Exam 16: Liquids and Solids

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The unit cell in a certain lattice consists of a cube formed by an anion at each corner, an anion in the center, and a cation at the center of each face. The unit cell contains a net

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Mn crystallizes in the same cubic unit cell as Cu. Assuming that the radius of Mn is 5.6% larger than the radius of Cu and that the density of copper is 8.96 g/cm3, calculate the density of Mn.

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Which of the following statements is incorrect?

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A sample consisting of CO2(g) and CO2(s) at equilibrium at -78°C and 1 atm pressure is heated to -30°C, and the pressure is increased to 8 atm. Based on the phase diagram below, what will happen? A sample consisting of CO<sub>2</sub>(g) and CO<sub>2</sub>(s) at equilibrium at -78°C and 1 atm pressure is heated to -30°C, and the pressure is increased to 8 atm. Based on the phase diagram below, what will happen?

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Shown below is a phase diagram for sulfur (not drawn to scale). Sulfur can exist in solid modifications, rhombic and monoclinic, denoted by SR and SM, respectively. Which of the following statements is incorrect? Shown below is a phase diagram for sulfur (not drawn to scale). Sulfur can exist in solid modifications, rhombic and monoclinic, denoted by S<sub>R</sub> and S<sub>M</sub>, respectively. Which of the following statements is incorrect?

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A metal crystallizes in a body-centered unit cell with an edge length of 2.18 102 pm. Assume the atoms in the cell touch along the cube diagonal. What will be the percentage of empty volume in the unit cell?

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If equal, rigid spheres are arranged in a simple cubic lattice in the usual way (that is, in such a way that they touch each other), what fraction of the corresponding solid will be empty space? [The volume of a sphere is (4/3)r3, with = 3.14.]

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A certain substance, X, has a triple-point temperature of 20°C at a pressure of 2.0 atm. Which one of the following statements cannot possibly be true?

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A crystal of NaCl is

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Which of the following compounds has the lowest boiling point?

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Identify the major attractive force in Cl2.

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Which of the following chemical species has the highest boiling point?

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Alkali halides commonly have either the sodium chloride structure or the cesium chloride structure. The molar mass of CsCl is 2.88 times the molar mass of NaCl, and the edge length of the unit cell for NaCl is 1.37 times the edge length of the CsCl unit cell. Determine the ratio of the density of CsCl to the density of NaCl.

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Which intermolecular force is the strongest?

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Consider an ionic compound CxAy where the anions (A) are in a body-centered cubic arrangement and the cations (C) are located in all of the faces of the cubic unit cell. A) What is the empirical formula of the salt? B) If the edge length of the unit cell is 5.00 *10 cm and the molar masses of C and A are 50.0 g/mol and 100.0 g/mol, respectively, calculate the density of CxAy. C) If the ionic radius of A is 200. pm, estimate the ionic radius of C.

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Shown below is a phase diagram for compound X. At 25°C and 1 atm, in what state will X exist? Shown below is a phase diagram for compound X. At 25°C and 1 atm, in what state will X exist?

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Which one of the following is the strongest intermolecular force experienced by noble gases?

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Molecular complexity leads to lower viscosity.

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What is the net number of face-centered atoms contained in a face-centered cubic unit cell?

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The table below lists the ionic radii for the cations and anions in three ionic compounds. The table below lists the ionic radii for the cations and anions in three ionic compounds.   Each compound has a cubic structure like NaCl, CsCl, or ZnS. Using radius ratios, predict the cubic structure that each compound is most likely to form (that of NaCl, CsCl, or ZnS), the type of holes filled by the cations, and the fraction of holes filled by cations. Each compound has a cubic structure like NaCl, CsCl, or ZnS. Using radius ratios, predict the cubic structure that each compound is most likely to form (that of NaCl, CsCl, or ZnS), the type of holes filled by the cations, and the fraction of holes filled by cations.

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