Exam 16: Principles of Reactivity: Chemical Equilibria

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Given the following equilibria, Ni2+(aq)+ 2 OH-(aq)  Given the following equilibria, Ni<sup>2+</sup>(aq)+ 2 OH<sup>-</sup>(aq)   Ni(OH)<sub>2</sub>(s) ~~~~~~~~  K<sub>1</sub> = 1.8  \times  10<sup>15</sup> Ni<sup>2+</sup>(aq)+ 4 CN<sup>-</sup>(aq)   Ni(CN)<sub>4</sub><sup>2-</sup>(aq) ~~  ~~   K<sub>2</sub> = 2.0  \times 10<sup>31</sup> Determine the equilibrium constant,K<sub>c</sub>,for the following reaction. Ni(OH)<sub>2</sub>(s)+ 4 CN<sup>-</sup>(aq)   Ni(CN)<sub>4</sub><sup>2-</sup>(aq)+ 2 OH<sup>-</sup>(aq) Ni(OH)2(s)         ~~~~~~~~ K1 = 1.8 ×\times 1015 Ni2+(aq)+ 4 CN-(aq)  Given the following equilibria, Ni<sup>2+</sup>(aq)+ 2 OH<sup>-</sup>(aq)   Ni(OH)<sub>2</sub>(s) ~~~~~~~~  K<sub>1</sub> = 1.8  \times  10<sup>15</sup> Ni<sup>2+</sup>(aq)+ 4 CN<sup>-</sup>(aq)   Ni(CN)<sub>4</sub><sup>2-</sup>(aq) ~~  ~~   K<sub>2</sub> = 2.0  \times 10<sup>31</sup> Determine the equilibrium constant,K<sub>c</sub>,for the following reaction. Ni(OH)<sub>2</sub>(s)+ 4 CN<sup>-</sup>(aq)   Ni(CN)<sub>4</sub><sup>2-</sup>(aq)+ 2 OH<sup>-</sup>(aq) Ni(CN)42-(aq)     ~~ ~~ K2 = 2.0 ×\times 1031 Determine the equilibrium constant,Kc,for the following reaction. Ni(OH)2(s)+ 4 CN-(aq)  Given the following equilibria, Ni<sup>2+</sup>(aq)+ 2 OH<sup>-</sup>(aq)   Ni(OH)<sub>2</sub>(s) ~~~~~~~~  K<sub>1</sub> = 1.8  \times  10<sup>15</sup> Ni<sup>2+</sup>(aq)+ 4 CN<sup>-</sup>(aq)   Ni(CN)<sub>4</sub><sup>2-</sup>(aq) ~~  ~~   K<sub>2</sub> = 2.0  \times 10<sup>31</sup> Determine the equilibrium constant,K<sub>c</sub>,for the following reaction. Ni(OH)<sub>2</sub>(s)+ 4 CN<sup>-</sup>(aq)   Ni(CN)<sub>4</sub><sup>2-</sup>(aq)+ 2 OH<sup>-</sup>(aq) Ni(CN)42-(aq)+ 2 OH-(aq)

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Given the equilibrium constants for the following reactions: 4Cu(s)+ O2(g) Given the equilibrium constants for the following reactions: 4Cu(s)+ O<sub>2</sub>(g)   2Cu<sub>2</sub>O(s),K<sub>1</sub> 4CuO(s)   2Cu<sub>2</sub>O(s)+ O<sub>2</sub>(g),K<sub>2</sub> What is K for the system 2Cu(s)+ O<sub>2</sub>(g)   2CuO(s) Equivalent to? 2Cu2O(s),K1 4CuO(s) Given the equilibrium constants for the following reactions: 4Cu(s)+ O<sub>2</sub>(g)   2Cu<sub>2</sub>O(s),K<sub>1</sub> 4CuO(s)   2Cu<sub>2</sub>O(s)+ O<sub>2</sub>(g),K<sub>2</sub> What is K for the system 2Cu(s)+ O<sub>2</sub>(g)   2CuO(s) Equivalent to? 2Cu2O(s)+ O2(g),K2 What is K for the system 2Cu(s)+ O2(g) Given the equilibrium constants for the following reactions: 4Cu(s)+ O<sub>2</sub>(g)   2Cu<sub>2</sub>O(s),K<sub>1</sub> 4CuO(s)   2Cu<sub>2</sub>O(s)+ O<sub>2</sub>(g),K<sub>2</sub> What is K for the system 2Cu(s)+ O<sub>2</sub>(g)   2CuO(s) Equivalent to? 2CuO(s) Equivalent to?

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The thermochemical equation for the formation of ammonia from elemental nitrogen and hydrogen is as follows. N2(g)+ 3 H2(g)  The thermochemical equation for the formation of ammonia from elemental nitrogen and hydrogen is as follows. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)   2  NH<sub>3</sub>(g) ~~~~~~~~   ~~~~~~~~   \Delta H = -92.2 kJ Given a system that is initially at equilibrium,which of the following actions cause the reaction to proceed to the left? 2 NH3(g)         ~~~~~~~~         ~~~~~~~~ Δ\Delta H = -92.2 kJ Given a system that is initially at equilibrium,which of the following actions cause the reaction to proceed to the left?

