Exam 16: Principles of Reactivity: Chemical Equilibria

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Exactly 1.0 mol N2O4 is placed in an empty 1.0-L container and allowed to reach equilibrium described by the equation N2O4(g) Exactly 1.0 mol N<sub>2</sub>O<sub>4</sub> is placed in an empty 1.0-L container and allowed to reach equilibrium described by the equation N<sub>2</sub>O<sub>4</sub>(g)   2NO<sub>2</sub>(g).If at equilibrium the N<sub>2</sub>O<sub>4</sub> is 28.0% dissociated,what is the value of the equilibrium constant,K<sub>c</sub>,for the reaction under these conditions? 2NO2(g).If at equilibrium the N2O4 is 28.0% dissociated,what is the value of the equilibrium constant,Kc,for the reaction under these conditions?

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Assume that the following chemical reaction is at equilibrium. 2 ICl(g)  Assume that the following chemical reaction is at equilibrium. 2 ICl(g)   I<sub>2</sub>(g)+ Cl<sub>2</sub>(g) ~~~~~~~~   ~~~~~~~~   \Delta H<sup> \circ </sup> = +26.9 kJ  At 25 <sup> \circ </sup>C,K<sub>p</sub> = 2.0  \times  10<sup>5</sup>.If the temperature is increase to 45 <sup> \circ </sup>C,which statement applies? I2(g)+ Cl2(g)         ~~~~~~~~         ~~~~~~~~ Δ\Delta H \circ = +26.9 kJ At 25 \circ C,Kp = 2.0 ×\times 105.If the temperature is increase to 45 \circ C,which statement applies?

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What is the reaction quotient,Q,for the equilibrium What is the reaction quotient,Q,for the equilibrium  SCN<sup>-</sup>(aq) When 0.4257 L of   M Ag<sup>+</sup> is combined with 0.2376 L of   M SCN<sup>-</sup> in the presence of an excess of AgSCN(s)?SCN-(aq) When 0.4257 L of What is the reaction quotient,Q,for the equilibrium  SCN<sup>-</sup>(aq) When 0.4257 L of   M Ag<sup>+</sup> is combined with 0.2376 L of   M SCN<sup>-</sup> in the presence of an excess of AgSCN(s)? M Ag+ is combined with 0.2376 L of What is the reaction quotient,Q,for the equilibrium  SCN<sup>-</sup>(aq) When 0.4257 L of   M Ag<sup>+</sup> is combined with 0.2376 L of   M SCN<sup>-</sup> in the presence of an excess of AgSCN(s)? M SCN- in the presence of an excess of AgSCN(s)?

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When gaseous carbon monoxide and hydrogen are combined in a sealed vessel and heated they will eventually form an equilibrium mixture of reactants and products according to the balanced chemical equilibrium below.CO(g)+ 3H2(g) When gaseous carbon monoxide and hydrogen are combined in a sealed vessel and heated they will eventually form an equilibrium mixture of reactants and products according to the balanced chemical equilibrium below.CO(g)+ 3H<sub>2</sub>(g)   CH<sub>4</sub>(g)+ H<sub>2</sub>O(g) In one such reaction 3 moles of one reactant were combined with 1 mole of the other reactant in a fixed volume vessel and heated to 1200 K.Analysis of the reaction mixture at various times gave the results below.Which component of the reaction mixture is represented by curve C?  CH4(g)+ H2O(g) In one such reaction 3 moles of one reactant were combined with 1 mole of the other reactant in a fixed volume vessel and heated to 1200 K.Analysis of the reaction mixture at various times gave the results below.Which component of the reaction mixture is represented by curve C? When gaseous carbon monoxide and hydrogen are combined in a sealed vessel and heated they will eventually form an equilibrium mixture of reactants and products according to the balanced chemical equilibrium below.CO(g)+ 3H<sub>2</sub>(g)   CH<sub>4</sub>(g)+ H<sub>2</sub>O(g) In one such reaction 3 moles of one reactant were combined with 1 mole of the other reactant in a fixed volume vessel and heated to 1200 K.Analysis of the reaction mixture at various times gave the results below.Which component of the reaction mixture is represented by curve C?

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In an experiment,0.42 mol H2 and 0.42 mol I2 are mixed in a 1.00-L container,and the reaction forms HI.If Kc = 49.for this reaction,what is the equilibrium concentration of HI? I2(g)+ H2(g) In an experiment,0.42 mol H<sub>2</sub> and 0.42 mol I<sub>2</sub> are mixed in a 1.00-L container,and the reaction forms HI.If K<sub>c</sub> = 49.for this reaction,what is the equilibrium concentration of HI? I<sub>2</sub>(g)+ H<sub>2</sub>(g)    2HI(g) 2HI(g)

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At 25 \circ C,0.138 mg AgBr dissolves in 10.0 L of water.What is the equilibrium constant for the reaction below?  At 25 <sup> \circ </sup>C,0.138 mg AgBr dissolves in 10.0 L of water.What is the equilibrium constant for the reaction below?

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The reaction quotient,Q,for a system is The reaction quotient,Q,for a system is   .If the equilibrium constant for the system at some temperature is   ,what will happen as the reaction mixture returns to equilibrium? .If the equilibrium constant for the system at some temperature is The reaction quotient,Q,for a system is   .If the equilibrium constant for the system at some temperature is   ,what will happen as the reaction mixture returns to equilibrium? ,what will happen as the reaction mixture returns to equilibrium?

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What is the Kc expression for the following equilibrium? What is the K<sub>c</sub> expression for the following equilibrium?

