Exam 13: Structure Determination

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Which of the following compounds would show the longest wavelength lmax in its UV spectrum? a.Which of the following compounds would show the longest wavelength l<sub>max</sub> in its UV spectrum? a.  b.  c.  d. b.Which of the following compounds would show the longest wavelength l<sub>max</sub> in its UV spectrum? a.  b.  c.  d. c.Which of the following compounds would show the longest wavelength l<sub>max</sub> in its UV spectrum? a.  b.  c.  d. d.Which of the following compounds would show the longest wavelength l<sub>max</sub> in its UV spectrum? a.  b.  c.  d.

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What are the units for electromagnetic radiation used in infrared spectroscopy?

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Which type of spectroscopy (IR, UV, or MS) will best distinguish between the pair of compounds below? Give a brief reason. Which type of spectroscopy (IR, UV, or MS) will best distinguish between the pair of compounds below? Give a brief reason.

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Below is the mass spectrum of an unknown hydrocarbon. In addition, this hydrocarbon shows characteristic absorption at 2100 cm-1 in its IR spectrum. Give the structure of this unknown. Below is the mass spectrum of an unknown hydrocarbon. In addition, this hydrocarbon shows characteristic absorption at 2100 cm<sup>-1</sup> in its IR spectrum. Give the structure of this unknown.   (Spectrum obtained from: SDBSWeb: http://www.aist.go.jp/RIODB/SDBS/) The formula weight of 54 corresponds to a molecular formula of C<sub>4</sub>H<sub>6</sub>, which has two degrees of unsaturation. Possible structures for this formula are: (Spectrum obtained from: SDBSWeb: http://www.aist.go.jp/RIODB/SDBS/) The formula weight of 54 corresponds to a molecular formula of C4H6, which has two degrees of unsaturation. Possible structures for this formula are:

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