Exam 15: Acids and Bases

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What concentration of potassium hydroxide will result from the reaction of 0.170 g of potassium with 100.mL of water?

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4.35 * 10-2 M

Identify the conjugate acid of HCO3- in the reaction HCO3- + HPO42- Identify the conjugate acid of HCO<sub>3</sub><sup>-</sup> in the reaction HCO<sub>3</sub><sup>-</sup> + HPO<sub>4</sub><sup>2-</sup>   H<sub>2</sub>CO<sub>3</sub> + PO<sub>4</sub><sup>3-</sup> H2CO3 + PO43-

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C

What is the H+ ion concentration in a 4.8 * 10-2 M KOH solution?

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E

Acid strength decreases in the series: HCl > HSO4- > HCN. Which of these species is the strongest base?

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Calculate the concentration of chromate ion (CrO42-)in a 0.450 M solution of chromic acid (H2CrO4).[For chromic acid, Ka1 = 0.18, Ka2 = 3.2 * 10-7.]

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The pH of a Ba(OH)2 solution is 10.00. What is the H+ ion concentration of this solution?

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The pH of a 0.6 M solution of a weak acid is 4.0.What percent of the acid has ionized?

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Predict the direction in which the equilibrium will lie for the reaction H3PO4 + NO3- Predict the direction in which the equilibrium will lie for the reaction H<sub>3</sub>PO<sub>4</sub> + NO<sub>3</sub><sup>-</sup>   H<sub>2</sub>PO<sub>4</sub><sup>-</sup> + HNO<sub>3</sub> K<sub>a</sub>(H<sub>3</sub>PO<sub>4</sub>)= 7.5 * 10<sup>-3</sup> H2PO4- + HNO3 Ka(H3PO4)= 7.5 * 10-3

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Arrange the acids HOBr, HBrO3, and HBrO2 in order of increasing acid strength.

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Write the chemical formula for perchloric acid.

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When comparing acid strength of binary acids HX, as X varies within a particular group of the periodic table, which one of these factors dominates in affecting the acid strength?

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The equilibrium constant for the reaction C7H15COOH(aq)+ HCOO-(aq) The equilibrium constant for the reaction C<sub>7</sub>H<sub>15</sub>COOH(aq)+ HCOO<sup>-</sup>(aq)   C<sub>7</sub>H<sub>15</sub>COO<sup>-</sup>(aq)+ HCOOH(aq) Is 7.23 * 10<sup>-2</sup> at 25°C. If K<sub>a</sub> for formic acid (HCOOH)is 1.77 * 10<sup>-4</sup>, what is the acid dissociation constant for C<sub>7</sub>H<sub>15</sub>COOH? C7H15COO-(aq)+ HCOOH(aq) Is 7.23 * 10-2 at 25°C. If Ka for formic acid (HCOOH)is 1.77 * 10-4, what is the acid dissociation constant for C7H15COOH?

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In the reaction HNO3 + NH3 In the reaction HNO<sub>3</sub> + NH<sub>3</sub>   NH<sub>4</sub><sup>+</sup> + NO<sub>3</sub><sup>-</sup>, NH<sub>4</sub><sup>+</sup> and NH<sub>3</sub> are a conjugate acid-base pair. NH4+ + NO3-, NH4+ and NH3 are a conjugate acid-base pair.

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Predict the direction in which the equilibrium will lie for the reaction H3PO4(aq)+ HSO4-(aq) Predict the direction in which the equilibrium will lie for the reaction H<sub>3</sub>PO<sub>4</sub>(aq)+ HSO<sub>4</sub><sup>-</sup>(aq)   <sub> </sub>H<sub>2</sub>PO<sub>4</sub><sup>-</sup>(aq)<sup> </sup>+ H<sub>2</sub>SO<sub>4</sub>(aq). K<sub>a1</sub>(H<sub>3</sub>PO<sub>4</sub>)= 7.5 * 10<sup>-3</sup>; K<sub>a</sub>(H<sub>2</sub>SO<sub>4</sub>)= very large H2PO4-(aq) + H2SO4(aq). Ka1(H3PO4)= 7.5 * 10-3; Ka(H2SO4)= very large

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An unknown substance was added to a solution and the pH decreases. What type of substance was added?

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The OH- concentration in a 2.5 * 10-3 M Ba(OH)2 solution is

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Calculate the concentration of malonate ion (C3H2O42-)in a 0.200 M solution of malonic acid (C3H4O4).[For malonic acid, Ka1 = 1.4 * 10-3, Ka2 = 2.0 * 10-6.]

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If the pH of seawater is 8.0, what is the hydroxide ion concentration in seawater?

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Which one of these equations represents the reaction of a weak acid with a weak base?

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For H3PO4, Ka1 = 7.3 * 10-3, Ka2 = 6.2 * 10-6, and Ka3 = 4.8 * 10-13. An aqueous solution of NaH2PO4 therefore would be

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