Exam 11: Properties of Solutions Their Concentrations and Colligative Properties

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Determine the molal concentration of a table sugar (C12H22O11, 342.3 g/mol) solution in water that has a freezing point of -2.10 °\degree C.(Kf =1.86 °\degree C/m for water)

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The smell of fresh-cut pine is due in part to a cyclic alkene called pinene.A graph of the natural logarithm of the vapor pressure of pinene vs.1/temperature produces a straight line with a slope of -4936.37 K.What is the enthalpy of vaporization of pinene?

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Drinking seawater is dehydrating to humans because

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Gasoline is primarily a mixture of hydrocarbons and is sold with an octane rating that is based on a comparison with the properties of isooctane (C8H18), which has an enthalpy of vaporization of 35.8 kJ/mol and a normal boiling point of 98.2 °\degree C.Determine the vapor pressure of isooctane on a very hot day when the temperature is 38.0 °\degree C.

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What is the freezing point of an aqueous solution prepared by dissolving 113 g of sodium phosphate (Na3PO4, 163.94 g/mol) in 2.50 kg of water? Use the ideal van 't Hoff factor.(Kf (water) =1.86 °\degree C/m)

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What is the boiling point of a solution prepared by dissolving 10.00 g of naphthalene (C10H8, 128.17 g/mol) in 200.0 g of benzene (C6H6, 78.12 g/mol)? The normal boiling point of benzene is 80.1 °\degree C and Kb =2.53 °\degree C/m.

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Which of the following statements regarding solubility of gases in liquids is NOT correct?

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Does the temperature of the vapors in a still head increase or decrease as a fractional distillation progresses? Explain.

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Water contains about 42 mg of oxygen per liter at 20 °\degree C and 1 atm.What is the Henry's law constant for oxygen dissolving in water?

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A 275 mg sample of a nonelectrolyte compound was dissolved in water to produce 10.0 mL of a solution at 25 °\degree C.The osmotic pressure of this solution was measured and found to be 3.67 atm.What is the molar mass of this compound?

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The arrow in the diagram below indicates the direction of solvent flow through a membrane in osmosis.Which solution, A or B, is more concentrated? Explain your reasoning. The arrow in the diagram below indicates the direction of solvent flow through a membrane in osmosis.Which solution, A or B, is more concentrated? Explain your reasoning.

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Calculate the molality of a solution containing 0.575 mol of ethanol (CH3CH2OH) and 395 g of water.

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A solution contains 6.50 mol of water, 0.300 mol of sucrose, and 0.200 mol of glucose.The solutes are nonvolatile.What is the vapor pressure of the solution at 35 °\degree C given that the vapor pressure of water is 42.2 torr?

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Calculate the minimum pressure that must be applied to achieve reverse osmosis of 0.320 M KBr at 25.0 °\degree C.

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A solution contains two isomers, n-propyl alcohol and isopropyl alcohol, at 25 °\degree C.The total vapor pressure is 38.6 torr.What are the mole fractions of each alcohol in the liquid and in the vapor phase? The vapor pressures are 21.0 torr for n-propyl alcohol and 45.2 torr for isopropyl alcohol.

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The aroma from almonds and cherries is due in part to a compound called benzaldehyde.A graph of the natural logarithm of the vapor pressure of benzaldehyde vs.1/temperature produces a straight line with a slope of -5870.99 K.What is the enthalpy of vaporization of benzaldehyde?

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Which of the following solutions is isotonic with the solution inside a red blood cell, which has an osmotic pressure of 7.89 atm at 37.0 °\degree C?

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Which solution will have the lowest osmotic pressure when measured against pure water?

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How many grams of potassium nitrate (KNO3) must be added to 450.0 g of water to produce a 1.30 m solution?

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Indicate which aqueous solution has the slowest evaporation rate.

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