Exam 16: Applications of Aqueous Equilibria

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What is the approximate value of the equilibrium constant,Kn,for the neutralization of nitrous acid with ammonia,shown in the equation below? The Ka for HNO2 is 4.5 × 10-4 and the Kb for NH3 is 1.8 × 10-5. HNO2(aq)+ NH3(aq)⇌ NH4NO2(aq)

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What is the approximate value of the equilibrium constant,Kn,for the neutralization of acetic acid with potassium hydroxide,shown in the equation below? The Ka for acetic acid is 1.8 × 10-5. CH3CO2H(aq)+ KOH(aq)⇌ H2O(l)+ NaCH3CO2(aq)

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What volume of 5.00 × 10-3 M HNO3 is needed to titrate 100.00 mL of 5.00 × 10-3 M Ca(OH)2 to the equivalence point?

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The balanced net ionic equation for the neutralization reaction involving equal molar amounts of HCl and CH3CH2NH2 is ________.

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What is the pH of the solution formed when 50 mL of 0.250 M NaOH is added to 50 mL of 0.120 M HCl?

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The following pictures represent solutions at various points in the titration of a weak acid HA with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity). The following pictures represent solutions at various points in the titration of a weak acid HA with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup> initially present,OH<sup>-</sup> initially present and solvent water molecules have been omitted for clarity).   -Which picture represents the solution before the equivalence point? -Which picture represents the solution before the equivalence point?

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What is the resulting pH when 0.005 moles of KOH is added to 0.100 L of a buffer solution that is 0.100 M in H2PO4- and 0.100 M HPO42- and the Ka2 = 6.2 × 10-8?

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What is the common ion in a solution prepared by mixing 0.55 M LiCH3CO2 with 0.10 M CH3CO2H?

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What is the pH of a solution prepared by mixing 25.00 mL of 0.10 M methylamine,CH3NH2,with 25.00 mL of 0.10 M methylammonium chloride,CH3NH3Cl? Assume that the volume of the solutions are additive and that Kb = 3.70 × 10-4 for methylamine.

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The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H2A with NaOH. The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H<sub>2</sub>A with NaOH.   -Which point a-d represents pK<sub>a2</sub>? -Which point a-d represents pKa2?

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What is the Ka of the amino acid glutamine if it is 33.0% dissociated at pH = 8.82?

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What is the pH of 1 L of 0.30 M TRIS,0.60 M TRISH+ buffer to which one has added 5.0 mL of 12 M HCl? The Kb for the TRIS/TRISH+ is 1.2 × 10-6.

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What is the molar solubility of AgCl in 0.10 M NH3? Ksp for AgCl is 1.8 × 10-10 and the Kf for Ag(NH3)2+ is 1.7 × 107.

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What is the pH of a solution prepared by mixing 50.00 mL of 0.10 M NH3 with 20.00 mL of 0.10 M NH4Cl? Assume that the volume of the solutions are additive and that Kb = 1.8 × 10-5 for NH3.

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What is the molar solubility of Mg(OH)2 in a basic solution with a pH of 12.00? Ksp for Mg(OH)2 is 5.6 × 10-12.

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What is the molar solubility of AgCl in 0.50 M NaCN if the colorless complex ion Ag(CN)2- forms? Ksp for AgCl is 1.8 × 10-10 and Kf for Ag(CN)2- is 1.0 × 1021.

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The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup>,OH<sup>-</sup>,and solvent H<sub>2</sub>O molecules have been omitted for clarity. )   -Which solution has the lowest pH? -Which solution has the lowest pH?

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Which is a net ionic equation for the neutralization of a strong acid with a strong base?

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The following plot shows two titration curves,each representing the titration of 50.00 mL of 0.100 M acid with 0.100 M NaOH. The following plot shows two titration curves,each representing the titration of 50.00 mL of 0.100 M acid with 0.100 M NaOH.   -Which points a-d represent the half-equivalence point and the equivalence point,respectively,for the titration of a weak acid? -Which points a-d represent the half-equivalence point and the equivalence point,respectively,for the titration of a weak acid?

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The following pictures represent solutions of CuS,which may also contain ions other than Cu2+ and S2- which are not shown.Gray spheres represent Cu2+ ions and dotted spheres represent S2- ions. The following pictures represent solutions of CuS,which may also contain ions other than Cu<sup>2+</sup> and S<sup>2-</sup> which are not shown.Gray spheres represent Cu<sup>2+</sup> ions and dotted spheres represent S<sup>2-</sup> ions.   -If solution (1)is a saturated solution of CuS,which of solutions (2)-(4)are saturated? -If solution (1)is a saturated solution of CuS,which of solutions (2)-(4)are saturated?

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