Exam 19: The Transition Metals

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Arrange the following complexes in order of increasing orbital splitting enegy: [Co(NH3)6]3+, [Co(NH3)4]2+, [Co(NH3)6]2+.(If needed, use the following equation:Spectrochemical Series I- < Br- < Cl- < F- < OH- < H2O< NH3 < en < NO2- < CN- < CO)

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C

You have two samples, one contains [Cr(CN)6]3- and the second [CrF6]3-. One solution is yellow, the second is green and they were found to have absorbance maxima at 650 and 380 nm. Unfortunately, you forgot to annotate which sample was which. Based on your knowledge which of the below show the correct assignments?(If needed, use the following equation:Spectrochemical Series I- < Br- < Cl- < F- < OH- < H2O< NH3 < en < NO2- < CN- < CO)

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B

Which of the following transition metals in the 3d series has the least variability in preferred oxidation number?

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E

How many chloride ions, Cl-, would you expect to find in a platinum complex described as PtCl4 . 5NH3?(If needed, use the following equation:Spectrochemical Series I- < Br- < Cl- < F- < OH- < H2O< NH3 < en < NO2- < CN- < CO)

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The three main functions of metalloproteins are

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Which of the following has the most unpaired electrons?(If needed, use the following equation:Spectrochemical Series I- < Br- < Cl- < F- < OH- < H2O< NH3 < en < NO2- < CN- < CO)

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What is the correct arrangement of Sc, V, and Cu in order of increasing melting point?

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Which metal is primarily used in the photographic industry?

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In which of the following complexes would you expect the pairing energy to be larger than the orbital splitting energy?(If needed, use the following equation:Spectrochemical Series I- < Br- < Cl- < F- < OH- < H2O< NH3 < en < NO2- < CN- < CO)

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Titanium is used in many specialized engineering applications. Which of the following is characteristic of titanium?

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What is the material just one reaction away from chromium metal?

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The complexes Co(NH3)63+ and Mo(CO)6 are isoelectronic and diamagnetic. The first complex is orange and the second complex is white. What can you deduce about the value of Δ\Delta in both of these complexes?(If needed, use the following equation:Spectrochemical Series I- < Br- < Cl- < F- < OH- < H2O< NH3 < en < NO2- < CN- < CO)

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What is the correct arrangement of Pd, Ni, and Pt in order of decreasing density?

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The standard reduction potential for aqueous Ag+ is 0.80 V. This value of the reduction potential

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Which of the techniques in production of metals takes advantage of different solubilities?

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Which metals were discovered first?

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What process must be applied to ilmenite ore (FeTiO3) before it can be converted to titanium metal?

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Which of the techniques in production of metals takes advantage of different redox properties?

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The metals of which group are most often used in batteries?

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Deoxyhaemoglobin is bluish in colour, oxyhaemoglobin is bright red. This indicates that the crystal field splitting is

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