Exam 14: Solutions and Their Behavior

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According to the National Institute of Standards webbook,the Henry's Law constant for N2 gas is 0.00060 mol/kg.bar at 25 \circ C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)

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Which of the following solutions would have the highest osmotic pressure?

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The vapor pressure of water at 90°C is 0.692 atm.What is the vapor pressure (in atm)of a solution made by dissolving 1.28 mole(s)of CsF(s)in 1.00 kg of water? Assume that Raoult's law applies.

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Henry's Law constant is 0.034 mol/kg.bar and 0.0013 mol/kg.bar for CO2 and O2 respectively at 25 \circ C.What pressure of O2 is required to achieve the same solubility as 0.218 bar of CO2?

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________ are colloidal dispersions of one liquid in another liquid.

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The Henry's law constant for O2 in water at 25 \circ C is 1.3 ×\times 10-3 mol/kg.bar.What partial pressure of O2 (in atm)is necessary to achieve an equilibrium concentration of 2.9 ×\times 10-3 mol/kg O2? (1 atm = 0.9869 bar)

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Two nonpolar solvents,such as hexane and carbon tetrachloride,may be miscible even though the enthalpy of mixing of these liquids might be small.A reason that mixing occurs is that mixtures have a greater dispersal of energy relative to pure solvents.The tendency toward greater dispersal of energy is a thermodynamic function called ____.

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Assuming ideal behavior,which of the following aqueous solutions should have the highest boiling point?

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What mass of ethylene glycol,when mixed with 225 g H2O,will reduce the equilibrium vapor pressure of H2O from 1.00 atm to 0.800 atm at 100 \circ C? The molar masses of water and ethylene glycol are 18.02 g/mol and 62.07 g/mol,respectively.Assume ideal behavior for the solution.

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The change in energy accompanying the process below is the ____ of MX. MX(s) \to M+(aq)+ X-(aq)

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What is the vapor pressure at 20°C of an ideal solution prepared by the addition of 4.60 g of the nonvolatile solute urea,CO(NH2)2,to 50.2 g of methanol,CH3OH? The vapor pressure of pure methanol at 20°C is 89.0 mmHg.

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If the concentration of sodium carbonate in water is 12.8 ppm,what is the molarity of Na2CO3(aq)? The molar mass of Na2CO3 is 106.0 g/mol.Assume the density of the solution is 1.00 g/mL.

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If 27.9 g LiCl is dissolved in 175 g H2O,what is the weight percent of LiCl in the solution?

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For the following gas-liquid equilibrium for an aqueous system at a constant partial pressure of O2, O2(g) \leftrightarrows O2(aq) What is the effect on the equilibrium composition of the liquid when the  temperature \underline{\text{ temperature }} of the liquid is decreased?

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What type of colloid is formed when a solid is dispersed in a liquid?

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At 37°C,what is the osmotic pressure of a 0.59% NaCl by weight aqueous solution? Assume the density of the solution is 1.0 g/mL.Assume no ion pairing.(R = 0.0821 L · atm/K·mol)

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Which of the following liquids will be miscible with water in any proportion: ethanol (CH3CH2OH),carbon tetrachloride (CCl4),hexane (C6H14),and/or formic acid (HCO2H)?

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Which of the following statements about soaps and detergents is  false? \underline{\text{ false? }}

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Concentrated sodium hydroxide is 19.4 M and has a density of 1.54 g/mL.What is the molality of concentrated NaOH?

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Ideally,colligative properties depend only on the

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