Exam 13: Structure Determination
Exam 1: Structure and Bonding:acids and Bases40 Questions
Exam 2: Alkanes: The Nature of Organic Compounds47 Questions
Exam 3: Alkenes and Alkynes: the Nature of Organic Reactions37 Questions
Exam 4: Reactions of Alkenes and Alkynes44 Questions
Exam 5: Aromatic Compounds51 Questions
Exam 6: Sterechemistry at Tetrahedral Centers35 Questions
Exam 7: Organohalides: Nucleophilic Substitutions and Eliminations49 Questions
Exam 8: Alcohols, Phenols, Ethers, and Their Sulfur Analogs39 Questions
Exam 9: Aldehydes and Ketones: Nucleophilic Addition Reactions32 Questions
Exam 10: Carboxylic Acids and Derivatives: Nucleophilic Acyl Substitution Reactions66 Questions
Exam 11: Carbonyl Alpha-Substitution Reactions and Condensation Reactions37 Questions
Exam 12: Amines31 Questions
Exam 13: Structure Determination64 Questions
Exam 14: Biomolecules: Carbohydrates41 Questions
Exam 15: Biomolecules: Amino Acids, Peptides, and Proteins43 Questions
Exam 16: Biomolecules: Lipids and Nucleic Acids37 Questions
Exam 17: The Organic Chemistry of Metabolic Pathways35 Questions
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Instructions: For each of the compounds below tell how many signals you would expect the molecule to have in its normal, broadband decoupled 13C NMR spectra.
Number of signals: 

(Essay)
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Which of the following compounds would produce the most downfield signal in a 13C NMR spectrum? 

(Multiple Choice)
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Circle any of the following compounds that would be a candidate to produce a UV absorption spectrum. 

(Essay)
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Instructions: Refer to the structure of 3-methylbutan-2-one below to answer the following question(s).
Refer to instructions. What is the splitting pattern for the hydrogens in 3-methylbutan-2-one labeled A, B, and C, respectively?

(Multiple Choice)
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Consider the compound below:
a) At what approximate positions might the compound show IR absorptions?
b) How would this spectrum differ from that of cyclohexand?

(Essay)
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Which of the following compounds gives an infrared spectrum with a peak at ~1750 cm-1, but no significant peaks at 3000-3500 cm-1 or 1050-1250 cm-1?
(Multiple Choice)
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Which feature in the 1H NMR spectrum provides information about the number of neighboring protons of each proton in the compound?
(Multiple Choice)
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A 3.42 ´ 10-5 M solution of dibenzalacetone in ethanol produced an absorbance of 0.753 in a 1.00 cm cell. Based on this data, what is e for this compound?
(Multiple Choice)
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Instructions: Refer to the structure of 3-methylbutan-2-one below to answer the following question(s).
Refer to instructions. What is the ratio of peak areas upon integration of the spectrum for A, B, and C respectively?

(Multiple Choice)
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Instructions: Match a structure from the list below to the following IR spectra.
A.
B.
C.
D.
E.
F.







(Essay)
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Which of the following compounds gives an infrared spectrum with peaks at 3000-3500 cm-1 and ~1750 cm-1?
(Multiple Choice)
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Instructions: For each of the compounds below tell how many signals you would expect the molecule to have in its normal, broadband decoupled 13C NMR spectra.
Number of signals: 

(Essay)
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Which of the following bonds gives rise to a strong absorbance near 1700 cm-1 in the infrared spectrum?
(Multiple Choice)
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The amount of energy in electromagnetic radiation is related to the frequency and wavelength of the radiation. High energy radiation, like gamma rays, is of:
(Multiple Choice)
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A compound with the molecular formula C6H4ClBr produces only two doublets in the 1H NMR spectrum.
a) Propose a structure for this compound.
b) How many signals would be present in the for this structure?
(Essay)
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Which of the following combinations of peaks appears in the 1H NMR spectrum of diethyl ether, CH3CH2OCH2CH3?
(Multiple Choice)
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At what approximate positions might the compound below show IR absorptions? 

(Essay)
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Instructions: For each of the compounds below tell how many signals you would expect the molecule to have in its normal, broadband decoupled 13C NMR spectra.
Number of signals: 

(Essay)
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Which of the following compounds would have the longest lmax in the UV region of the electromagnetic spectrum? 

(Multiple Choice)
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