Exam 16: Principles of Reactivity: Chemical Equilibria

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Ozone is formed from oxygen.3 O2(g)  Ozone is formed from oxygen.3 O<sub>2</sub>(g)   2 O<sub>3</sub>(g) Calculate the value of K<sub>p</sub>,given that K<sub>c</sub> = 2.5  \times 10<sup>-29</sup> at 298 K.(R = 0.08206 L.atm/mol.K) 2 O3(g) Calculate the value of Kp,given that Kc = 2.5 ×\times 10-29 at 298 K.(R = 0.08206 L.atm/mol.K)

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The standard enthalpy of formation of ammonia is -46.1 kJ/mol. 1/2 N2(g)+ 3/2 H2(g) The standard enthalpy of formation of ammonia is -46.1 kJ/mol. 1/2 N<sub>2</sub>(g)+ 3/2 H<sub>2</sub>(g)    NH<sub>3</sub>(g)  Commercially,the reaction is carried out at high temperatures.Using your knowledge of kinetics and equilibrium,explain an advantage and a disadvantage of synthesizing ammonia at high temperatures. NH3(g) Commercially,the reaction is carried out at high temperatures.Using your knowledge of kinetics and equilibrium,explain an advantage and a disadvantage of synthesizing ammonia at high temperatures.

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If a stress is applied to an equilibrium system,the system will respond in such a way as to relieve that stress.This is a statement of ________ principle.

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At 25 \circ C,the decomposition of dinitrogen tetraoxide N2O4(g)  At 25 <sup> \circ </sup>C,the decomposition of dinitrogen tetraoxide N<sub>2</sub>O<sub>4</sub>(g)   2 NO<sub>2</sub>(g) Has an equilibrium constant (K<sub>p</sub>)of 0.144.At equilibrium,the total pressure of the system is 0.0758 atm.What is the partial pressure of each gas? 2 NO2(g) Has an equilibrium constant (Kp)of 0.144.At equilibrium,the total pressure of the system is 0.0758 atm.What is the partial pressure of each gas?

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For which one of the following reactions does Kp equal Kc?

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What is the balanced equation for the following equilibrium expression? What is the balanced equation for the following equilibrium expression?

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Given the following chemical equilibrium, COCl2(g)  Given the following chemical equilibrium, COCl<sub>2</sub>(g)   CO(g)+ Cl<sub>2</sub>(g) Calculate the value of K<sub>c</sub>,given that K<sub>p</sub> = 6.5  \times  10<sup>11</sup> at 298 K.(R = 0.08206 L.atm/mol.K) CO(g)+ Cl2(g) Calculate the value of Kc,given that Kp = 6.5 ×\times 1011 at 298 K.(R = 0.08206 L.atm/mol.K)

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Consider the following reaction: Consider the following reaction:   Given that 1.00 mol of HF(g),0.389 mol of H<sub>2</sub>(g),and 0.750 mol of F<sub>2</sub>(g)are mixed in a 5.00-L flask,determine the reaction quotient,Q. Given that 1.00 mol of HF(g),0.389 mol of H2(g),and 0.750 mol of F2(g)are mixed in a 5.00-L flask,determine the reaction quotient,Q.

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Write the expression for Kp for the reaction below. Write the expression for K<sub>p</sub> for the reaction below.

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A 3.00-liter flask initially contains 3.00 mol of gas A and 1.50 mol of gas B.Gas A decomposes according to the following reaction: A 3.00-liter flask initially contains 3.00 mol of gas A and 1.50 mol of gas B.Gas A decomposes according to the following reaction:   The equilibrium concentration of gas C is 0.146 mol/L.Determine the value of the equilibrium constant,K<sub>c</sub>. The equilibrium concentration of gas C is 0.146 mol/L.Determine the value of the equilibrium constant,Kc.

