Exam 6: Oxidation-Reduction Reactions

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KMnO4 in acidic media is a powerful oxidizing agent, which is often used in redox titrations.

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A solution was made by taking 2.500 g of KMnO4 and dissolving it in enough water to make 1.000 liter of solution. This solution was used to titrate H2C2O4·2H2O, which can be readily obtained in high purity. In acidic media, the reaction is:2 MnO4-(aq)+ 5 H2C2O4(aq)+ 6 H+ → 10 CO2(g)+ 2 Mn2+(aq)+ 8 H2O How many mL of this solution are required to titrate a 0.480 g sample of H2C2O4·2H2O? Hint: Remember to use moles as an intermediary when performing your stoichiometry calculations for the titration.

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What two products are formed when CH4 reacts with a very limited supply of molecular oxygen? Hint: Oxygen must be conserved in the products.

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What is the oxidation number of the arsenic atom in the AsO43 ion?

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Which substance in the reaction 5 H2O(l)+ 4 Cl2(g)+ S2O32-(aq)→ 2 SO42-(aq)+ 8 Cl-(aq)+ 10 H+(aq)is the reducing agent?

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Identify the reducing agent in the chemical reaction Cd + NiO2 + 2H2O → Cd(OH)2 + Ni(OH)2.

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The activity series of metals is Au < Ag < Cu < Sn < Cd < Zn < Al < Mg < Na < Cs Which reaction below occurs spontaneously upon mixing the reagents shown?

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The activity series of metals is Au < Ag < Cu < Sn < Cd < Zn < Al < Mg < Na < Cs Which reaction below does not occur spontaneously upon mixing the reagents shown?

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A partial activity series of metals is: Au < Ag < Cu < Pb < Sn. Which ion is most easily reduced: Au3+, Pb2+, Ag+?

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Which element would react most rapidly with water?

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Three metallic elements, copper, magnesium and gold, can be distinguished from one another on the basis of how they react with two strong acids, HNO3(aq)and HCl(aq). Which set below, using the abbreviations R (for reaction occurs)and NR (no reaction)correctly describes what occurs? Three metallic elements, copper, magnesium and gold, can be distinguished from one another on the basis of how they react with two strong acids, HNO<sub>3</sub>(aq)and HCl(aq). Which set below, using the abbreviations R (for reaction occurs)and NR (no reaction)correctly describes what occurs?

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A partial activity series is: Au < Ag < Cu < H2 < Pb < Sn < Co < Fe. Which metal will be produced when each of the following compounds reacts with Sn metal:Co(NO3)2(aq); Fe(NO3)2(aq); HNO3(aq); Cu(NO3)2(aq); Sn(NO3)2(aq)?

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When organic compounds that contain sulfur undergo complete combustion with oxygen, one of the products is hydrogen sulfide.

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You can dissolve a penny using nitric acid, HNO3. The reaction Cu(s)+ 4 HNO3(aq) \rarr Cu(NO3)2(aq)+ 2 NO2(g)+ 2 H2O(l)is used to dissolve copper metal. If there is 1.000 g of copper to be dissolved, and instructions say to use four times as much acid as the required amount, how many mL (to the nearest mL)of 15.0 M nitric acid would be required to dissolve the copper? Hint: Don't forget the coefficients in the balanced reaction above when performing your calculations with nitric acid.

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Which statement is true concerning an oxidation-reduction reaction?

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The activity series of metals is Au < Ag < Cu < Sn < Cd < Zn < Al < Mg < Na < Cs Based on this list, which element below would undergo oxidation least readily?

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Balancing a redox reaction in acidic media is no different than balancing the same reaction in a basic media.

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The activity series of metals is Au < Ag < Cu < Sn < Cd < Zn < Al < Mg < Na < Cs Based on this list, which element below would undergo oxidation most readily?

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When aluminum is exposed to the environment it does not corrode in the same way as iron. Which of the following best explains why? Hint: Look at the chemical properties of iron and aluminum.

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When a metal is reacted with nitric acid, which element in nitric acid is reduced?

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