Exam 16: Applications of Aqueous Equilibria

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Selenous acid,H2SeO3 has acid dissociation constants Ka1 = 3.5 × 10-2 and Ka2 = 5 × 10-8.When 25.00 mL of 0.100 M selenous acid is titrated with 0.200 M NaOH the first equivalence point occurs at pH = ________.

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What is the pH of the resulting solution if 40.00 mL of 0.10 M acetic acid is added to 10.00 mL of 0.10 M NaOH? Assume that the volumes of the solutions are additive.Ka = 1.8 × 10-5 for CH3CO2H.

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Potassium chromate is slowly added to a solution containing 0.20 M AgNO3 and 0.20 M Ba(NO3)2.Describe what happens if the Ksp for Ag2CrO4 is 1.1 × 10-12 and the Ksp of BaCrO4 is 1.2 × 10-10.

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What is the pH of a solution made by mixing 30.00 mL of 0.10 M acetic acid with 40.00 mL of 0.10 M KOH? Assume that the volumes of the solutions are additive.Ka = 1.8 × 10-5 for CH3CO2H.

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What is the equilibrium constant expression for the Ksp of Sr3(PO4)2?

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Use the graphs below to answer the following questions. Use the graphs below to answer the following questions.   -What is the characteristic pH-titrant curve for the titration of a strong base by a strong acid? -What is the characteristic pH-titrant curve for the titration of a strong base by a strong acid?

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Consider a buffered solution consisting of H2CO3 and HCO3- where the pKa = 6.4.At pH = 6.4,which of the following is true?

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What is the molar solubility of Mg(OH)2 in a basic solution with a pH of 12.00? Ksp for Mg(OH)2 is What is the molar solubility of Mg(OH)<sub>2</sub> in a basic solution with a pH of 12.00? K<sub>sp</sub> for Mg(OH)<sub>2</sub> is

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Oxalic acid,H2C2O4 has acid dissociation constants Ka1 = 5.9 × 10-2 and Ka2 = 6.4 × 10-5.What is the pH after 20.00 mL of 0.0500 M NaOH is added to 5.00 mL of 0.2000 M H2C2O4?

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The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H2A with NaOH. The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H<sub>2</sub>A with NaOH.   -Which point a-d represents the HX<sup>-</sup>/X2<sup>-</sup> buffer region? -Which point a-d represents the HX-/X2- buffer region?

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CaF2 has Ksp = 3.5 × 10-11.If 25 mL of 8.0 × 10-4 M Ca(NO3)2 is mixed with 75 mL of 4.0 × 10-4 M KF,a precipitate of CaF2 ________ (will,will not)form.

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When 70 mL of 0.18 M NH4Cl is added to 70 mL of 0.18 M NH3,relative to the pH of the 0.10 M NH3 solution the pH of the resulting solution will

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The following pictures represent solutions at various stages in the titration of a weak diprotic acid H2A with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A2- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity). The following pictures represent solutions at various stages in the titration of a weak diprotic acid H<sub>2</sub>A with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A<sup>2-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup> initially present,OH<sup>-</sup> initially present and solvent water molecules have been omitted for clarity).   -Which picture represents the system with the lowest pH? -Which picture represents the system with the lowest pH?

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What is the most soluble salt of the following set?

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The following pictures represent solutions that contain a weak acid HA (pKa = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA (pK<sub>a</sub> = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup>,OH<sup>-</sup>,and solvent H<sub>2</sub>O molecules have been omitted for clarity. )   -Which of these solutions are buffers? -Which of these solutions are buffers?

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The following pictures represent solutions that contain a weak acid HA (pKa = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA (pK<sub>a</sub> = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+ </sup>initially present,OH<sup>- </sup>initially present and solvent water molecules have been omitted for clarity. )   -Which picture represents the equilibrium state of the solution after addition of one H<sub>3</sub>O<sup>+</sup> ion to the solution shown in picture (1)? -Which picture represents the equilibrium state of the solution after addition of one H3O+ ion to the solution shown in picture (1)?

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The following pictures represent solutions that contain a weak acid HA (pKa = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA (pK<sub>a</sub> = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup>,OH<sup>-</sup>,and solvent H<sub>2</sub>O molecules have been omitted for clarity. )   -Which solution has the lowest pH? -Which solution has the lowest pH?

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What is the pH of a solution prepared by mixing 50.00 mL of 0.10 M methylamine,CH3NH2,with 15.00 mL of 0.10 M methylammonium chloride,CH3NH3Cl? Assume that the volume of the solutions are additive and that Kb = 3.70 × 10-4 for methylamine.

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Which statement about buffers is true?

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Which set of ions precipitate as sulfides?

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