Exam 27: Synthetic Polymers

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Provide the structure of poly(acrylonitrile).

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Propose a synthesis of poly(vinyl alcohol)from H2C Propose a synthesis of poly(vinyl alcohol)from H<sub>2</sub>C   CHO<sub>2</sub>CCH<sub>3</sub>. CHO2CCH3.

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Show the three methods by which the following radical can be terminated. Show the three methods by which the following radical can be terminated.

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Provide a mechanism to show how H2C Provide a mechanism to show how H<sub>2</sub>C   CHCO<sub>2</sub>CH<sub>3</sub> is polymerized using butyllithium as the initiator. CHCO2CH3 is polymerized using butyllithium as the initiator.

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Natural rubber is a

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Draw the structure of Nylon 66.

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The pattern below is found in what type of polymer? AAAABBBBAAAABBBB

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Which of the following species can best serve as an initiator for cationic polymerization?

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Draw a short segment of plexiglass,using five monomers.

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Which dimer (step-growth dimerization)will form from the following monomer? Which dimer (step-growth dimerization)will form from the following monomer?

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Which of the following monomers has the greatest ability to undergo anionic polymerization? Which of the following monomers has the greatest ability to undergo anionic polymerization?

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Draw the structure of the polymer produced in the following reaction. Draw the structure of the polymer produced in the following reaction.

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Which of the following is characteristic of oriented polymers?

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As the % crystallinity of polyethylene increases,its density ________ and its melting point ________.

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Identify the type of polymer for nylon 66.

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What is the structure of the monomer from which the following polymer is made? What is the structure of the monomer from which the following polymer is made?

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