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A 2.50-mol sample of HI is placed in a 1.00-L vessel at 460°C,and the reaction system is allowed to come to equilibrium.The HI partially decomposes,forming 0.191 mol H2 and 0.191 mol I2 at equilibrium.What is the equilibrium constant Kc for the following reaction at 460°C? ½ H2(g)+ ½ I2(g) A 2.50-mol sample of HI is placed in a 1.00-L vessel at 460°C,and the reaction system is allowed to come to equilibrium.The HI partially decomposes,forming 0.191 mol H<sub>2</sub> and 0.191 mol I<sub>2</sub> at equilibrium.What is the equilibrium constant K<sub>c</sub> for the following reaction at 460°C? ½ H<sub>2</sub>(g)+ ½ I<sub>2</sub>(g)   HI(g) HI(g)

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Excess Ag2SO4(s)is placed in water at 25 \circ C.At equilibrium,the solution contains 0.029 M Ag+(aq).What is the equilibrium constant for the reaction below?  Excess Ag<sub>2</sub>SO<sub>4</sub>(s)is placed in water at 25 <sup> \circ </sup>C.At equilibrium,the solution contains 0.029 M Ag<sup>+</sup>(aq).What is the equilibrium constant for the reaction below?

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Consider the following equilibrium: Consider the following equilibrium:   Suppose 15.6 g each of CH<sub>4</sub>,C<sub>2</sub>H<sub>6</sub>,C<sub>5</sub>H<sub>12</sub>,and C<sub>6</sub>H<sub>14</sub> are placed in a 45.0-L reaction vessel at 500 K.Which of the following statements is correct? Suppose 15.6 g each of CH4,C2H6,C5H12,and C6H14 are placed in a 45.0-L reaction vessel at 500 K.Which of the following statements is correct?

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At 800 K,the equilibrium constant,Kp,for the following reaction is 3.2 ×\times 10-7.2 H2S(g)  At 800 K,the equilibrium constant,K<sub>p</sub>,for the following reaction is  3.2  \times  10<sup>-7</sup>.2 H<sub>2</sub>S(g)   2 H<sub>2</sub>(g)+ S<sub>2</sub>(g) A reaction vessel at 800 K initially contains 3.00 atm of H<sub>2</sub>S.If the reaction is allowed to equilibrate,what is the equilibrium pressure of S<sub>2</sub>? 2 H2(g)+ S2(g) A reaction vessel at 800 K initially contains 3.00 atm of H2S.If the reaction is allowed to equilibrate,what is the equilibrium pressure of S2?

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Given the equilibrium constants for the equilibria, 2NH4+(aq)+ 2H2O(l) Given the equilibrium constants for the equilibria, 2NH<sub>4</sub><sup>+</sup>(aq)+ 2H<sub>2</sub>O(l)   2NH<sub>3</sub>(aq)+ 2H<sub>3</sub>O<sup>+</sup>(aq); K<sub>c</sub> =   CH<sub>3</sub>COOH(aq)+ H<sub>2</sub>O(l)   CH<sub>3</sub>COO<sup>-</sup>(aq)+ H<sub>3</sub>O<sup>+</sup>(aq); K<sub>c</sub> =   Determine K<sub>c</sub> for the following equilibrium. CH<sub>3</sub>COOH(aq)+ NH<sub>3</sub>(aq)   CH<sub>3</sub>COO<sup>-</sup>(aq)+ NH<sub>4</sub><sup>+</sup>(aq) 2NH3(aq)+ 2H3O+(aq); Kc = Given the equilibrium constants for the equilibria, 2NH<sub>4</sub><sup>+</sup>(aq)+ 2H<sub>2</sub>O(l)   2NH<sub>3</sub>(aq)+ 2H<sub>3</sub>O<sup>+</sup>(aq); K<sub>c</sub> =   CH<sub>3</sub>COOH(aq)+ H<sub>2</sub>O(l)   CH<sub>3</sub>COO<sup>-</sup>(aq)+ H<sub>3</sub>O<sup>+</sup>(aq); K<sub>c</sub> =   Determine K<sub>c</sub> for the following equilibrium. CH<sub>3</sub>COOH(aq)+ NH<sub>3</sub>(aq)   CH<sub>3</sub>COO<sup>-</sup>(aq)+ NH<sub>4</sub><sup>+</sup>(aq) CH3COOH(aq)+ H2O(l) Given the equilibrium constants for the equilibria, 2NH<sub>4</sub><sup>+</sup>(aq)+ 2H<sub>2</sub>O(l)   2NH<sub>3</sub>(aq)+ 2H<sub>3</sub>O<sup>+</sup>(aq); K<sub>c</sub> =   CH<sub>3</sub>COOH(aq)+ H<sub>2</sub>O(l)   CH<sub>3</sub>COO<sup>-</sup>(aq)+ H<sub>3</sub>O<sup>+</sup>(aq); K<sub>c</sub> =   Determine K<sub>c</sub> for the following equilibrium. CH<sub>3</sub>COOH(aq)+ NH<sub>3</sub>(aq)   CH<sub>3</sub>COO<sup>-</sup>(aq)+ NH<sub>4</sub><sup>+</sup>(aq) CH3COO-(aq)+ H3O+(aq); Kc = Given the equilibrium constants for the equilibria, 2NH<sub>4</sub><sup>+</sup>(aq)+ 2H<sub>2</sub>O(l)   2NH<sub>3</sub>(aq)+ 2H<sub>3</sub>O<sup>+</sup>(aq); K<sub>c</sub> =   CH<sub>3</sub>COOH(aq)+ H<sub>2</sub>O(l)   CH<sub>3</sub>COO<sup>-</sup>(aq)+ H<sub>3</sub>O<sup>+</sup>(aq); K<sub>c</sub> =   Determine K<sub>c</sub> for the following equilibrium. CH<sub>3</sub>COOH(aq)+ NH<sub>3</sub>(aq)   CH<sub>3</sub>COO<sup>-</sup>(aq)+ NH<sub>4</sub><sup>+</sup>(aq) Determine Kc for the following equilibrium. CH3COOH(aq)+ NH3(aq) Given the equilibrium constants for the equilibria, 2NH<sub>4</sub><sup>+</sup>(aq)+ 2H<sub>2</sub>O(l)   2NH<sub>3</sub>(aq)+ 2H<sub>3</sub>O<sup>+</sup>(aq); K<sub>c</sub> =   CH<sub>3</sub>COOH(aq)+ H<sub>2</sub>O(l)   CH<sub>3</sub>COO<sup>-</sup>(aq)+ H<sub>3</sub>O<sup>+</sup>(aq); K<sub>c</sub> =   Determine K<sub>c</sub> for the following equilibrium. CH<sub>3</sub>COOH(aq)+ NH<sub>3</sub>(aq)   CH<sub>3</sub>COO<sup>-</sup>(aq)+ NH<sub>4</sub><sup>+</sup>(aq) CH3COO-(aq)+ NH4+(aq)

