Exam 21: Transition Metals and Coordination Chemistry
Exam 1: Chemical Foundations96 Questions
Exam 2: Atoms, molecules, and Ions91 Questions
Exam 3: Stoichiometry134 Questions
Exam 4: Chemical Reactions and Solutions Stoichiometry117 Questions
Exam 5: Gases132 Questions
Exam 6: Thermochemistry86 Questions
Exam 7: Atomic Structure and Periodicity149 Questions
Exam 8: Bonding: General Concepts146 Questions
Exam 9: Covalent Bonding: Orbitals101 Questions
Exam 10: Liquids and Solids126 Questions
Exam 11: Properties of Solutions108 Questions
Exam 12: Chemical Kinetics113 Questions
Exam 13: Chemical Equilibrium87 Questions
Exam 14: Acids and Bases149 Questions
Exam 15: Acid-Base Equilibria94 Questions
Exam 16: Solubility and Complex Ion Equilibria93 Questions
Exam 17: Spontaneity, entropy, and Free Energy117 Questions
Exam 18: Electrochemistry138 Questions
Exam 19: The Nucleus: a Chemists View83 Questions
Exam 20: The Representative Elements154 Questions
Exam 21: Transition Metals and Coordination Chemistry142 Questions
Exam 22: Organic and Biological Molecules164 Questions
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How many of the following compounds exhibit geometric isomers?
I.Pt(NH3)2Cl2 (square planar)
II.[Co(H2O)2]Cl3
III.Ni(NH3)4(NO2)2
IV.K2[CoCl4]
(Multiple Choice)
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Which of the following is true about coordination complexes?
(Multiple Choice)
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The 3d electrons in Co(NH3)63+ are all paired but Fe(H2O)63+ has unpaired electrons (is paramagnetic).Explain.
(Essay)
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In the crystal field model,ligands are treated as negative point charges.
(True/False)
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Here are some crystal field representations of d electrons in an octahedral complex:
I)
II)
III)
IV)
V)
Choose the representation that fits the transition metal atom in the following species:
-Fe(OH2)63+ (assume weak field)





(Multiple Choice)
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The empirical formula of a compound with a mass percent composition of 6.78% H,31.43% N,39.76% Cl,and 22.03% Co is consistent with which of the following complexes?
(Multiple Choice)
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Which of the transition metals is the best conductor of heat and electric current?
(Multiple Choice)
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A coordination compound of Cu2+ can be described as Cu(NH3)xSO4 and is known to contain 29.92% NH3 by mass.The value of x is:
(Multiple Choice)
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The metals with the highest ionization energies are most likely to be found in nature in the elemental state.
(True/False)
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In which of the following complexes does the transition metal have a d8 configuration?
(Multiple Choice)
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For the process Co(NH3)5Cl2+ + Cl- Co(NH3)4Cl2+ + NH3 what would be the ratio of cis to trans isomer in the product?
(Multiple Choice)
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Oxygen is stored in mammalian tissue in which type of molecule?
(Multiple Choice)
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How many unpaired electrons are found in each of the following complex ions?
-[Cr(CN)4]2-
(Short Answer)
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