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Sulfuryl chloride decomposes to sulfur dioxide and chlorine. SO2Cl2(g) Sulfuryl chloride decomposes to sulfur dioxide and chlorine. SO<sub>2</sub>Cl<sub>2</sub>(g)   SO<sub>2</sub>(g)+ Cl<sub>2</sub>(g) K<sub>c</sub> is 0.045 at 648 K.If an initial concentration of 0.075 M SO<sub>2</sub>Cl<sub>2</sub> is allowed to equilibrate,what is the equilibrium concentration of Cl<sub>2</sub>? SO2(g)+ Cl2(g) Kc is 0.045 at 648 K.If an initial concentration of 0.075 M SO2Cl2 is allowed to equilibrate,what is the equilibrium concentration of Cl2?

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At a given temperature,K = 0.021 for the equilibrium: PCl5(g) At a given temperature,K = 0.021 for the equilibrium: PCl<sub>5</sub>(g)   PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g) What is K for: Cl<sub>2</sub>(g)+ PCl<sub>3</sub>(g)   PCl<sub>5</sub>(g)? PCl3(g)+ Cl2(g) What is K for: Cl2(g)+ PCl3(g) At a given temperature,K = 0.021 for the equilibrium: PCl<sub>5</sub>(g)   PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g) What is K for: Cl<sub>2</sub>(g)+ PCl<sub>3</sub>(g)   PCl<sub>5</sub>(g)? PCl5(g)?

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For the reaction given below,2.00 moles of A and 3.00 moles of B are placed in a 6.00-L container. A(g)+ 2B(g) For the reaction given below,2.00 moles of A and 3.00 moles of B are placed in a 6.00-L container. A(g)+ 2B(g)   C(g) At equilibrium,the concentration of A is 0.223 mol/L.What is the value of K<sub>c</sub>? C(g) At equilibrium,the concentration of A is 0.223 mol/L.What is the value of Kc?

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Which of the following statements about the reaction quotient,Q,is false?

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The equilibrium constant,Kc,for the decomposition of ammonium hydrogen sulfide is 1.8 ×\times 10-4 at 25 \circ C.NH4HS(s)  The equilibrium constant,K<sub>c</sub>,for the decomposition of ammonium hydrogen sulfide is 1.8  \times  10<sup>-4</sup> at 25 <sup> \circ </sup>C.NH<sub>4</sub>HS(s)   NH<sub>3</sub>(g)+ H<sub>2</sub>S(g) If excess NH<sub>4</sub>HS(s)is allowed to equilibrate at 25 <sup> \circ </sup>C,what is the equilibrium concentration of NH<sub>3</sub>? NH3(g)+ H2S(g) If excess NH4HS(s)is allowed to equilibrate at 25 \circ C,what is the equilibrium concentration of NH3?

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If the reaction quotient,Q,is greater than K in a gas phase reaction,then

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Consider the reaction H2 + I2 Consider the reaction H<sub>2</sub> + I<sub>2</sub>   2HI for which K<sub>c</sub> = 43.6 at a high temperature.If an equimolar mixture of reactants gives the concentration of the product to be 0.50 M at equilibrium,determine the equilibrium concentration of the hydrogen. 2HI for which Kc = 43.6 at a high temperature.If an equimolar mixture of reactants gives the concentration of the product to be 0.50 M at equilibrium,determine the equilibrium concentration of the hydrogen.

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Write a balanced chemical equation which corresponds to the following equilibrium constant expression. Write a balanced chemical equation which corresponds to the following equilibrium constant expression.

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Which of the following equilibria would not be affected by pressure changes at constant temperature?

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If the reaction quotient,Q,is equal to K in a gas phase reaction,then

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For the equilibrium PCl5(g) For the equilibrium PCl<sub>5</sub>(g)   PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g),K<sub>c</sub> = 4.0 at 228°C.If pure PCl<sub>5</sub> is placed in a 1.00-L container and allowed to come to equilibrium,and the equilibrium concentration of PCl<sub>5</sub>(g)is 0.26 M,what is the equilibrium concentration of PCl<sub>3</sub>? PCl3(g)+ Cl2(g),Kc = 4.0 at 228°C.If pure PCl5 is placed in a 1.00-L container and allowed to come to equilibrium,and the equilibrium concentration of PCl5(g)is 0.26 M,what is the equilibrium concentration of PCl3?

