Question 1

Which of the following compounds is the least reactive toward nucleophilic acyl substitution?

Accepted Answer

A)    
B)    
C)    
D)    
E)    
A)    
B)    
C)    
D)    
E)

Question 2

Provide the name of the compound below.

Accepted Answer

The answer of Provide the name of the compound below....

Question 3

Provide a detailed,stepwise mechanism for the reaction of propanoic anhydride with phenol.

Accepted Answer

The answer of Provide a detailed,stepwise mechanism for the reaction...

Question 4

Which of the following is one of the steps in the mechanism of the following reaction?

Accepted Answer

A)    
B)    
C)    
D)    
E)    
A)    
B)    
C)    
D)    
E)

Question 5

Which of the following compounds would yield acetic acid when hydrolyzed under heat?

Accepted Answer

A)    
B) CH3C   N 
C)    
D)    
E) all the above 
A)    
B) CH3C   N 
C)    
D)    
E) all the above

Question 6

Provide a detailed,stepwise mechanism for the base-mediated transesterification of methyl benzoate with sodium ethoxide.

Accepted Answer

The answer of Provide a detailed,stepwise mechanism for the base-mediated...

Question 7

List the following carboxylic acid derivatives in decreasing order of reactivity in nucleophilic acyl substitution reactions: acetic anhydride,methyl acetate,acetamide,acetyl chloride.

Accepted Answer

acetyl chloride > ac

Question 8

Give the product of the reaction.

Accepted Answer

A)    
B)    
C)    
D)    
E)    
A)    
B)    
C)    
D)    
E)

Question 9

Give the systematic name of the structure.

Accepted Answer

5-methyl-2

Question 10

Arrange the compounds below in order of increasing boiling point.

Accepted Answer

The answer of Arrange the compounds below in order of...

Question 11

Provide the proper IUPAC name for the compound below.

Accepted Answer

trans-5-oc

Question 12

What is the common name for the following compound?

Accepted Answer

A) λ-chlorobutanoic acid 
B) β-chlorobutanoic acid 
C) β-chlorobutyric acid 
D) λ-chlorobutyric acid 
E) 3-chlorobutyric acid 
A) λ-chlorobutanoic acid 
B) β-chlorobutanoic acid 
C) β-chlorobutyric acid 
D) λ-chlorobutyric acid 
E) 3-chlorobutyric acid

Question 13

Predict the reagents for this reaction.

Accepted Answer

A) 1 equivalents of (CH3)3N 
B) 2 equivalents of (CH3)3N 
C) 1 equivalents of (CH3)2NH 
D) 2 equivalents of (CH3)2NH 
E) all of the above 
A) 1 equivalents of (CH3)3N 
B) 2 equivalents of (CH3)3N 
C) 1 equivalents of (CH3)2NH 
D) 2 equivalents of (CH3)2NH 
E) all of the above

Question 14

Provide the major organic product of the following.

Accepted Answer

The answer of Provide the major organic product of the...

Question 15

What is the IUPAC name for the following compound?

Accepted Answer

A) 3-methylpentanoic acid 
B) isohexanoic acid 
C) β-methylvaleric acid 
D) 2-methylpentanoic acid 
E) 3-methylvaleric acid 
A) 3-methylpentanoic acid 
B) isohexanoic acid 
C) β-methylvaleric acid 
D) 2-methylpentanoic acid 
E) 3-methylvaleric acid

Question 16

What is the product obtained from the following reaction?

Accepted Answer

A) I 
B) II 
C) III 
D) IV 
E) V 
A) I 
B) II 
C) III 
D) IV 
E) V

Question 17

Which of the following compounds is benzoyl chloride?

Accepted Answer

A) I 
B) II 
C) III 
D) IV 
E) V 
A) I 
B) II 
C) III 
D) IV 
E) V

Question 18

Provide the major organic product of the following.

Accepted Answer

The answer of Provide the major organic product of the...

Question 19

Give the products of the reaction.

Accepted Answer

The answer of Give the products of the reaction. ...

Question 20

Give the products of the reaction.

Accepted Answer

The answer of Give the products of the reaction. ...

Exam 15: Reactions of Carboxylic Acids and Carboxylic Acid Derivatives

Which of the following compounds is the least reactive toward nucleophilic acyl substitution?

Provide the name of the compound below.

Provide a detailed,stepwise mechanism for the reaction of propanoic anhydride with phenol.

Which of the following is one of the steps in the mechanism of the following reaction?

Which of the following compounds would yield acetic acid when hydrolyzed under heat?

Provide a detailed,stepwise mechanism for the base-mediated transesterification of methyl benzoate with sodium ethoxide.

List the following carboxylic acid derivatives in decreasing order of reactivity in nucleophilic acyl substitution reactions: acetic anhydride,methyl acetate,acetamide,acetyl chloride.

Give the product of the reaction.

Give the systematic name of the structure.

Arrange the compounds below in order of increasing boiling point.

Provide the proper IUPAC name for the compound below.

What is the common name for the following compound?

Predict the reagents for this reaction.

Provide the major organic product of the following.

What is the IUPAC name for the following compound?

What is the product obtained from the following reaction?

Which of the following compounds is benzoyl chloride?

Provide the major organic product of the following.

Give the products of the reaction.

Give the products of the reaction.

Remembering General Chemistry: Electronic Structure and Bonding

Acids and Bases: Central to Understanding Organic Chemistry

An Introduction to Organic Compounds: Nomenclature, physical Properties, and Structure

Isomers: the Arrangement of Atoms in Space

Alkenes: Structure,nomenclature,and an Introduction to Reactivity - Thermodynamics and Kinetics

The Reactions of Alkenes - the Stereochemistry of Addition Reactions

The Reactions of Alkynes - Introduction to Multistep Synthesis

Delocalized Electrons: Their Effect on Stability, pka, and the Products of a Reaction - Aromaticity and Electronic Effects: an Introduction to the Reactions of Benzene

Substitution and Elimination Reactions of Alkyl Halides

Reactions of Alcohols, ethers, epoxides, amines and Sulfur-Containing Compounds

Organometallic Compounds

Radicals

Mass Spectrometry,infrared Spectroscopy,and Uvvis Spectroscopy

Nmr Spectroscopy

Reactions of Aldehydes and Ketones

Reactions at the Α-Carbon

Reactions of Benzene and Substituted Benzenes

More About Amines - Reactions of Heterocylic Compounds

The Organic Chemistry of Carbohydrates

Amino Acids,peptides,and Proteins

Catalysis in Organic Reactions and in Enzymatic Reactions

The Organic Chemistry of the Coenzymes, compounds Derived From Vitamins

The Organic Chemistry of the Metabolic Pathways

The Organic Chemistry of Lipids

The Chemistry of the Nucleic Acids

Synthetic Polymers

Pericyclic Reactions

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