Exam 9: Molecular Geometry: Shape Determines Function

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For which one of the following molecules (BF3, CF4, NF3, OF2, XeF4) is the electron geometry tetrahedral and the molecular geometry triangular pyramidal? Draw its Lewis structure with the correct bond angles.

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  In the diagram each F has 3 pairs of nonbonding electrons. In the diagram each F has 3 pairs of nonbonding electrons.

Which of the following diagrams shows the correct orientation of the dipole in sulfur dioxide?

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A

Which of the following compounds has a trigonal bipyramidal shape?

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C

Light-emitting diodes are semiconductors that emit light when a current is passed through them. What is the key factor that must be changed to change the wavelength of the emitted light in an LED?

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According to the molecular orbital energy-level diagram below, which one of the following statements is not correct about NO, NO, and NO? These molecular orbitals are formed from the 2s and 2p atomic orbitals. According to the molecular orbital energy-level diagram below, which one of the following statements is not correct about NO, NO<font face=symbol><sup></sup></font>, and NO<font face=symbol><sup></sup></font>? These molecular orbitals are formed from the 2s and 2p atomic orbitals.

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Use the following molecular orbital diagram for the valence orbitals of carbon monoxide, predict the bond order of the following molecules. CO, CO2, CO2 Use the following molecular orbital diagram for the valence orbitals of carbon monoxide, predict the bond order of the following molecules. CO, CO<sup>2</sup><font face=symbol><sup></sup></font>, CO<sup>2</sup><font face=symbol><sup></sup></font>

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Which of the following molecules or ions has a trigonal pyramid shape?

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Which of the following diagrams shows the correct orientation of the dipole in sulfur tetrafluoride?

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For the molecule CH3CHCHCH3, the local molecular geometry around a carbon atom at the end and its hybridization are ________

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Which type of molecular orbital has maximum electron density above and below the internuclear axis but zero density in a plane perpendicular to the internuclear axis?

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What hybridization is needed to describe the square planar molecular geometry of KrF4?

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In the following reaction, what is the change in geometry of the silicon-containing compound? SiH4(g) 2O2(g) H2SiO(g) 2H(g)

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The amide group is an important structural unit in proteins. The simplest amide is formamide, HCONH2. In a valence bond picture of the C-N bond, ________ hybrid orbitals of C overlap with ________ hybrid orbitals of N.

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Which statement about VSEPR theory is not correct?

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Which one of the following molecules has a bond order of 3?

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What is the molecular geometry of XeF2?

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Which bond is the most polar?

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Which of the following molecules is paramagnetic?

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Metal solids are good conductors of electricity because ________

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Which statement regarding a bond between two carbon atoms is correct?

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