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For the reaction TlSCN(s)  For the reaction TlSCN(s)   Tl<sup>+</sup>(aq)+ SCN<sup>-</sup>(aq),K<sub>c</sub> =   At 25<sup> \circ </sup>C.Which of the following concerning a 125 mL solution containing   M Tl<sup>+</sup>,   M SCN<sup>-</sup> and a large excess of TlSCN(s)is/are correct? 1)The mixture is at equilibrium. 2)Additional TlSCN(s)must precipitate to attain equilibrium. 3)The reaction quotient (Q)is greater than one. Tl+(aq)+ SCN-(aq),Kc =  For the reaction TlSCN(s)   Tl<sup>+</sup>(aq)+ SCN<sup>-</sup>(aq),K<sub>c</sub> =   At 25<sup> \circ </sup>C.Which of the following concerning a 125 mL solution containing   M Tl<sup>+</sup>,   M SCN<sup>-</sup> and a large excess of TlSCN(s)is/are correct? 1)The mixture is at equilibrium. 2)Additional TlSCN(s)must precipitate to attain equilibrium. 3)The reaction quotient (Q)is greater than one. At 25 \circ C.Which of the following concerning a 125 mL solution containing  For the reaction TlSCN(s)   Tl<sup>+</sup>(aq)+ SCN<sup>-</sup>(aq),K<sub>c</sub> =   At 25<sup> \circ </sup>C.Which of the following concerning a 125 mL solution containing   M Tl<sup>+</sup>,   M SCN<sup>-</sup> and a large excess of TlSCN(s)is/are correct? 1)The mixture is at equilibrium. 2)Additional TlSCN(s)must precipitate to attain equilibrium. 3)The reaction quotient (Q)is greater than one. M Tl+,  For the reaction TlSCN(s)   Tl<sup>+</sup>(aq)+ SCN<sup>-</sup>(aq),K<sub>c</sub> =   At 25<sup> \circ </sup>C.Which of the following concerning a 125 mL solution containing   M Tl<sup>+</sup>,   M SCN<sup>-</sup> and a large excess of TlSCN(s)is/are correct? 1)The mixture is at equilibrium. 2)Additional TlSCN(s)must precipitate to attain equilibrium. 3)The reaction quotient (Q)is greater than one. M SCN- and a large excess of TlSCN(s)is/are correct? 1)The mixture is at equilibrium. 2)Additional TlSCN(s)must precipitate to attain equilibrium. 3)The reaction quotient (Q)is greater than one.

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For the equilibrium PCl5(g)  For the equilibrium PCl<sub>5</sub>(g)   PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g),K<sub>c</sub> = 2.0  \times  10<sup>1</sup> at 240°C.If pure PCl<sub>5</sub> is placed in a 1.00-L container and allowed to come to equilibrium,and the equilibrium concentration of PCl<sub>3</sub>(g)is 0.23 M,what is the equilibrium concentration of PCl<sub>5</sub>(g)? PCl3(g)+ Cl2(g),Kc = 2.0 ×\times 101 at 240°C.If pure PCl5 is placed in a 1.00-L container and allowed to come to equilibrium,and the equilibrium concentration of PCl3(g)is 0.23 M,what is the equilibrium concentration of PCl5(g)?

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Which expression correctly describes the equilibrium constant Kc for the following reaction? Which expression correctly describes the equilibrium constant K<sub>c</sub> for the following reaction?

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A flask contains the following chemical system at equilibrium. CuCO3(s) A flask contains the following chemical system at equilibrium. CuCO<sub>3</sub>(s)   Cu<sup>2+</sup>(aq)+ 2 CO<sub>3</sub><sup>2-</sup>(aq) Addition of which of the following substances will increase the solubility of CuCO<sub>3</sub>(s)in water? 1)aqueous hydrochloric acid 2)aqueous sodium carbonate 3)solid copper(II)carbonate Cu2+(aq)+ 2 CO32-(aq) Addition of which of the following substances will increase the solubility of CuCO3(s)in water? 1)aqueous hydrochloric acid 2)aqueous sodium carbonate 3)solid copper(II)carbonate

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At a given temperature,0.0664 mol N2O4(g)is placed in a 1.00 L flask.After reaching equilibrium,the concentration of NO2(g)is 6.1 ×\times 10-3 M.What is Kc for the reaction below?  At a given temperature,0.0664 mol N<sub>2</sub>O<sub>4</sub>(g)is placed in a 1.00 L flask.After reaching equilibrium,the concentration of NO<sub>2</sub>(g)is 6.1  \times  10<sup>-3</sup> M.What is K<sub>c</sub> for the reaction below?

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Consider the following equilibrium: CO2(g)+ H2(g) Consider the following equilibrium: CO<sub>2</sub>(g)+ H<sub>2</sub>(g)  CO(g)+ H<sub>2</sub>O(g); K<sub>c</sub> = 1.6 at 1260 K Suppose 0.038 mol CO<sub>2</sub> and 0.022 mol H<sub>2 </sub>are placed in a 1.50-L vessel at 1260 K.What is the equilibrium partial pressure of CO(g)? (R = 0.0821 L · atm/K·mol)CO(g)+ H2O(g); Kc = 1.6 at 1260 K Suppose 0.038 mol CO2 and 0.022 mol H2 are placed in a 1.50-L vessel at 1260 K.What is the equilibrium partial pressure of CO(g)? (R = 0.0821 L · atm/K·mol)

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