Exam 19: More About Amines - Reactions of Heterocylic Compounds

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Draw the structure of a porphyrin ring system,and list three common,naturally-occurring molecules which contain a porphyrin-like ring system as part of their structure.

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Circle the stronger base in the pair below,and briefly explain your choice. Circle the stronger base in the pair below,and briefly explain your choice.

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Give the major product for the following reaction. Give the major product for the following reaction.

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Draw the structure of the aziridinium ion and explain why its pKa is lower than a typical secondary ammonium ion.

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Which of the following is the structure of purine? Which of the following is the structure of purine?

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Which of the following compounds is indole? Which of the following compounds is indole?

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Give the major product for the following reaction. Give the major product for the following reaction.

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Identify oxetane.

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The lone pair in pyridine is present in a

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What is the major product of the following reaction? What is the major product of the following reaction?

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Indicate whether the following molecule is aromatic,antiaromatic,or nonaromatic. Indicate whether the following molecule is aromatic,antiaromatic,or nonaromatic.

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What is the major organic product of the following reaction? What is the major organic product of the following reaction?

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Show how the dipole moments are oriented in pyrrolidine and pyrrole,and explain why they are oriented in opposite directions.

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Provide the major organic products of the reaction shown. Provide the major organic products of the reaction shown.

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Which heterocyclic ring is present in heme?

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Which of the following is a quaternary ammonium ion?

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Which of the following compounds is not aromatic? Which of the following compounds is not aromatic?

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What is/are the product(s)of the following reaction? What is/are the product(s)of the following reaction?

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Provide the major organic product(s)of the reaction below. Provide the major organic product(s)of the reaction below.

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How would you carry out the following transformation? How would you carry out the following transformation?

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