is the final temperature of the gas? (γ = 1.67)

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Nitrogen gas is heated by a pulsed laser to 50 000 K.If the diameter of the nitrogen atoms is assumed to be 1.0 × 10−10 m,and the pressure is 1.0 atm,what is the mean free path?

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If the rms speed of helium atoms is vrms,He at temperature T,what is the rms speed of CO2 at the same temperature?

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The average kinetic energy of a nitrogen molecule at room temperature (20°C)is

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The theorem of equipartition of energy states that the energy each degree of freedom contributes to each molecule in the system (an ideal gas)is

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The average molecular translational kinetic energy of a molecule in an ideal gas is

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The relation PV = nRT holds for all ideal gases.The additional relation PVγ holds for an adiabatic process.The figure below shows two curves: one is an adiabat and one is an isotherm.Each starts at the same pressure and volume.Which statement is correct? (Note: "∝" means "is proportional to". ) The relation PV = nRT holds for all ideal gases.The additional relation PVγ holds for an adiabatic process.The figure below shows two curves: one is an adiabat and one is an isotherm.Each starts at the same pressure and volume.Which statement is correct? (Note: ∝ means is proportional to. )

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Assume molecules have an average diameter of 3.00 × 10−10 m.How many times larger is the mean free path than the diameter at one atmosphere and 0°C?

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The molar specific heat at constant volume at 0°C of an ideal monatomic gas is

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The molar specific heat at constant pressure at 0°C of an ideal monatomic gas is

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An ideal gas is allowed to expand adiabatically until its volume increases by 50%.By approximately what factor is the pressure reduced? (γ = 5/3. )

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The temperature of a quantity of an ideal gas is

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During the volcanic eruption of Mt.Pelee in 1902,an incredibly hot "burning cloud" rolled down the mountain and incinerated the town of Saint-Pierre.From the damage done,the temperature in the cloud was estimated at 700°C.If the air temperature was 20°C and a mole of air is 29 grams,estimate the molecular weight of the gas in the "burning cloud" that made it heavier than the surrounding air.(As a follow-on,estimate the most probable composition of the cloud.Some typical volcanic gases are H2S,SO2,H2SO4,CO2,NO. )

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If CP for an ideal gas is 35.4 J/mol⋅K,which of the following is CV for this gas?

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A 50-gram sample of dry ice (solid CO2)is placed in a 4-liter container.The system is sealed and allowed to reach room temperature (20°C).By approximately how much does the pressure inside the container increase when the dry ice turns to gas? (Ignore the initial volume of the sample. )

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