Exam 27: Synthetic Polymers

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Which of the following polymers can be recycled?

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D

Provide the structure of poly(tetrafluoroethylene).

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What are common factors that enter into the choice of radical initiators for chain-growth polymerization?

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1.A relatively weak bond like the oxygen-oxygen single bond 2.Desired solubility of the initiator 3.Temperature of the polymerization reaction

Identify the product of the following reaction. Identify the product of the following reaction.

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Which of the following polymers is being used in medical applications such as sutures,stents etc.

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Draw the monomer for poly(vinyl acetate).

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What structural characteristic is shared by compounds used as radical initiators?

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Provide a mechanism to show how H2C Provide a mechanism to show how H<sub>2</sub>C   C(CH<sub>3</sub>)<sub>2</sub> is polymerized using BF<sub>3</sub> as the initiator. C(CH3)2 is polymerized using BF3 as the initiator.

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List the two main groups of polymers and give one example of each.

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Identify the monomer(s)that undergo radical polymerization.You may choose more than one answer.

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Explain why some monomers are better able to undergo chain-growth polymerization by a radical mechanism.

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Identify the initiator in an anionic polymerization.

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What is the main structural difference between high-density and low-density polyethylene,and how does this structural difference affect the properties and uses of these polymers?

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Identify the initiator in a radical polymerization.

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Provide the structure of the monomer from which Orlon [poly(acrylonitrile)] is prepared.

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Which of the following are characteristics of thermosetting polymers?

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Which of the following polymers is used in bullet-proof vests?

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Identify the monomer(s)that undergo anionic polymerization.You may choose more than one answer.

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The pattern below is found in what type of polymer? AABBBABAABABBAAB

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What is the mass of each repeating unit in poly(ethylene)?

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