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Consider the following equilibrium at 25°C: 2ICl(g)  Consider the following equilibrium at 25°C: 2ICl(g)   I<sub>2</sub>(g)+ Cl<sub>2</sub>(g);  \Delta H = 27 kJ; K<sub>p</sub> = 6.2  \times  10<sup>-6</sup> Which of the following would be true if the temperature were increased to 100°C? 1)The value of K<sub>p</sub> would increase. 2)The concentration of ICl(g)would increase. 3)The partial pressure of I<sub>2</sub> would increase. I2(g)+ Cl2(g); Δ\Delta H = 27 kJ; Kp = 6.2 ×\times 10-6 Which of the following would be true if the temperature were increased to 100°C? 1)The value of Kp would increase. 2)The concentration of ICl(g)would increase. 3)The partial pressure of I2 would increase.

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Write the expression for K for the reaction below. Write the expression for K for the reaction below.

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If Kc = 0.152 for A2 + 2B If K<sub>c</sub> = 0.152 for A<sub>2</sub> + 2B   2AB,what is the value of K<sub>c</sub> for the reaction 4AB   2A<sub>2</sub> + 4B? 2AB,what is the value of Kc for the reaction 4AB If K<sub>c</sub> = 0.152 for A<sub>2</sub> + 2B   2AB,what is the value of K<sub>c</sub> for the reaction 4AB   2A<sub>2</sub> + 4B? 2A2 + 4B?

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What is the expression for Kc for the following equilibrium? What is the expression for K<sub>c</sub> for the following equilibrium?

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A sample of solid NH4NO3 was placed in an evacuated container and then heated so that it decomposed explosively according to the following equation: A sample of solid NH<sub>4</sub>NO<sub>3</sub> was placed in an evacuated container and then heated so that it decomposed explosively according to the following equation:   At equilibrium the total pressure in the container was found to be 2.81 atm at a temperature of 500.°C.Calculate K<sub>p</sub>. At equilibrium the total pressure in the container was found to be 2.81 atm at a temperature of 500.°C.Calculate Kp.

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