Exam 15: Reactions of Carboxylic Acids and Carboxylic Acid Derivatives

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Draw the resonance contributors of the following two molecules.Indicate which molecule has more stable resonance structure and explain why?

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Question 1

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The resonance contributor of the amide is more stable than ester because nitrogen is less electronegative than oxygen and thus,can better accommodate the positive charge.

Give the name of the structure.

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Question 2

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What is the hybridization and geometry of the carbonyl carbon in carboxylic acids and their derivatives?

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Question 3

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Provide the major organic product of the reaction below.

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Question 4

Provide the IUPAC name for the organic compound below.

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Question 5

What is the major organic product of the following reaction?

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Question 6

What is the main intramolecular force between two molecules of acetonitrile?

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Question 7

Give the name of the structure.

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Question 8

Provide the major organic product of the following.

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Question 9

Provide the systematic name of the compound shown below.

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Question 10

Which of the following is formed in the reaction between ethyl butanoate and ethyl amine?

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Question 11

Provide a detailed,stepwise mechanism for the reaction of butyrolactone with ammonia.

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Question 12

What is the common name for the following compound?

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Question 13

Which of the following compounds is D-valerolactam?

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Question 14

Give the product of the reaction.

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Question 15

What is the major product of the following reaction?

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Question 16

The best leaving group must be a

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Question 17

Provide the IUPAC name for the organic compound below.

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Question 18

What is the common name for the following compound?

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Question 19

Which of the following is the best method for preparing aspirin?

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Question 20

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Exam 15: Reactions of Carboxylic Acids and Carboxylic Acid Derivatives

Draw the resonance contributors of the following two molecules.Indicate which molecule has more stable resonance structure and explain why?

Give the name of the structure.

What is the hybridization and geometry of the carbonyl carbon in carboxylic acids and their derivatives?

Provide the major organic product of the reaction below.

Provide the IUPAC name for the organic compound below.

What is the major organic product of the following reaction?

What is the main intramolecular force between two molecules of acetonitrile?

Give the name of the structure.

Provide the major organic product of the following.

Provide the systematic name of the compound shown below.

Which of the following is formed in the reaction between ethyl butanoate and ethyl amine?

Provide a detailed,stepwise mechanism for the reaction of butyrolactone with ammonia.

What is the common name for the following compound?

Which of the following compounds is D-valerolactam?

Give the product of the reaction.

What is the major product of the following reaction?

The best leaving group must be a

Provide the IUPAC name for the organic compound below.

What is the common name for the following compound?

Which of the following is the best method for preparing aspirin?

Remembering General Chemistry: Electronic Structure and Bonding

Acids and Bases: Central to Understanding Organic Chemistry

An Introduction to Organic Compounds: Nomenclature, physical Properties, and Structure

Isomers: the Arrangement of Atoms in Space

Alkenes: Structure,nomenclature,and an Introduction to Reactivity - Thermodynamics and Kinetics

The Reactions of Alkenes - the Stereochemistry of Addition Reactions

The Reactions of Alkynes - Introduction to Multistep Synthesis

Delocalized Electrons: Their Effect on Stability, pka, and the Products of a Reaction - Aromaticity and Electronic Effects: an Introduction to the Reactions of Benzene

Substitution and Elimination Reactions of Alkyl Halides

Reactions of Alcohols, ethers, epoxides, amines and Sulfur-Containing Compounds

Organometallic Compounds

Radicals

Mass Spectrometry,infrared Spectroscopy,and Uvvis Spectroscopy

Nmr Spectroscopy

Reactions of Aldehydes and Ketones

Reactions at the Α-Carbon

Reactions of Benzene and Substituted Benzenes

More About Amines - Reactions of Heterocylic Compounds

The Organic Chemistry of Carbohydrates

Amino Acids,peptides,and Proteins

Catalysis in Organic Reactions and in Enzymatic Reactions

The Organic Chemistry of the Coenzymes, compounds Derived From Vitamins

The Organic Chemistry of the Metabolic Pathways

The Organic Chemistry of Lipids

The Chemistry of the Nucleic Acids

Synthetic Polymers

Pericyclic Reactions

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