Exam 16: Principles of Reactivity: Chemical Equilibria
Exam 1: Basic Concepts of Chemistry53 Questions
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Exam 3: Atoms, molecules, and Ions105 Questions
Exam 4: Chemical Reactions85 Questions
Exam 5: Stoichiometry: Quantitative Information About Chemical Reactions76 Questions
Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions74 Questions
Exam 7: The Structure of Atoms73 Questions
Exam 8: The Structure of Atoms and Periodic Trends82 Questions
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Exam 13: The Chemistry of Solids77 Questions
Exam 14: Solutions and Their Behavior83 Questions
Exam 15: Chemical Kinetics: the Rates of Chemical Reactions84 Questions
Exam 16: Principles of Reactivity: Chemical Equilibria82 Questions
Exam 17: The Chemistry of Acids and Bases93 Questions
Exam 18: Principles of Reactivity: Other Aspects of Aqueous Equilibria88 Questions
Exam 19: Entropy and Free Energy76 Questions
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Given the following equilibria,
Ni2+(aq)+ 2 OH-(aq)
Ni(OH)2(s) K1 = 1.8 1015
Ni2+(aq)+ 4 CN-(aq)
Ni(CN)42-(aq) K2 = 2.0 1031
Determine the equilibrium constant,Kc,for the following reaction.
Ni(OH)2(s)+ 4 CN-(aq)
Ni(CN)42-(aq)+ 2 OH-(aq)



(Multiple Choice)
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Given the equilibrium constants for the following reactions:
4Cu(s)+ O2(g)
2Cu2O(s),K1
4CuO(s)
2Cu2O(s)+ O2(g),K2
What is K for the system
2Cu(s)+ O2(g)
2CuO(s)
Equivalent to?



(Multiple Choice)
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The thermochemical equation for the formation of ammonia from elemental nitrogen and hydrogen is as follows.
N2(g)+ 3 H2(g)
2 NH3(g) H = -92.2 kJ
Given a system that is initially at equilibrium,which of the following actions cause the reaction to proceed to the left?

(Multiple Choice)
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Sulfuryl chloride decomposes to sulfur dioxide and chlorine.
SO2Cl2(g)
SO2(g)+ Cl2(g)
Kc is 0.045 at 648 K.If an initial concentration of 0.075 M SO2Cl2 is allowed to equilibrate,what is the equilibrium concentration of Cl2?

(Multiple Choice)
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At a given temperature,K = 0.021 for the equilibrium:
PCl5(g)
PCl3(g)+ Cl2(g)
What is K for: Cl2(g)+ PCl3(g)
PCl5(g)?


(Multiple Choice)
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For the reaction given below,2.00 moles of A and 3.00 moles of B are placed in a 6.00-L container.
A(g)+ 2B(g)
C(g)
At equilibrium,the concentration of A is 0.223 mol/L.What is the value of Kc?

(Multiple Choice)
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Which of the following statements about the reaction quotient,Q,is false?
(Multiple Choice)
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The equilibrium constant,Kc,for the decomposition of ammonium hydrogen sulfide is 1.8 10-4 at 25 C.NH4HS(s)
NH3(g)+ H2S(g)
If excess NH4HS(s)is allowed to equilibrate at 25 C,what is the equilibrium concentration of NH3?

(Multiple Choice)
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If the reaction quotient,Q,is greater than K in a gas phase reaction,then
(Multiple Choice)
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Consider the reaction H2 + I2
2HI for which Kc = 43.6 at a high temperature.If an equimolar mixture of reactants gives the concentration of the product to be 0.50 M at equilibrium,determine the equilibrium concentration of the hydrogen.

(Multiple Choice)
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Write a balanced chemical equation which corresponds to the following equilibrium constant expression. 

(Multiple Choice)
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Which of the following equilibria would not be affected by pressure changes at constant temperature?
(Multiple Choice)
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If the reaction quotient,Q,is equal to K in a gas phase reaction,then
(Multiple Choice)
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For the equilibrium PCl5(g)
PCl3(g)+ Cl2(g),Kc = 4.0 at 228°C.If pure PCl5 is placed in a 1.00-L container and allowed to come to equilibrium,and the equilibrium concentration of PCl5(g)is 0.26 M,what is the equilibrium concentration of PCl3?

(Multiple Choice)
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For the reaction TlSCN(s)
Tl+(aq)+ SCN-(aq),Kc =
At 25 C.Which of the following concerning a 125 mL solution containing
M Tl+,
M SCN- and a large excess of TlSCN(s)is/are correct?
1)The mixture is at equilibrium.
2)Additional TlSCN(s)must precipitate to attain equilibrium.
3)The reaction quotient (Q)is greater than one.




(Multiple Choice)
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For the equilibrium PCl5(g)
PCl3(g)+ Cl2(g),Kc = 2.0 101 at 240°C.If pure PCl5 is placed in a 1.00-L container and allowed to come to equilibrium,and the equilibrium concentration of PCl3(g)is 0.23 M,what is the equilibrium concentration of PCl5(g)?

(Multiple Choice)
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Which expression correctly describes the equilibrium constant Kc for the following reaction?


(Multiple Choice)
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A flask contains the following chemical system at equilibrium.
CuCO3(s)
Cu2+(aq)+ 2 CO32-(aq)
Addition of which of the following substances will increase the solubility of CuCO3(s)in water?
1)aqueous hydrochloric acid
2)aqueous sodium carbonate
3)solid copper(II)carbonate

(Multiple Choice)
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At a given temperature,0.0664 mol N2O4(g)is placed in a 1.00 L flask.After reaching equilibrium,the concentration of NO2(g)is 6.1 10-3 M.What is Kc for the reaction below?

(Multiple Choice)
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Consider the following equilibrium:
CO2(g)+ H2(g)
CO(g)+ H2O(g); Kc = 1.6 at 1260 K
Suppose 0.038 mol CO2 and 0.022 mol H2 are placed in a 1.50-L vessel at 1260 K.What is the equilibrium partial pressure of CO(g)? (R = 0.0821 L · atm/K·mol)

(Multiple Choice)
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