Exam 18: Solubility and Simultaneous Equilibria

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Mercury ions (Hg2+)are very difficult to dissolve in a solution of water, or even a dilute solution of NaOH. But if ammonia is added to the water, mercury ions are more readily soluble. Which of the following best explains why this happens?

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Methylamine, CH3NH2, is a weak molecular base with a value of 4.4 × 10-4 for Kb. An aqueous solution contains 0.200 M CH3NH2 and 0.400 M CH3NH3Cl per liter as the only solutes. If the Ksp of Mg(OH)2 is 7.1 × 10-12, what is the maximum [Mg2+] that can coexist with these solutes in the solution?Hint: Use the Henderson-Hasselbalch formula to find the pOH of the solution, and then use that to find [OH-].

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The solubility of magnesium carbonate, MgCO3, in pure water is 2.6 × 10-4 moles per liter. Calculate the value of Ksp for magnesium carbonate from this data.

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Will a precipitate form when 20.0 mL of 1.8 × 10-3 M Pb(NO3)2 is added to 30.0 mL of5.0 × 10-4 M Na2SO4? The Ksp of (PbSO4)is 6.3 × 10-7.Hint: Find the concentration of each ion in the insoluble compound, and use those to find Q.

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Which of the following is the expression for the solubility product of calcium fluoride, CaF2?

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The solubility of barium carbonate is 14.8 mg L-1 at 30 °C. Calculate the Ksp value for BaCO3.

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200 mL of an aqueous solution contains 0.030 M concentrations of both Pb2+ and Ag+. If 100 mL of 0.20 M NaCl is added to this solution will a precipitate form? If so, what will the precipitate be? The Ksp values for PbCl2 and AgCl are 1.7 × 10-5 and 1.8 × 10-10.Hint: Remember that the solutions are being diluted and use the diluted concentrations.

(Short Answer)
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What is the maximum concentration of Mg2+ ion that can exist in a 0.10 M NaF(aq)solution, without precipitating any magnesium fluoride? The Ksp of MgF2 is 6.6 × 10-9.

(Multiple Choice)
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Given the following information: Given the following information:   What is the equilibrium constant for the reaction below?  What is the equilibrium constant for the reaction below? Given the following information:   What is the equilibrium constant for the reaction below?

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The sulfide ion is too basic to exist as such in aqueous solutions.

(True/False)
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Methylamine, CH3NH2, is a weak molecular base with a value of 4.4 × 10-4 for Kb. An aqueous solution contains 0.200 M CH3NH2 and 0.300 M CH3NH3Cl per liter as the only solutes. If the Ksp of Fe(OH)2 is 7.9 × 10-16, what is the maximum [Fe2+] that can coexist with these solutes in the solution?Hint: Use the Henderson-Hasselbalch formula to find the pOH of the solution, and then use that to find [OH-].

(Multiple Choice)
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The formation constant for the diammine silver(I)ion is 1.6 × 107, while the solubility product constant for silver chloride is 1.8 × 1010. What is the equilibrium constant for the reaction,AgCl(s)+ 2 NH3(aq) The formation constant for the diammine silver(I)ion is 1.6 × 10<sup>7</sup>, while the solubility product constant for silver chloride is 1.8 × 10<sup>10</sup>. What is the equilibrium constant for the reaction,AgCl(s)+ 2 NH<sub>3</sub>(aq)   Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq)+ Cl(aq)? Ag(NH3)2+(aq)+ Cl(aq)?

(Short Answer)
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Metal cations in the chloride solubility group can be separated from other cations because they form ________ chloride compounds in a solution of HCl.

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The solubility product for Ag3PO4 is: Ksp = 2.8 × 10-18. What is the solubility of Ag3PO4 in water, in grams per liter?

(Multiple Choice)
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Even though silver chloride is only very slightly soluble in water, addition of a reagent which forms complex ions with silver ions increases this solubility.

(True/False)
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The Ksp value for barium chromate is 2.1 × 10-10. A 4.16 g sample of BaCl2 and a 5.83 g sample of potassium chromate were added to a 1.000 liter volumetric flask, and distilled water was added to the mark. After placing the stopper and shaking the flask to dissolve as much chemicals as would dissolve, how many grams of precipitate, if any, would be formed?Hint: Solving this problem requires comparing Q vs Ksp.

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The solubility of strontium fluoride, SrF2, can be expressed in terms of the resulting ion concentrations. Which relationship is correct?

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What is the solubility, in moles per liter, of AgCl (Ksp = 1.8 × 10-10), in 0.0100 molar aqueous potassium chloride solution?Hint: Be sure to account for the presence of a common ion. You should also be able to simplify the math because the solubility is very low.

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Which one of the compounds below has the lowest solubility in water, expressed in moles per liter?

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Many metal sulfides have ________ solubilities.

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