Exam 19: The Transition Metals

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What differences might you expect between the two complexes, Fe(CN)64- and FeF64-?(If needed, use the following equation:Spectrochemical Series I- < Br- < Cl- < F- < OH- < H2O< NH3 < en < NO2- < CN- < CO)

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Aqueous copper(I) chloride is nearly colourless whereas aqueous copper(II) chloride is blue in colour. This difference is because(If needed, use the following equation:Spectrochemical Series I- < Br- < Cl- < F- < OH- < H2O< NH3 < en < NO2- < CN- < CO)

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Which of the following transition metals in the 3d series has the most variability in preferred oxidation number?

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[Co(NH3)5NO2]Cl2 and [Co(NH3)5ONO]Cl2 are examples of what type of isomer?(If needed, use the following equation:Spectrochemical Series I- < Br- < Cl- < F- < OH- < H2O< NH3 < en < NO2- < CN- < CO)

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What is the oxidation state of iron in deoxyhaemoglobin and oxyhaemoglobin?

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What is the correct arrangement of Hf, Ti, and Zr in order of increasing melting point?

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Which of the metals is most likely to be found in elemental form in nature?

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What are reasons that metals are used in metalloproteins?

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What is at the active site for superoxide dismutase?

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What is the layer above molten iron in a blast furnace called?

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The complex Fe(C2O4)33- has one unpaired electron. What is the electron configuration of this complex?(If needed, use the following equation:Spectrochemical Series I- < Br- < Cl- < F- < OH- < H2O< NH3 < en < NO2- < CN- < CO)

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What is the correct arrangement of Cr, Ni, and Zn in order of decreasing density?

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Which transition metal compounds are most likely to found as pure elements?

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What is the oxidation state of rhodium in pentaamminebromorhodium bromide, [Rh(NH3)5Br]Br2?

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Which of the following five complexes are paramagnetic with 2 unpaired electrons? Which of the following five complexes are paramagnetic with 2 unpaired electrons?   (If needed, use the following equation:Spectrochemical Series  I<sup>-</sup> < Br<sup>-</sup> < Cl<sup>-</sup> < F<sup>-</sup> < OH<sup>-</sup> < H<sub>2</sub>O< NH<sub>3</sub> < en < NO<sub>2</sub><sup>-</sup> < CN<sup>-</sup> < CO) (If needed, use the following equation:Spectrochemical Series I- < Br- < Cl- < F- < OH- < H2O< NH3 < en < NO2- < CN- < CO)

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Which is the chemical formula for the compound named hexamminecobalt(III) sulphate?

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The transition metals with the electron configurations of 4s23d2 and 5s24d7 are

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Which of the following groups has primary use as catalysts?

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