Exam 10: Reactions of Alcohols, ethers, epoxides, amines and Sulfur-Containing Compounds

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Give the product of the following reaction. Give the product of the following reaction.

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Starting with isopropyl alcohol as the only organic material,synthesize isopropyl propyl ether. Starting with isopropyl alcohol as the only organic material,synthesize isopropyl propyl ether.

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Propose a detailed,step-by-step mechanism for the reaction pathway shown below. Propose a detailed,step-by-step mechanism for the reaction pathway shown below.

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How are certain arene oxides believed to cause cancer?

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What is the major product from the following reaction? What is the major product from the following reaction?

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Provide the sequence of reagents needed to carry out the following conversion. CH3C Provide the sequence of reagents needed to carry out the following conversion. CH<sub>3</sub>C   CH→ CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>OH CH→ CH3CH2CH2CH2CH2OH

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Provide the major organic product of the reaction below. Provide the major organic product of the reaction below.

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Provide the major organic product of the reaction below. Provide the major organic product of the reaction below.

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Which of the following alcohols gives a rearranged carbocation when dehydrated? Which of the following alcohols gives a rearranged carbocation when dehydrated?

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Provide the major organic product of the reaction below. Provide the major organic product of the reaction below.

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Draw the tosylate ion and explain why it is a particularly good leaving group.

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Propose a detailed,step-by-step mechanism for the reaction pathway shown below. Propose a detailed,step-by-step mechanism for the reaction pathway shown below.

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Predict the starting material for this reaction. Predict the starting material for this reaction.

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Provide the structure of the major organic product of the following reaction.Explain the stereochemistry which results in this product. Provide the structure of the major organic product of the following reaction.Explain the stereochemistry which results in this product.

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What is the major product of the following reaction? What is the major product of the following reaction?

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Which of the following is the best method for preparing CH3Br?

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Provide the structure of the major organic product which results when naphthalene oxide undergoes rearrangement in the presence of water.Explain the regioselectivity of this rearrangement.

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What is the major product of the following reaction? What is the major product of the following reaction?

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Provide the major organic product of the reaction below. Provide the major organic product of the reaction below.

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Give the major product for the following reaction. Give the major product for the following reaction.

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