Exam 16: Applications of Aqueous Equilibria

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What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous hydrofluoric acid requires 30.00 mL of 0.100 M NaOH? Ka = 6.76 × 10-4 for HF.

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What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous hydrofluoric acid requires 30.00 mL of 0.400 M NaOH? Ka = 6.76 × 10-4 for HF.

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Calculate the solubility (in g/L)of calcium fluoride in water at 25°C if the Ksp for Ca F2 is 3.5 × Calculate the solubility (in g/L)of calcium fluoride in water at 25°C if the K<sub>sp</sub> for Ca<sub> </sub>F<sub>2</sub> is 3.5 ×   . .

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0.10 M potassium chromate is slowly added to a solution containing 0.10 M AgNO3 and 0.10 M Ba(NO3)2.What is the Ag+ concentration when BaCrO4 just starts to precipitate? The Ksp for Ag2CrO4 and BaCrO4 are 1.1 × 10-12 and 1.2 × 10-10,respectively.

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What is the pH of a buffered system made by dissolving 17.42 g of KH2PO4 and 20.41 g of K2HPO4 in water to give a volume of 200.0 mL? The Ka2 for dihydrogen phosphate is 6.2 × 10-8 and the equilibrium reaction of interest is H2PO4-(aq)+ H2O(l)⇌ H3O+(aq)+ HPO4-(aq).

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The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup>,OH<sup>-</sup>,and solvent H<sub>2</sub>O molecules have been omitted for clarity. )   -Which solution has the greatest buffer capacity? -Which solution has the greatest buffer capacity?

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What is the least soluble salt of the following set?

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What is the molar solubility of lead(II)chromate in 0.10 M HNO3 if the Ksp for PbCrO4 is 2.8 × 10-13 and the Ka2 for H2CrO4 is 3.0 × 10-7? Note that H2CrO4 is considered to be a strong acid.

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The solution formed upon adding 80.00 mL of 0.50 M NH4Cl to 80.00 mL of 0.50 M NH3 will have a pH that is ________ the pH of the original NH3 solution.

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What is the pH of the resulting solution if 30.00 mL of 0.10 M acetic acid is added to 10.00 mL of 0.10 M NaOH? Assume that the volumes of the solutions are additive.Ka = 1.8 × 10-5 for CH3CO2H.

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What is the pH of a solution made by mixing 30.00 mL of 0.10 M acetic acid with 45.00 mL of 0.100 M KOH? Assume that the volumes of the solutions are additive.Ka = 1.8 × 10-5 for CH3CO2H.

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Which metal sulfides can be precipitated from a solution that is 0.01 M in Mn2+,Zn2+,Pb2+ and Cu2+ and 0.10 M in H2S at a pH of 1.0? Which metal sulfides can be precipitated from a solution that is 0.01 M in Mn<sup>2+</sup>,Zn<sup>2+</sup>,Pb<sup>2+</sup> and Cu<sup>2+</sup> and 0.10 M in H<sub>2</sub>S at a pH of 1.0?

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What volume of 0.100 M NaOH is needed to make 100.0 mL of a buffer solution with a pH of 6.00 if one starts with 50.0 mL of 0.100 M potassium hydrogen phthalate? The Ka2 for potassium hydrogen phthalate is 3.1 × 10-6.

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What is the pH of the resulting solution if 40.mL of 0.432 M methylamine,CH3NH2,is added to 15 mL of 0.234 M HCl? Assume that the volumes of the solutions are additive.Ka = 2.70 × 10-11 for CH3NH3+.

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What is the Henderson-Hasselbalch equation for the acidic buffer HA/A-?

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The neutralization constant Kn for the neutralization of acetylsalicylic acid (C9H8O4)and codeine (C18H21NO3)is 4.8 × 104.The acid dissociation constant Ka for acetylsalicylic acid is 3.0 × 10-4.What is the base dissociation constant Kb for codeine?

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The dissociation equilibrium constants for the protonated form of alanine (a diprotic amino acid,H2X+)are Ka1 = 4.6 × 10-3 and Ka2 = 2.0 × 10-10.What is the pH of 50.00 mL of a 0.050 M solution of alanine after 37.50 mL of 0.100 M NaOH has been added?

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Addition of 0.0125 mol KOH to 150 mL of a 0.150 M formic acid/0.100 M sodium formate buffer results in a pH = ________.The Ka of formic acid is 1.8 × 10-4.

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The equivalence point pH of the titration of four weak acids is given.Which is the strongest acid?

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Which is the best acid to use in the preparation of a buffer with pH = 9.3?

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