Exam 13: Mixtures at the Molecular Level: Properties of Solutions

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A solution is prepared by mixing 0.3355 moles of NaNO3 (84.995 g mol-1)with 235.0 g of water (18.015 g mol-1). Its density is 1.0733 g mL-1. What is the molarity of the solution?

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A solution is sitting undisturbed on a side shelf in the laboratory. A small crystal of the same solute of which the solution is made was gently dropped into the solution. Suddenly, a mass of crystals forms and settles to the bottom of the container. The solution is, or must have been

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Calculate the molality of a 25.0% by mass solution of MgCl2 in H2O. The density of this solution is 1.127 g/mL.

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A solution is made by dissolving 1.25 moles of magnesium nitrate in 300.0 g of water. If the van't Hoff factor, i, for this particular concentration is 2.25, what is the expected freezing point of this solution? Kf = 1.86 °C m-1.

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An unknown ionic substance has a van't Hoff factor of 1.89 with a concentration of 0.1 M. If the concentration of this ionic substance was increased to 0.5 M the value of the van't Hoff factor would ________. Hint: Dilute solutions behave closer to expectations than concentrated solutions.

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9.92 grams of a compound with a molar mass of 124.0 grams/mole when dissolved in 150.0 grams of water gave a solution that had a freezing point of -2.69°C. Calculate the experimental value of the van't Hoff factor. Kf = 1.86 °C m-1.

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An aqueous solution made by dissolving 168 mg of an unknown compound (a nonelectrolyte)in enough water to make 500.0 mL of solution, develops an osmotic pressure of 5.22 torr at a temperature of 23.5°C. What is the molecular mass of this unknown compound?Hint: Find molarity, then moles, then molar mass, being sure to keep track of units.

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The van't Hoff factor describes to what degree an ionic substance ________.

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An aqueous solution of orthophosphoric acid, H3PO4, has a measured density of 1.2089 g mL-1 and is 5.257 molal. How many moles of H3PO4 are there in one liter of this solution?

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At 28.0°C, the vapor pressure of n-propyl mercaptan, C3H7SH, is 175 torr, while that of acetonitrile, CH3CN, is 102 torr. What is the vapor pressure, at 28.0°C, of a solution made by mixing 100.0 g of C3H7SH and 100.0 g CH3CN, if Raoult's Law is obeyed?

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An aqueous solution of ethanol, C2H5OH, is 19.00% ethanol by mass and has a density of 0.9700 g mL-1. Calculate the molality of the ethanol solution.

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Which aqueous solution will have the highest boiling point temperature?

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Which of the following would best be classified as a heterogeneous suspension?

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Wax is a solid mixture of hydrocarbon compounds consisting of molecules with long chains of carbon atoms. Which solvent would you expect to be most capable of dissolving wax?

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A solution in a beaker has some un-dissolved solute lying on the bottom of the beaker. If the rate of dissolution of the solute exceeds the rate of crystallization, the solution is described as

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A solution is made by mixing acetone and methyl alcohol, whose structures are shown as I and II below. Which statement below best describes the characteristics of this mixture? A solution is made by mixing acetone and methyl alcohol, whose structures are shown as I and II below. Which statement below best describes the characteristics of this mixture?   Hint: How does the strength of hydrogen bonds compare to other intermolecular forces? Hint: How does the strength of hydrogen bonds compare to other intermolecular forces?

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The mixture of air bubbles in whipped cream would best be classified as

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A solution of sodium nitrite is prepared by mixing 3.25 g of NaNO2 with 12.0 g of water. The percent, by mass, of NaNO2 is

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A mixture of fine sand in water would best be classified as what kind of solution or mixture?

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A solution of sodium nitrate, NaNO3, in water is 5.181 molar and its density is 1.2680 g mL-1. Calculate the percent, by weight, of sodium nitrate in the solution.

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