Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions

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Which of the following processes is/are endothermic? 1)the combustion of hydrogen 2)the condensation of water 3)the evaporation of isopropyl alcohol

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C

Which one of the following statements is INCORRECT?

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B

A chemical reaction in a bomb calorimeter evolves 3.86 kJ of energy in the form of heat.If the temperature of the bomb calorimeter increases by 4.17 K,what is the heat capacity of the calorimeter?

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C

One statement of the first law of thermodynamics is that

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Why are you at greater risk from being burned by steam at 100 \circ C than from liquid water at the same temperature?

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When 1 mole of Fe2O3(s)reacts with H2(g)to form Fe(s)and H2O(g)according to the following equation,98.8 kJ of energy are absorbed. Fe2O3(s)+ 3 H2(g) \to 2 Fe(s)+ 3 H2O(g) (A)  When 1 mole of Fe<sub>2</sub>O<sub>3</sub>(s)reacts with H<sub>2</sub>(g)to form Fe(s)and H<sub>2</sub>O(g)according to the following equation,98.8 kJ of energy are absorbed.  Fe<sub>2</sub>O<sub>3</sub>(s)+ 3 H<sub>2</sub>(g) \to  2 Fe(s)+ 3 H<sub>2</sub>O(g)  (A)    (B)   Is the reaction endothermic or exothermic,and which of the enthalpy diagrams above Represents this reaction? (B)  When 1 mole of Fe<sub>2</sub>O<sub>3</sub>(s)reacts with H<sub>2</sub>(g)to form Fe(s)and H<sub>2</sub>O(g)according to the following equation,98.8 kJ of energy are absorbed.  Fe<sub>2</sub>O<sub>3</sub>(s)+ 3 H<sub>2</sub>(g) \to  2 Fe(s)+ 3 H<sub>2</sub>O(g)  (A)    (B)   Is the reaction endothermic or exothermic,and which of the enthalpy diagrams above Represents this reaction? Is the reaction endothermic or exothermic,and which of the enthalpy diagrams above Represents this reaction?

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Which of the following is an endothermic process?

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The standard enthalpy change for the combustion of 1 mole of propane is -2043.0 kJ.C3H8(g)+ 5 O2(g) \to 3 CO2(g)+ 4 H2O(g) Calculate Δ\Delta fH \circ for propane based on the following standard molar enthalpies of formation. The standard enthalpy change for the combustion of 1 mole of propane is -2043.0 kJ.C<sub>3</sub>H<sub>8</sub>(g)+ 5 O<sub>2</sub>(g) \to  3 CO<sub>2</sub>(g)+ 4 H<sub>2</sub>O(g) Calculate  \Delta <sub>f</sub>H<sup> \circ </sup> for propane based on the following standard molar enthalpies of formation.

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A bomb calorimeter has a heat capacity of 2.47 kJ/K.When a 0.105-g sample of a certain hydrocarbon was burned in this calorimeter,the temperature increased by 2.14 K.Calculate the energy of combustion for 1 g of the hydrocarbon.

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Iron oxide reacts with aluminum in an exothermic reaction. Fe2O3(s)+ 2 Al(s) \to 2 Fe(s)+ Al2O3(s) The reaction of 5.00 g Fe2O3 with excess Al(s)evolves 26.6 kJ of energy in the form of heat.Calculate the enthalpy change per mole of Fe2O3 reacted.

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At constant pressure and 25 \circ C,what is Δ\Delta rH \circ for the following reaction 2C2H6(g)+ 7O2(g) \to 4CO2(g)+ H2O(l) If the complete consumption of 89.4 g of C2H6 liberates -4638 kJ of heat energy?

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Which of the following chemical equations does not correspond to a standard molar enthalpy of formation?

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The heat required to convert a solid at its melting point to a liquid is called the heat of ________.

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The thermochemical equation for the combustion of butane is shown below.C4H10(g)+ 13/2 O2(g) \to 4 CO2(g)+ 5 H2O(  The thermochemical equation for the combustion of butane is shown below.C<sub>4</sub>H<sub>10</sub>(g)+ 13/2 O<sub>2</sub>(g) \to  4 CO<sub>2</sub>(g)+ 5 H<sub>2</sub>O(    )  \Delta <sub>r</sub>H<sup> \circ </sup> = -2877 kJ/mol-rxn What is the enthalpy change for the following reaction? 8 CO<sub>2</sub>(g)+ 10 H<sub>2</sub>O(    ) \to  2 C<sub>4</sub>H<sub>10</sub>(g)+ 13 O<sub>2</sub>(g) ) Δ\Delta rH \circ = -2877 kJ/mol-rxn What is the enthalpy change for the following reaction? 8 CO2(g)+ 10 H2O( 11ea8937_ab5c_9838_a16d_1fd5f2335456_TB4499_11 ) \to 2 C4H10(g)+ 13 O2(g)

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The overall chemical equation resulting from the sum of the following three steps is 2C(s)+ 2H2O(g) \to 2CO(g)+ 2H2(g) CO(g)+ H2O(g) \to CO2(g)+ H2(g) CO(g)+ 3H2(g) \to CH4(g)+ H2O(g)

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Which of the following statements is/are CORRECT? 1)Specific heat capacity is a positive value for liquids and solids and a negative value for gases. 2)The larger the heat capacity of an object,the more thermal energy it can store. 3)When heat is transferred from the surroundings to the system,q is negative.

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What is the change in internal energy of the system ( Δ\Delta U)if 7 kJ of heat energy is evolved by the system and 99 kJ of work is done on the system for a certain process?

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Calculate the energy in the form of heat (in kJ)required to convert 325 grams of liquid water at 20.0 \circ C to steam at 115 \circ C.Assume that no energy in the form of heat is transferred to the environment.(Heat of fusion = 333 J/g; heat of vaporization = 2256 J/g; specific heat capacities: liquid water = 4.184 J/g.K,steam = 1.92 J/g.K)

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Which of the following reactions corresponds to the thermochemical equation for the standard molar enthalpy of formation of solid calcium nitrate?

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Determine the standard enthalpy of formation of calcium carbonate from the thermochemical equations given below. Determine the standard enthalpy of formation of calcium carbonate from the thermochemical equations given below.

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