Exam 16: Principles of Reactivity: Chemical Equilibria
Exam 1: Basic Concepts of Chemistry53 Questions
Exam 2: Mathlets Review: The Tools of Quantitative Chemistry78 Questions
Exam 3: Atoms, molecules, and Ions105 Questions
Exam 4: Chemical Reactions85 Questions
Exam 5: Stoichiometry: Quantitative Information About Chemical Reactions76 Questions
Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions74 Questions
Exam 7: The Structure of Atoms73 Questions
Exam 8: The Structure of Atoms and Periodic Trends82 Questions
Exam 9: Bonding and Molecular Structure97 Questions
Exam 10: Bonding and Molecular Structure: Orbital Hybridization and Molecular Orbitals72 Questions
Exam 11: Gases and Their Properties92 Questions
Exam 12: Intermolecular Forces and Liquids79 Questions
Exam 13: The Chemistry of Solids77 Questions
Exam 14: Solutions and Their Behavior83 Questions
Exam 15: Chemical Kinetics: the Rates of Chemical Reactions84 Questions
Exam 16: Principles of Reactivity: Chemical Equilibria82 Questions
Exam 17: The Chemistry of Acids and Bases93 Questions
Exam 18: Principles of Reactivity: Other Aspects of Aqueous Equilibria88 Questions
Exam 19: Entropy and Free Energy76 Questions
Exam 20: Principles of Reactivity: Electron Transfer Reactions86 Questions
Exam 21: Environmental Chemistry Earths Environment,energy,and Sustainability48 Questions
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Exam 24: Carbon: Not Just Another Element93 Questions
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The following reaction occurred when a 1.0-liter reaction vessel was initially charged with 2.0 moles of N2(g)and 4.0 moles of H2(g):
Once equilibrium was established,the concentration of NH3(g)was determined to be 0.59 M at 700.°C.The value for Kc at 700.°C for the formation of ammonia is:

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(Multiple Choice)
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Correct Answer:
B
At a high temperature,equal concentrations of 0.160 mol/L of H2(g)and I2(g)are initially present in a flask.The H2 and I2 react according to the balanced equation below.
When equilibrium is reached,the concentration of H2(g)has decreased to 0.036 mol/L.What is the equilibrium constant,Kc,for the reaction?

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(Multiple Choice)
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Correct Answer:
E
A 2.5 L flask is filled with 0.25 mol SO3,0.20 mol SO2,and 0.40 mol O2,and allowed to reach equilibrium.Assume the temperature of the mixture is chosen so that Kc = 0.12.Predict the effect on the concentration of SO3 as equilibrium is achieved by using Q,the reaction quotient.
2 SO3(g)
2 SO2(g)+ O2(g)

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(Multiple Choice)
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Correct Answer:
B
In which of the following reactions does a decrease in the volume of the reaction vessel at constant temperature favor formation of the products?
(Multiple Choice)
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Consider the following equilibrium:
PCl5(g)
PCl3(g)+ Cl2(g); H = 92 kJ
The concentration of PCl3 at equilibrium may be increased by

(Multiple Choice)
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When 0.20 mole HF is dissolved in water to a volume of 1.00 L,5.8% of the HF dissociates to form F-(aq).What is the equilibrium constant for the reaction?


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When 1.0 mole of acetic acid is diluted with water to a volume of 1.0 L at 25 C,0.42% of the acetic acid ionizes to form acetate ion and hydronium ion.CH3CO2H(aq)+ H2O(
)
CH3CO2-(aq)+ H3O+(aq)
What percentage of the acid ionizes when 0.75 mole of acetic acid is diluted with water to 1.0 L at 25 C?


(Short Answer)
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Nitrogen trifluoride decomposes at to form nitrogen and fluorine gases according to the following equation:
6.00-L reaction vessel is initially charged with 1.96 mol of NF3 and allowed to come to equilibrium at 800 K.Once equilibrium is established,the reaction vessel is found to contain 0.0380 mol of N2.What is the value of Kp at this temperature? (R = 0.0821 L.atm.mol.K)

(Multiple Choice)
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For the reaction N2O4(g)
2NO2(g),Kp = 0.148 at a temperature of 298 K.What is Kp for the following reaction?
14NO2(g)
7N2O4(g)


(Multiple Choice)
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Write a balanced chemical equation which corresponds to the following equilibrium constant expression. 

(Multiple Choice)
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Given the following chemical equilibria,
N2(g)+ O2(g)
2 NO(g) K1
N2(g)+ 3 H2(g)
2 NH3(g) K2
H2(g)+ 1/2 O2(g)
H2O(g) K3
Determine the method used to calculate the equilibrium constant for the reaction below.
4 NH3(g)+ 5 O2(g)
4 NO(g)+ 6 H2O(g) K c




(Multiple Choice)
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Nitrogen and oxygen gases may react to form nitrogen monoxide.
At 1500 C,Kc equals 1.0 10-5.N2(g)+ O2(g)
2 NO(g)
If 0.030 mol N2 and 0.030 mol O2 are sealed in a 1.0 L flask at 1500 C,what is the concentration of NO(g)when equilibrium is established?

(Multiple Choice)
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At 700 K,Kp for the following equilibrium is
5.6 10-3.2HgO(s)
2Hg(l)+ O2(g)
Suppose 51.2 g of mercury(II)oxide is placed in a sealed 3.00-L vessel at 700 K.What is the partial pressure of oxygen gas at equilibrium? (R = 0.0821 L · atm/(K · mol))

(Multiple Choice)
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A 10.0-g sample of solid NH4Cl is heated in a 5.00-L container to 900.°C.At equilibrium the pressure of NH3(g)is 1.47 atm.
NH4Cl(s)
NH3(g)+ HCl(g)
The equilibrium constant,Kp,for the reaction is:

(Multiple Choice)
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The equilibrium constant at 25 C for the dissolution of silver iodide is
8.5 10-17.AgI(s)
Ag+(aq)+ I-(aq)
If an excess quantity of AgI(s)is added to water and allowed to equilibrate,what is the equilibrium concentration of I-?

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Given the following equilibria,
PbBr2(s)
Pb2+(aq)+ 2 Br-(aq) K1 = 6.6 0 10-6
Pb(OH)2(s)
Pb2+(aq)+ 2 OH-(aq) K2 = 1.4 10-15
Determine the equilibrium constant,Kc,for the following reaction.
PbBr2(s)+ 2 OH-(aq)
Pb(OH)2(s)+ 2 Br-(aq)



(Multiple Choice)
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What balanced equation is the following equilibrium expression derived from? 

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What is the Kc equilibrium-constant expression for the following equilibrium?


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An aqueous mixture of phenol and ammonia has initial concentrations of 0.200 M C6H5OH(aq)and 0.120 M NH3(aq).At equilibrium,the C6H5O-(aq)concentration is 0.050 M.Calculate K for the reaction.
C6H5OH(aq)+ NH3(aq)
C6H5O- + NH4+(aq)

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