Exam 3: An Introduction to Organic Compounds: Nomenclature, physical Properties, and Structure

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Which of the following is the staggered conformation for rotation about the C1-C2 bond in the following structure? Which of the following is the staggered conformation for rotation about the C<sub>1</sub>-C<sub>2</sub> bond in the following structure?

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A

There are 8 isomers that have the molecular formula C5H11Br.How many of these are tertiary alkyl bromides?

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Provide the systematic name of the compound shown. Provide the systematic name of the compound shown.

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6,7-dimethyl-3-octanol

Provide an acceptable name for the alkane shown below. Provide an acceptable name for the alkane shown below.

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Which of the following will have the lowest boiling point?

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Draw the most stable conformer of cis-1-ethyl-3-methylcyclohexane.

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Draw the Newman projection that represents the least stable conformation of 3,3-dimethylhexane viewed along the C3-C4 bond.

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Which of the following has the greatest van der Waal's interaction between molecules of the same kind?

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How many axial hydrogens are present in this molecule? How many axial hydrogens are present in this molecule?

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Define the term conformation.

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Draw the structure of N-ethyl-5-methyl-3-hexanamine.

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In the boat conformation of cyclohexane,the "flagpole" hydrogens are located on

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Which of the molecules below has the higher boiling point? Briefly explain your choice. CH3CH2CH2OH or CH3CH2OCH3

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Provide an acceptable name for the alkane shown below. CH3CH2CH2CH2CH2CH3

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Which of the following atoms has the highest polarizability?

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Provide an acceptable name for the compound shown below. Provide an acceptable name for the compound shown below.

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Provide the IUPAC name of the compound. Provide the IUPAC name of the compound.

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Explain why the molecule shown below has a lower boiling point than CH3CH2CH2CH3. Explain why the molecule shown below has a lower boiling point than CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub>.

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Arrange the following amines in order of increasing boiling point,lowest bp to highest bp: (CH3)2CHCH2CH2NH2,(CH3)2CHN(CH3)2,and (CH3)2CHCH2NHCH3.

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Draw the most stable conformer of cis-1-isopropyl-2-methylcyclohexane.

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