Exam 21: Transition Metals and Coordination Chemistry

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How many of the following compounds exhibit geometric isomers? I.Pt(NH3)2Cl2 (square planar) II.[Co(H2O)2]Cl3 III.Ni(NH3)4(NO2)2 IV.K2[CoCl4]

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What is the correct IUPAC name for [AuCl4(H2O)2]-?

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Which of the following is true about coordination complexes?

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The 3d electrons in Co(NH3)63+ are all paired but Fe(H2O)63+ has unpaired electrons (is paramagnetic).Explain.

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The complexes of Zn2+ are all diamagnetic.

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In the crystal field model,ligands are treated as negative point charges.

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Ni(NH3) 62+

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What is the formula for the hexaaquachromium(II)ion?

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Here are some crystal field representations of d electrons in an octahedral complex: I) Here are some crystal field representations of d electrons in an octahedral complex: I)   II)   III)   IV)   V)   Choose the representation that fits the transition metal atom in the following species: -Fe(OH<sub>2</sub>)<sub>6</sub><sup>3+</sup> (assume weak field) II) Here are some crystal field representations of d electrons in an octahedral complex: I)   II)   III)   IV)   V)   Choose the representation that fits the transition metal atom in the following species: -Fe(OH<sub>2</sub>)<sub>6</sub><sup>3+</sup> (assume weak field) III) Here are some crystal field representations of d electrons in an octahedral complex: I)   II)   III)   IV)   V)   Choose the representation that fits the transition metal atom in the following species: -Fe(OH<sub>2</sub>)<sub>6</sub><sup>3+</sup> (assume weak field) IV) Here are some crystal field representations of d electrons in an octahedral complex: I)   II)   III)   IV)   V)   Choose the representation that fits the transition metal atom in the following species: -Fe(OH<sub>2</sub>)<sub>6</sub><sup>3+</sup> (assume weak field) V) Here are some crystal field representations of d electrons in an octahedral complex: I)   II)   III)   IV)   V)   Choose the representation that fits the transition metal atom in the following species: -Fe(OH<sub>2</sub>)<sub>6</sub><sup>3+</sup> (assume weak field) Choose the representation that fits the transition metal atom in the following species: -Fe(OH2)63+ (assume weak field)

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The empirical formula of a compound with a mass percent composition of 6.78% H,31.43% N,39.76% Cl,and 22.03% Co is consistent with which of the following complexes?

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Which of the following is a d7 ion?

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Which of the transition metals is the best conductor of heat and electric current?

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Which of the following is paramagnetic?

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A coordination compound of Cu2+ can be described as Cu(NH3)xSO4 and is known to contain 29.92% NH3 by mass.The value of x is:

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The metals with the highest ionization energies are most likely to be found in nature in the elemental state.

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In which of the following complexes does the transition metal have a d8 configuration?

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Which of the following ligands might give linkage isomers?

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For the process Co(NH3)5Cl2+ + Cl- \to Co(NH3)4Cl2+ + NH3 what would be the ratio of cis to trans isomer in the product?

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Oxygen is stored in mammalian tissue in which type of molecule?

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How many unpaired electrons are found in each of the following complex ions? -[Cr(CN)4]2-

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