Exam 18: Solubility and Simultaneous Equilibria

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NaOH is added to sea water containing 0.050 moles per liter of Mg2+ ion until the pH reaches 12.0. A certain quantity of Mg(OH)2 precipitates. How many parts per billion of magnesium are left behind in the solution? The Ksp of Mg(OH)2 is 7.1 × 10-12.Hint: Find [Mg2+], then convert to ppb.

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Calculate the minimum concentration of Ag+ ion that must be added to (or built up in)a 0.140 M Na2CrO4 solution, in order to initiate a precipitation of silver chromate. The Ksp of Ag2CrO4 is 1.2 × 10-12.Hint: Use an ICE table to help organize your given information and remember to account for the presence of a common ion.

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Addition of a common ion to a solution of a slightly soluble salt will ________ the solubility of the slightly soluble salt.

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200 mL of an aqueous solution contains 0.030 M concentrations of both Pb2+ and Ag+. If 100 mL of 6.0 × 10-2 M NaCl is added to this solution will a precipitate form? If so, what will the precipitate be? The Ksp values for PbCl2 and AgCl are 1.7 × 10-5 and 1.8 × 10-10.Hint: Remember that the solutions are being diluted and use the diluted concentrations.

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What is the solubility, in moles per liter, of AgCl (Ksp = 1.8 × 10-10), in 0.0300 M CaCl2 solution?Hint: Be sure to account for the presence of a common ion and carefully organize. You should also be able to simplify the math because the solubility is very low.

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The oxide ion can exist in aqueous solutions provided the pH is higher than 11.00.

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The solubility of silver phosphate, Ag3PO4, can be expressed in terms of the resulting ion concentrations. Which relationship is correct?

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The solubility product of barium fluoride (BaF2)is 1.7 × 10-6. Calculate the concentration of fluoride ions in a saturated solution of barium fluoride.

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What is the solubility, in moles per liter, of PbSO4 (Ksp = 6.3 × 10-7)in 0.0230 molar MgSO4 solution?Hint: Be sure to account for the presence of a common ion. You should also be able to simplify the math, because the solubility is very low.

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Given the following information Given the following information   What is the equilibrium constant for the reaction below?  What is the equilibrium constant for the reaction below? Given the following information   What is the equilibrium constant for the reaction below?

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A solution contains Ba2+ (1.0 × 10-3 M), Ca2+ (1.0 × 10-3 M)and K+ (1.0 × 10-3 M). Drops of a 5.0 × 10-1 M solution of NaF were added through a microburet until the [F-] in the solution mix reached 1.5 × 10-3 M. Should a precipitate form? If so, what is the precipitate? The Ksp values are BaF2: 1.0 × 10-6, CaF2: 5.3 × 10-9. (Neglect the slight change in volume resulting from the added NaF solution.)

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The solubility of silver carbonate, Ag2CO3, in pure water is 1.27 × 10-4 moles per liter. Calculate the value of Ksp for silver carbonate from this data.

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The Ksp value for barium chromate is 2.1 × 10-10. A 4.16 g sample of BaCl2 and a 5.83 g sample of potassium chromate were added to a 1.000 liter volumetric flask, and distilled water was added to the mark. After placing the stopper and shaking the flask to dissolve as much chemicals as would dissolve, what would be the barium ion concentration remaining in solution afterwards? Be mindful that a precipitate may be formed.Hint: Solving this problem requires comparing Q vs Ksp.

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The solubility of lead iodide is 578 mg L-1 at 25 °C. What is the Ksp for PbI2?

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A precipitate will form when a solution containing a cation and a solution containing an anion are mixed if the ________ exceeds the value of the ________.

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Which one of the following salts has the highest solubility in water, expressed in moles per liter?

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Calculate the concentration of chloride ions in a saturated lead(II)chloride solution. The Ksp = 2.4 × 10-4 for lead(II)chloride.

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The solubility of zinc(II)phosphate, Zn3(PO4)2, in pure water is 1.5 × 10-7 moles per liter. Calculate the value of Ksp for zinc(II)phosphate from this data.

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The formation constant for the tris(ethylenediammine)nickel(II)complex ion, [Ni(en)3]2+, is 4.1 × 1017. What is the concentration of the free nickel(II)ion in a solution in which the equilibrium concentration of free ethylenediammine is 0.400 M, and that of the nickel complex above is 0.0100 M?

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The solubility of calcium oxalate, CaC2O4, in pure water is 4.8 × 10-5 moles per liter. Calculate the value of Ksp for calcium oxalate from this data.

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