Exam 18: Principles of Reactivity: Other Aspects of Aqueous Equilibria
Exam 1: Basic Concepts of Chemistry53 Questions
Exam 2: Mathlets Review: The Tools of Quantitative Chemistry78 Questions
Exam 3: Atoms, molecules, and Ions105 Questions
Exam 4: Chemical Reactions85 Questions
Exam 5: Stoichiometry: Quantitative Information About Chemical Reactions76 Questions
Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions74 Questions
Exam 7: The Structure of Atoms73 Questions
Exam 8: The Structure of Atoms and Periodic Trends82 Questions
Exam 9: Bonding and Molecular Structure97 Questions
Exam 10: Bonding and Molecular Structure: Orbital Hybridization and Molecular Orbitals72 Questions
Exam 11: Gases and Their Properties92 Questions
Exam 12: Intermolecular Forces and Liquids79 Questions
Exam 13: The Chemistry of Solids77 Questions
Exam 14: Solutions and Their Behavior83 Questions
Exam 15: Chemical Kinetics: the Rates of Chemical Reactions84 Questions
Exam 16: Principles of Reactivity: Chemical Equilibria82 Questions
Exam 17: The Chemistry of Acids and Bases93 Questions
Exam 18: Principles of Reactivity: Other Aspects of Aqueous Equilibria88 Questions
Exam 19: Entropy and Free Energy76 Questions
Exam 20: Principles of Reactivity: Electron Transfer Reactions86 Questions
Exam 21: Environmental Chemistry Earths Environment,energy,and Sustainability48 Questions
Exam 22: The Chemistry of the Main Group Elements84 Questions
Exam 23: The Chemistry of the Transition Elements82 Questions
Exam 24: Carbon: Not Just Another Element93 Questions
Exam 25: Biochemistry54 Questions
Exam 26: Nuclear Chemistry79 Questions
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What mass of sodium hydroxide must be added to 40.0 mL of 0.607 M acetic acid in order to create a buffer with a pH of 4.66? Ka for acetic acid is 1.8 10-5.
(Multiple Choice)
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Which of the following conditions is/are met at the equivalence point of the titration of a monoprotic weak base with a strong acid?
1)The moles of acid added from the buret equals the initial moles of weak base.
2)The volume of acid added from the buret must equal the volume of base titrated.
3)The pH of the solution is less than 7.00.
(Multiple Choice)
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If the ratio of acid to base in a buffer is increased by a factor of 10,the buffer pH decreases by ________.
(Short Answer)
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A 50.00-mL solution of 0.0797 M ammonia (Kb = 1.8 10-5)is titrated with a 0.0315 M solution of hydrochloric acid as the titrant.What is the pH of the base solution after 23.88 mL of titrant have been added? (Kw = 1.00 10-14)
(Multiple Choice)
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What is the molar solubility of Fe(OH)3(s)in a solution that is buffered at pH 2.50 at 25 C? The Ksp of Fe(OH)3 is 6.3 10-38 at 25 C.
(Multiple Choice)
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In which of the following solutions would silver(I)phosphate,Ag3PO4,be least soluble?
(Multiple Choice)
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If 25 mL of 0.750 M HCl are added to 100.mL of 0.392 M NaOH,what is the final pH?
(Multiple Choice)
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A 50.00-mL solution of 0.0350 M quinoline (Kb = 8.0 10-10)is titrated with a 0.0137 M solution of hydrochloric acid as the titrant.What is the pH at the equivalence point? (Kw = 1.0 10-14)
(Multiple Choice)
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Potassium hydrogen phthalate (KHP)is used to standardize sodium hydroxide.If 35.39 mL of NaOH(aq)is required to titrate 0.8246 g KHP to the equivalence point,what is the concentration of the NaOH(aq)? (The molar mass of KHP = 204.2 g/mol)
HC8H4O4-(aq)+ OH-(aq)
C8H4O42-(aq)+ H2O(
)


(Multiple Choice)
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If 500 mL of 1.2 10-6 M AgNO3 is mixed with 500 mL of 1.2 10-6 M NaBr,what will occur? For AgBr,Ksp = 5 10-13.
(Multiple Choice)
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The concentration of magnesium carbonate in a saturated aqueous solution at 25°C is
M.What is the Ksp of this sparingly soluble salt?

(Multiple Choice)
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What is the pH of a buffer that results when 0.50 mole of H3PO4 is mixed with 0.75 mole of NaOH and diluted with water to 1.00 L? (The acid dissociation constants of phosphoric acid are Ka1 = 7.5 10-3,Ka2 = 6.2 10-8,and Ka3 = 3.6 10-13)
(Multiple Choice)
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You have 75.0 mL of 0.11 M HA.After adding 30.0 mL of 0.10 M NaOH,the pH is 5.50.What is the Ka value of HA?
(Multiple Choice)
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If 30 mL of 0.10 M NaOH is added to 40 mL of 0.20 M HC2H3O2,what is the pH of the resulting solution at 25°C? Ka for HC2H3O2 is 1.8 10-5 at 25°C.
(Multiple Choice)
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What is the pH of an aqueous solution composed of 0.64 M NH4+ and 0.20 M NH3? (Ka of NH4+ = 5.6 10-10)
(Multiple Choice)
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What is the pH of the buffer that results when 12.0 g of NaH2PO4 and 8.00 g of Na2HPO4 are diluted with water to a volume of 0.50 L? (Ka of H2PO4- = 6.2 10-8,the molar masses of NaH2PO4 and Na2HPO4 are 120.0 g/mol and 142.0 mol,respectively)
(Multiple Choice)
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A certain weak base B has a base-ionization constant Kb of 7.3 10-4 at 25°C.If strong acid is added to a solution of B,at what pH will [B] = [BH+]?
(Multiple Choice)
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Which of the following mathematical expressions is the Henderson-Hasselbalch equation?
(Multiple Choice)
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What is the maximum hydroxide-ion concentration that a 0.027 M MgCl2 solution could have without causing the precipitation of Mg(OH)2? For Mg(OH)2,Ksp = 1.8 10-11.
(Multiple Choice)
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Two important biological buffer systems control pH in the range between 6.9 and 7.4.These buffer systems are H2CO3/HCO3- and ________.
(Essay)
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