Exam 6: Oxidation-Reduction Reactions

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The oxidation number of P in HPO42- is ________.

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Coal is still a large part of the world's energy supply, but not all coal is the same. Some coal deposits contain high amounts of sulfur. Explain how burning coal with high sulfur content, in form of SO2,could be harmful to the environment.

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The sulfur in the coal will form SO2, which can further be oxidized to SO3. In the atmosphere, SO3 reacts with water to form H2SO4 which leads to acid rain. Acid rain has many harmful effects on the environment.

What is the change in the oxidation number of carbon in the following? K2C2O4 \rarr K2CO3

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What is the change in the oxidation number of sulfur in the following? K2SO3 \rarr K2SO4

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When concentrated nitric acid behaves as an oxidizing agent, how does the oxidation number of N change? Hint: An oxidizing agent is reduced.

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Nitric acid reacts with copper metal according to the unbalanced equation, Cu(s)+ HNO3(aq) \rarr Cu(NO3)2(aq)+ NO2(g)+ H2O Which is correct?

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The activity series of metals is Au < Ag < Cu < Sn < Cd < Zn < Al < Mg < Na < Cs Which reaction below occurs spontaneously upon mixing the reagents shown?

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After balancing the following equation for the reaction in acidic media, H+ + HSO3-(aq)+ MnO4-(aq) \rarr MnO2(s)+ HSO4-(aq)+ H2O what is the sum of ALL the coefficients in the equation? (Remember to include values of 1 in your summation.)Hint: Start by balancing each half-reaction.

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Consider the oxidation states of hydrogen in the following compounds: LiH, NaH, KH, MgH2, CaH2, NiH, CuH, ZnH2, HF, HCl, HBr, HI, H2O, H2S, H2Se, and H2Te. What statement is true?

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Ethanol, C2H5OH, is often found in gasoline. In these cases it is often produced from ethanol plants that turn corn into ethanol. The cost-benefit analysis of this process is often a topic of debate. Explain why some ethanol in gasoline could aid in the efficiency of your engine.

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Consider the redox equation, 2VO43-(aq)+ SO2(g)+ 8H+(aq) \rarr 2VO2+(aq)+ SO42-(aq)+ 4H2O(l) The oxidizing agent is

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Magnesium metal reacts with aqueous sulfuric acid solution to produce aqueous magnesium sulfate and hydrogen gas. In the course of the reaction, which element undergoes an increase in oxidation number?

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The activity series of metals is Au < Ag < Cu < Sn < Cd < Zn < Al < Mg < Na < Cs Which reaction below does not occur spontaneously upon mixing the reagents shown?

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The reaction, Cl2(g)+ NaBr(aq) \rarr NaCl(aq)+ Br2(l), involves changes in oxidation number and is therefore classified as a redox reaction.

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It is proposed to measure the CO gas present in air samples by passing the gas through a solution of potassium permanganate. The reaction that occurs is, It is proposed to measure the CO gas present in air samples by passing the gas through a solution of potassium permanganate. The reaction that occurs is,   In a trial run, it required 102 liters of air containing CO (no other substances that would react with permanganate were present)to completely decolorize 250 mL of 0.0150 M MnO<sub>4</sub><sup>-</sup>(aq)solution in a scrubber. If air weighs 1.29 g/liter, what is the percent by weight of CO in the air? Hint: Make sure your equation is balanced and pay attention to your units throughout the problem. In a trial run, it required 102 liters of air containing CO (no other substances that would react with permanganate were present)to completely decolorize 250 mL of 0.0150 M MnO4-(aq)solution in a scrubber. If air weighs 1.29 g/liter, what is the percent by weight of CO in the air? Hint: Make sure your equation is balanced and pay attention to your units throughout the problem.

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What is the oxidation number of sulfur in Rb2S2O4?

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In a chemical reaction, one of the reactants is MnO2. It is transformed into MnSO4. What is the change in the oxidation number of the manganese?

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After balancing the following equation for the reaction in acidic media, Fe2+(aq)+ Cr2O72(aq)+ H+(aq) \rarr Cr3+(aq)+ Fe3+(aq)+ H2O(l)what is the sum of ALL the coefficients in the equation?(Remember to include values of 1 in your summation.)Hint: Start by balancing each half-reaction.

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Fe2+(aq)reacts with MnO4-(aq)ion in acidic solution to yield Fe3+(aq)ions and Mn2+(aq)ions.5Fe2+(aq)+ MnO4-(aq)+ 8H+ \rarr 5 Fe3+(aq)+ Mn2+(aq)+ 4H2O Melanterite is a greenish mineral, and can be found on the walls of mines. A sample of melanterite, FeSO4·7H2O, was analyzed for purity using this reaction by titration of an aqueous solution of the sample. One such sample required 47.35 mL of 0.0175350 M permanganate solution to completely titrate all the iron in the sample by the reaction shown above. How much did the sample weigh, if it was in fact pure melanterite? Hint: Watch your units carefully at each step of the problem.

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Balance the redox reaction below in basic solution.Cl2(g)→ Cl-(aq)+ ClO-(aq)What is the coefficient of OH- in the final balanced equation? Hint: Consider your oxidation numbers when balancing redox reactions.

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