Exam 11: Properties of Solutions Their Concentrations and Colligative Properties

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The normal temperature range of the liquid phase of pure water is 0 °\degree C to 100 °\degree C.Which of the following solutions will have the largest temperature range for the liquid state?

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What is the molality of a 5.32 M NaCl aqueous solution that has a density of 1.197 g/mL at 20.0 °\degree C?

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A solution is made by dissolving 2.50 * 102 g of essentially nonvolatile ethylene glycol (C2H6O2) in 5.00 *102 g of water.What is the resulting freezing point of the solution? (Kf =1.86 °\degree C/m)

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Thiophene, C4H4S, is a fairly volatile liquid with a vapor pressure of 40.0 torr at 12.5 °\degree C, and its normal boiling point is 84.0 °\degree C.Calculate an estimate of thiophene's enthalpy of vaporization in kJ/mol.

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Which statement regarding osmotic pressure is NOT correct? Osmotic pressure

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Calculate the molality of a solution containing 0.755 mol of glucose (C6H12O6) and 1750 g of water.

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Pyridine, C5H5N, has a normal boiling point of 115.4 °\degree C.If the vapor pressure of pyridine is 40.0 torr at 38.0 °\degree C, calculate the molar enthalpy of vaporization, Δ\Delta Hvap, in kJ/mol at 38.0 °\degree C.

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A solution is prepared by mixing 45.68 g of carbon disulfide (CS2, 76.13 g/mol) with 16.42 g of acetonitrile (CH3CN, 41.06 g/mol).What is the vapor pressure of the solution at 25 °\degree C?  A solution is prepared by mixing 45.68 g of carbon disulfide (CS<sub>2</sub>, 76.13 g/mol) with 16.42 g of acetonitrile (CH<sub>3</sub>CN, 41.06 g/mol).What is the vapor pressure of the solution at 25  \degree C?

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Which statement below regarding evaporation is NOT correct?

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Describe the dynamic equilibrium between evaporation and condensation that is established when a liquid is in a closed container.

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A 75.0 mg sample of a natural product isolated from alfalfa hay was dissolved in water to make 100.0 mL of solution.The solution did not conduct electricity and had an osmotic pressure of 0.246 atm at 27.0 °\degree C.What is the molar mass of this compound?

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A solution is prepared by mixing 45.68 g of carbon disulfide (CS2, 76.13 g/mol) with 16.43 g of acetonitrile (CH3CN, 41.06 g/mol).By what factor is the vapor phase enriched in CS2 at 25 °\degree C?  A solution is prepared by mixing 45.68 g of carbon disulfide (CS<sub>2</sub>, 76.13 g/mol) with 16.43 g of acetonitrile (CH<sub>3</sub>CN, 41.06 g/mol).By what factor is the vapor phase enriched in CS<sub>2</sub> at 25  \degree C?

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A solution is prepared by dissolving 0.330 mol of sodium chloride (NaCl, 58.44 g/mol) in 0.2500 kg of water.How many grams of the solution contain 0.133 mol of NaCl?

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Which of the following would be most effective in melting ice on a sidewalk?

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The molal concentration of ions in seawater is 1.17 m, and the molar concentration is 1.15 M.What is the minimum pressure that must be applied to produce pure water from seawater through reverse osmosis at 25 °\degree C?

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You must mix 168 g of carbon disulfide (CS2, 76.13 g/mol) with acetonitrile (CH3CN, 41.06 g/mol) to create a solution that has a total vapor pressure of 292 torr at 25 °\degree C.Calculate the number of grams of CH3CN required.  You must mix 168 g of carbon disulfide (CS<sub>2</sub>, 76.13 g/mol) with acetonitrile (CH<sub>3</sub>CN, 41.06 g/mol) to create a solution that has a total vapor pressure of 292 torr at 25  \degree C.Calculate the number of grams of CH<sub>3</sub>CN required.

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Water at 25.0 °\degree C exposed to air at 1.00 atm pressure can contain a maximum of 13.7 mg/L of nitrogen gas.Calculate the value of Henry's law constant (mol/L . atm) for nitrogen at this temperature.The mole fraction of nitrogen in air is 0.78084.

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Which of the following pairs of liquids probably exhibits positive deviations from Raoult's law when mixed?

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Which statement below regarding vapor pressure is NOT correct?

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A bottle is half filled with a mixture of 25% liquid heptane and 75% liquid octane by moles at 25 °\degree C.What is the mole ratio of heptane to octane in the space above the liquid compared to in the liquid? The vapor pressures are 31 torr for heptane and 11 torr for octane.

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