Exam 10: Bonding and Molecular Structure: Orbital Hybridization and Molecular Orbitals

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Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s).For oxygen and fluorine,the σ\sigma 2p orbital should be lower in energy than the π\pi 2p orbitals.However,the diagram will still yield correct bond order and magnetic behavior for these molecules.  Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s).For oxygen and fluorine,the  \sigma <sub>2p</sub> orbital should be lower in energy than the  \pi <sub>2p</sub> orbitals.However,the diagram will still yield correct bond order and magnetic behavior for these molecules.   -Refer to Diagram 9-1.Assume that the molecular orbital energy diagram for a homonuclear diatomic molecule applies to a heteronuclear diatomic molecule.What is the molecular orbital configuration of CO? -Refer to Diagram 9-1.Assume that the molecular orbital energy diagram for a homonuclear diatomic molecule applies to a heteronuclear diatomic molecule.What is the molecular orbital configuration of CO?

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Which theory,valence bond or molecule orbital,correctly predicts the existence of paramagnetic molecules?

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What is the hybridization of an atom that has 1 σ\sigma bond,0 π\pi bonds,and 3 lone pairs?

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All of the following statements concerning molecular orbital (MO)theory are correct EXCEPT

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Which of the labeled carbon atoms (C1-C4)is/are sp hybridized? Which of the labeled carbon atoms (C<sub>1</sub>-C<sub>4</sub>)is/are sp hybridized?

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Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s).For oxygen and fluorine,the σ\sigma 2p orbital should be lower in energy than the π\pi 2p orbitals.However,the diagram will still yield correct bond order and magnetic behavior for these molecules.  Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s).For oxygen and fluorine,the  \sigma <sub>2p</sub> orbital should be lower in energy than the  \pi <sub>2p</sub> orbitals.However,the diagram will still yield correct bond order and magnetic behavior for these molecules.   -Refer to Diagram 9-1.According to molecular orbital theory,which of the following species will be diamagnetic? -Refer to Diagram 9-1.According to molecular orbital theory,which of the following species will be diamagnetic?

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For which of the following molecules does the carbon atom have sp3 hybridization?

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In molecular orbital theory,the bond order is defined as 1/2 ×\times (the number of electrons in ________ orbitals minus the number of electrons in antibonding orbitals).

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Which of the following concerning σ\sigma and π\pi bonds is/are correct? 1)Sigma bonds may only be formed from unhybridized orbitals. 2)Pi bonds are formed from unhybridized p orbitals. 3)A pi bond has an electron distribution above and below the bond axis.

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Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s).For oxygen and fluorine,the σ\sigma 2p orbital should be lower in energy than the π\pi 2p orbitals.However,the diagram will still yield correct bond order and magnetic behavior for these molecules.  Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s).For oxygen and fluorine,the  \sigma <sub>2p</sub> orbital should be lower in energy than the  \pi <sub>2p</sub> orbitals.However,the diagram will still yield correct bond order and magnetic behavior for these molecules.   -Refer to diagram 9-1.Identify the molecule or ion with the longest bond length. -Refer to diagram 9-1.Identify the molecule or ion with the longest bond length.

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What is the hybridization of the central atom in a molecule with a trigonal-planar molecular geometry?

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Which of the following characteristics apply to NCl3? 1)polar bonds 2)nonpolar molecule 3)triangular-planar molecular shape 4)sp2 hybridized N atom

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What is the hybridization of the sulfur atom in SO42-?

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Draw a Lewis structure of xenon trioxide.What is the hybridization of the xenon atom in this molecule?

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For which of the following molecules or ions does the central atom have sp hybridization: N3-,O3,and SF3+?

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Which diatomic molecule or ion has valence electron molecular orbital configuration provided below? [core electrons]( σ\sigma 2s)2( σ\sigma *2s)2( σ\sigma 2p)2( π\pi 2p)4( π\pi *2p)1

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What does the following figure represent? What does the following figure represent?

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For which of the following compounds is it possible for cis and trans isomers to exist? For which of the following compounds is it possible for cis and trans isomers to exist?

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The hybridization of the carbon atom in CF3+ is ________.

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In the NO2- ion,each atom can be viewed as sp2 hybridized.Thus,each atom has one remaining unhybridized p orbital.How many π\pi 2p molecular orbitals (including both bonding and antibonding orbitals)are formed using the unhybridized p orbitals?

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