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For the reaction NO(g)+ ½ O2(g) For the reaction NO(g)+ ½ O<sub>2</sub>(g)   NO<sub>2</sub>(g)at 750°C,what is the relationship between K<sub>c</sub> and K<sub>p</sub>? NO2(g)at 750°C,what is the relationship between Kc and Kp?

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The symbol Q is called the ________.

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Which of the following is always true for a reaction where Kc is  Which of the following is always true for a reaction where K<sub>c</sub> is   at 25<sup> \circ </sup>C? at 25 \circ C?

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For which of the following reactions are the numerical values of Kp and Kc the same? 1. 2SO2(g) + O2(g) For which of the following reactions are the numerical values of Kp and Kc the same?       1. 2SO<sub>2</sub>(g) + O<sub>2</sub>(g)  2SO3(g)      2. N2(g) + O2(g)    2NO(g)  3. H<sub>2</sub>(g)+ I<sub>2</sub>(g)   2HI(g)2SO3(g) 2. N2(g) + O2(g) 11ea8937_ab81_0f67_a16d_5b4ecfd630df_TB4499_11 2NO(g) 3. H2(g)+ I2(g) 11ea8937_ab81_0f67_a16d_5b4ecfd630df_TB4499_11 2HI(g)

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For the equilibrium N2O4(g)  For the equilibrium N<sub>2</sub>O<sub>4</sub>(g)   2NO<sub>2</sub>(g),at 298 K,K<sub>p</sub> = 0.15.For this reaction system,it is found that the partial pressure of N<sub>2</sub>O<sub>4</sub> is 3.6  \times  10<sup>-2</sup> atm at equilibrium.What is the partial pressure of NO<sub>2</sub> at equilibrium? 2NO2(g),at 298 K,Kp = 0.15.For this reaction system,it is found that the partial pressure of N2O4 is 3.6 ×\times 10-2 atm at equilibrium.What is the partial pressure of NO2 at equilibrium?

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Write the expression for K for the reaction of hydrofluoric acid with water. Write the expression for K for the reaction of hydrofluoric acid with water.

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Assume that the following  endothermic \underline{\text{ endothermic }} chemical reaction is at equilibrium. C(s)+ H2O(g)  Assume that the following  \underline{\text{ endothermic  }} chemical reaction is at equilibrium. C(s)+ H<sub>2</sub>O(g)   H<sub>2</sub>(g)+ CO(g) Which of the following statements is/are CORRECT? 1)Increasing the concentration of H<sub>2</sub>(g)will cause the reaction to proceed in the backward direction,increasing the equilibrium concentration of H<sub>2</sub>O(g). 2)Decreasing the temperature will cause the reaction to proceed in the forward direction,increasing the equilibrium concentration of CO(g). 3)Increasing the amount of C(s)will cause the reaction to proceed in the forward direction,increasing the equilibrium concentration of CO(g). H2(g)+ CO(g) Which of the following statements is/are CORRECT? 1)Increasing the concentration of H2(g)will cause the reaction to proceed in the backward direction,increasing the equilibrium concentration of H2O(g). 2)Decreasing the temperature will cause the reaction to proceed in the forward direction,increasing the equilibrium concentration of CO(g). 3)Increasing the amount of C(s)will cause the reaction to proceed in the forward direction,increasing the equilibrium concentration of CO(g).

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A mixture of nitrogen and hydrogen was allowed to come to equilibrium at a given temperature. 3H2 + N2 A mixture of nitrogen and hydrogen was allowed to come to equilibrium at a given temperature. 3H<sub>2</sub> + N<sub>2</sub>   2NH<sub>3</sub> An analysis of the mixture at equilibrium revealed 2.1 mol N<sub>2</sub>,3.2 mol H<sub>2</sub>,and 1.8 mol NH<sub>3</sub>.How many moles of H<sub>2</sub> were present at the beginning of the reaction? 2NH3 An analysis of the mixture at equilibrium revealed 2.1 mol N2,3.2 mol H2,and 1.8 mol NH3.How many moles of H2 were present at the beginning of the reaction?

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Which of the following statements is/are CORRECT? 1)For a chemical system,if the reaction quotient (Q)is greater than K,reactant must be converted to products to reach equilibrium. 2)For a chemical system at equilibrium,the forward and reverse rates of reaction are equal. 3)For a chemical system at equilibrium,the concentrations of products divided by the concentrations of reactants equals one.

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Nitrosyl bromide decomposes according to the chemical equation below.2 NOBr(g) Nitrosyl bromide decomposes according to the chemical equation below.2 NOBr(g)   2 NO(g)+ Br<sub>2</sub>(g) When 0.260 atm of NOBr is sealed in a flask and allowed to reach equilibrium,22% of the NOBr decomposes.What is the equilibrium constant,K<sub>p</sub>,for the reaction? 2 NO(g)+ Br2(g) When 0.260 atm of NOBr is sealed in a flask and allowed to reach equilibrium,22% of the NOBr decomposes.What is the equilibrium constant,Kp,for the reaction?

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Which of the following statements is/are CORRECT? 1)Product concentrations appear in the numerator of an equilibrium constant expression. 2)A reaction favors the formation of products if K >> 1. 3)Stoichiometric coefficients are used as exponents in an equilibrium constant expression.

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Consider the reaction A(aq)  Consider the reaction  A(aq)   2 B(aq)where K<sub>c</sub> = 4.1 at 25 <sup> \circ </sup>C.If 0.50 M A(aq)and 1.5 M B(aq)are initially present in a 1.0 L flask at 25 <sup> \circ </sup>C,what change in concentrations (if any)will occur in time? 2 B(aq)where Kc = 4.1 at 25 \circ C.If 0.50 M A(aq)and 1.5 M B(aq)are initially present in a 1.0 L flask at 25 \circ C,what change in concentrations (if any)will occur in time?

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