Exam 43: Molecules and Solids

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Assume a diatomic molecule can be considered to be two point masses separated by a distance r. The center of mass of the system is located a distance x from m1, equal to

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B

The energy gap for a semiconductor is 1.25 eV. Of the frequencies given below, what is the minimum frequency photon than can move an electron from the valence band to the conduction band?

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B

The energy gap for germanium is 0.670 eV at room temperature. What wavelength must a photon have (in nm) to excite the electron to the conduction band?

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C

What is the energy of the first rotational state of the hydrogen (H2) molecule? The separation between the protons is 10−10 m and the mass of each proton is 1.67 × 10−27 kg. (h = 6.626 × 10−34 J ⋅ s and 1 eV = 1.6 × 10−19 J.)

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An experiment determines that there are 49 allowed rotational energies for a diatomic molecule whose moment of inertia is 2 × 10−46 kg ⋅ m2. The maximum rotational kinetic energy (in eV) is

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The rotational kinetic energy of a diatomic molecule can take the form

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A diatomic molecule consists of two point masses, m1 and m2, separated by a distance r. If x is the distance from m1 to the center of mass, find the moment of inertia in terms of x about an axis perpendicular to the molecular axis through the center of mass.

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The rotation spectrum of the HCl molecule suggests a photon in the far infrared (around 5.0 × 10−6 m) can excite the first rotational level. From this data, the moment of inertia of the HCl molecule (in kg ⋅ m2) is

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The moment of inertia of a CO molecule is 1.46 × 10−46 kg ⋅ m2. What is the wavelength of the photon emitted if a rotational transition occurs from the J = 3 to the J = 2 state?

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Assume the angular momentum of a diatomic molecule is quantized according to the relation Assume the angular momentum of a diatomic molecule is quantized according to the relation   . What are the allowed rotational kinetic energies? . What are the allowed rotational kinetic energies?

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In the hydrogen molecule, H2, the separation between the protons is 10−10 m. If the molecule is in its first rotational energy state, what is the angular velocity of the molecule about its center of mass?

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If an electric field is applied to a metal

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An energy band in a solid consists of

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A diatomic molecule consists of two point masses, m1 and m2, separated by a distance r. Find the moment of inertia through the center of mass about an axis perpendicular to the molecular axis.

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The force constant of HCl is 480 N/m. If the atomic masses are 1 u and 35 u (1 u = 1.66 × 10−27 kg), find the fundamental frequency (in Hz).

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A molecule makes a transition from the J = 1 to the J = 0 rotational energy state. The wavelength of the emitted photon is 2.6 × 10−3 m. What is the moment of inertia of the molecule (in kg ⋅ m2)?

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When calculating the rotational kinetic energy of a diatomic molecule, with atoms of mass m1 and m2,the moment of inertia about an axis passing through the molecule's center of mass, with r the atomic separation, is

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When a molecule jumps from a rotational energy level characterized by the rotational quantum number J to one characterized by J − 1, the difference in energy of levels J and J − 1, EJ − EJ 1, is

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The Fermi temperature is

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A diatomic molecule consists of two point masses, m1 and m2, separated by a distance r. If x is the distance from m1 to the center of mass, find the moment of inertia in terms of x about an axis parallel to the molecular axis through the center of mass.

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