Exam 16: Principles of Reactivity: Chemical Equilibria
Exam 1: Basic Concepts of Chemistry53 Questions
Exam 2: Mathlets Review: The Tools of Quantitative Chemistry78 Questions
Exam 3: Atoms, molecules, and Ions105 Questions
Exam 4: Chemical Reactions85 Questions
Exam 5: Stoichiometry: Quantitative Information About Chemical Reactions76 Questions
Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions74 Questions
Exam 7: The Structure of Atoms73 Questions
Exam 8: The Structure of Atoms and Periodic Trends82 Questions
Exam 9: Bonding and Molecular Structure97 Questions
Exam 10: Bonding and Molecular Structure: Orbital Hybridization and Molecular Orbitals72 Questions
Exam 11: Gases and Their Properties92 Questions
Exam 12: Intermolecular Forces and Liquids79 Questions
Exam 13: The Chemistry of Solids77 Questions
Exam 14: Solutions and Their Behavior83 Questions
Exam 15: Chemical Kinetics: the Rates of Chemical Reactions84 Questions
Exam 16: Principles of Reactivity: Chemical Equilibria82 Questions
Exam 17: The Chemistry of Acids and Bases93 Questions
Exam 18: Principles of Reactivity: Other Aspects of Aqueous Equilibria88 Questions
Exam 19: Entropy and Free Energy76 Questions
Exam 20: Principles of Reactivity: Electron Transfer Reactions86 Questions
Exam 21: Environmental Chemistry Earths Environment,energy,and Sustainability48 Questions
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Ozone is formed from oxygen.3 O2(g)
2 O3(g)
Calculate the value of Kp,given that Kc = 2.5 10-29 at 298 K.(R = 0.08206 L.atm/mol.K)

(Multiple Choice)
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The standard enthalpy of formation of ammonia is -46.1 kJ/mol.
1/2 N2(g)+ 3/2 H2(g)
NH3(g)
Commercially,the reaction is carried out at high temperatures.Using your knowledge of kinetics and equilibrium,explain an advantage and a disadvantage of synthesizing ammonia at high temperatures.

(Essay)
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If a stress is applied to an equilibrium system,the system will respond in such a way as to relieve that stress.This is a statement of ________ principle.
(Short Answer)
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At 25 C,the decomposition of dinitrogen tetraoxide
N2O4(g)
2 NO2(g)
Has an equilibrium constant (Kp)of 0.144.At equilibrium,the total pressure of the system is 0.0758 atm.What is the partial pressure of each gas?

(Multiple Choice)
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What is the balanced equation for the following equilibrium expression? 

(Multiple Choice)
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Given the following chemical equilibrium,
COCl2(g)
CO(g)+ Cl2(g)
Calculate the value of Kc,given that Kp = 6.5 1011 at 298 K.(R = 0.08206 L.atm/mol.K)

(Multiple Choice)
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Consider the following reaction:
Given that 1.00 mol of HF(g),0.389 mol of H2(g),and 0.750 mol of F2(g)are mixed in a 5.00-L flask,determine the reaction quotient,Q.

(Multiple Choice)
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A 3.00-liter flask initially contains 3.00 mol of gas A and 1.50 mol of gas B.Gas A decomposes according to the following reaction:
The equilibrium concentration of gas C is 0.146 mol/L.Determine the value of the equilibrium constant,Kc.

(Multiple Choice)
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A 2.50-mol sample of HI is placed in a 1.00-L vessel at 460°C,and the reaction system is allowed to come to equilibrium.The HI partially decomposes,forming 0.191 mol H2 and 0.191 mol I2 at equilibrium.What is the equilibrium constant Kc for the following reaction at 460°C?
½ H2(g)+ ½ I2(g)
HI(g)

(Multiple Choice)
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Excess Ag2SO4(s)is placed in water at 25 C.At equilibrium,the solution contains 0.029 M Ag+(aq).What is the equilibrium constant for the reaction below?

(Multiple Choice)
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Consider the following equilibrium:
Suppose 15.6 g each of CH4,C2H6,C5H12,and C6H14 are placed in a 45.0-L reaction vessel at 500 K.Which of the following statements is correct?

(Multiple Choice)
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At 800 K,the equilibrium constant,Kp,for the following reaction is
3.2 10-7.2 H2S(g)
2 H2(g)+ S2(g)
A reaction vessel at 800 K initially contains 3.00 atm of H2S.If the reaction is allowed to equilibrate,what is the equilibrium pressure of S2?

(Multiple Choice)
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Given the equilibrium constants for the equilibria,
2NH4+(aq)+ 2H2O(l)
2NH3(aq)+ 2H3O+(aq); Kc =
CH3COOH(aq)+ H2O(l)
CH3COO-(aq)+ H3O+(aq); Kc =
Determine Kc for the following equilibrium.
CH3COOH(aq)+ NH3(aq)
CH3COO-(aq)+ NH4+(aq)





(Multiple Choice)
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Consider the following equilibrium at 25°C:
2ICl(g)
I2(g)+ Cl2(g); H = 27 kJ; Kp = 6.2 10-6
Which of the following would be true if the temperature were increased to 100°C?
1)The value of Kp would increase.
2)The concentration of ICl(g)would increase.
3)The partial pressure of I2 would increase.

(Multiple Choice)
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If Kc = 0.152 for A2 + 2B
2AB,what is the value of Kc for the reaction
4AB
2A2 + 4B?


(Multiple Choice)
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What is the expression for Kc for the following equilibrium?


(Multiple Choice)
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A sample of solid NH4NO3 was placed in an evacuated container and then heated so that it decomposed explosively according to the following equation:
At equilibrium the total pressure in the container was found to be 2.81 atm at a temperature of 500.°C.Calculate Kp.

(Multiple Choice)
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