Exam 4: Isomers: the Arrangement of Atoms in Space

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A newly isolated natural product was shown to be optically active.If a solution of 2.0 g in 10 mL of ethanol in a 50 cm tube gives a rotation of +2.57°,what is the specific rotation of this natural product?

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+2.57°

How many asymmetric centers are present in the compound shown below? How many asymmetric centers are present in the compound shown below?

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C

What type of isomers are CH3CH2OCH3 and CH3CH2CH2OH?

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A

Is the molecule shown below chiral or achiral? Is the molecule shown below chiral or achiral?

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Which of the following terms best describes the pair of compounds shown: enantiomers,diastereomers,or the same compound? Which of the following terms best describes the pair of compounds shown: enantiomers,diastereomers,or the same compound?

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Label the molecule shown as chiral or achiral. Label the molecule shown as chiral or achiral.

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The compound CH3CHClCH2CH=CHCH2CH3 contains only one asymmetric center.Explain why it has four stereoisomers.

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Is the molecule shown chiral? Is it a meso compound? Is the molecule shown chiral? Is it a meso compound?

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Is the molecule shown chiral? Is it a meso compound? Is the molecule shown chiral? Is it a meso compound?

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Give the complete name(s)of the following compound. Give the complete name(s)of the following compound.

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Twenty grams of a compound was dissolved in 100 mL of solvent and gave an observed rotation of -20 degrees.The sample tube is 4 dm long.Calculate the specific rotation.

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How many asymmetric centers are present in a molecule of 2,4,6-trimethylheptane?

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What is the relationship between the following compounds? What is the relationship between the following compounds?

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Which of the statements below correctly describes an achiral molecule?

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Which of the following groups has the highest priority using the Cahn,Ingold,Prelog rules?

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Label each asymmetrical carbon in the compound below as R or S. Label each asymmetrical carbon in the compound below as R or S.

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Draw the structure of (S)-1-bromo-1-chloropropane.Take particular care to indicate three-dimensional stereochemistry detail properly.

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Structure of pseudoephedrine,a nasal decongestant is shown below.Draw a diastereomer. Structure of pseudoephedrine,a nasal decongestant is shown below.Draw a diastereomer.

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Which of the following compounds has an R configuration?

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What is the relationship between the structures shown below? What is the relationship between the structures shown below?

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