Exam 18: Principles of Reactivity: Other Aspects of Aqueous Equilibria

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What mass of sodium hydroxide must be added to 40.0 mL of 0.607 M acetic acid in order to create a buffer with a pH of 4.66? Ka for acetic acid is 1.8 ×\times 10-5.

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Which of the following conditions is/are met at the equivalence point of the titration of a monoprotic weak base with a strong acid? 1)The moles of acid added from the buret equals the initial moles of weak base. 2)The volume of acid added from the buret must equal the volume of base titrated. 3)The pH of the solution is less than 7.00.

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If the ratio of acid to base in a buffer is increased by a factor of 10,the buffer pH decreases by ________.

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A 50.00-mL solution of 0.0797 M ammonia (Kb = 1.8 ×\times 10-5)is titrated with a 0.0315 M solution of hydrochloric acid as the titrant.What is the pH of the base solution after 23.88 mL of titrant have been added? (Kw = 1.00 ×\times 10-14)

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What is the molar solubility of Fe(OH)3(s)in a solution that is buffered at pH 2.50 at 25 \circ C? The Ksp of Fe(OH)3 is 6.3 ×\times 10-38 at 25 \circ C.

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In which of the following solutions would silver(I)phosphate,Ag3PO4,be least soluble?

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If 25 mL of 0.750 M HCl are added to 100.mL of 0.392 M NaOH,what is the final pH?

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A 50.00-mL solution of 0.0350 M quinoline (Kb = 8.0 ×\times 10-10)is titrated with a 0.0137 M solution of hydrochloric acid as the titrant.What is the pH at the equivalence point? (Kw = 1.0 ×\times 10-14)

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Potassium hydrogen phthalate (KHP)is used to standardize sodium hydroxide.If 35.39 mL of NaOH(aq)is required to titrate 0.8246 g KHP to the equivalence point,what is the concentration of the NaOH(aq)? (The molar mass of KHP = 204.2 g/mol) HC8H4O4-(aq)+ OH-(aq) Potassium hydrogen phthalate (KHP)is used to standardize sodium hydroxide.If 35.39 mL of NaOH(aq)is required to titrate 0.8246 g KHP to the equivalence point,what is the concentration of the NaOH(aq)? (The molar mass of KHP = 204.2 g/mol) HC<sub>8</sub>H<sub>4</sub>O<sub>4</sub><sup>-</sup>(aq)+ OH<sup>-</sup>(aq)   C<sub>8</sub>H<sub>4</sub>O<sub>4</sub><sup>2-</sup>(aq)+ H<sub>2</sub>O(   ) C8H4O42-(aq)+ H2O( Potassium hydrogen phthalate (KHP)is used to standardize sodium hydroxide.If 35.39 mL of NaOH(aq)is required to titrate 0.8246 g KHP to the equivalence point,what is the concentration of the NaOH(aq)? (The molar mass of KHP = 204.2 g/mol) HC<sub>8</sub>H<sub>4</sub>O<sub>4</sub><sup>-</sup>(aq)+ OH<sup>-</sup>(aq)   C<sub>8</sub>H<sub>4</sub>O<sub>4</sub><sup>2-</sup>(aq)+ H<sub>2</sub>O(   ) )

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If 500 mL of 1.2 ×\times 10-6 M AgNO3 is mixed with 500 mL of 1.2 ×\times 10-6 M NaBr,what will occur? For AgBr,Ksp = 5 ×\times 10-13.

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The concentration of magnesium carbonate in a saturated aqueous solution at 25°C is The concentration of magnesium carbonate in a saturated aqueous solution at 25°C is   M.What is the K<sub>sp</sub> of this sparingly soluble salt? M.What is the Ksp of this sparingly soluble salt?

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What is the pH of a buffer that results when 0.50 mole of H3PO4 is mixed with 0.75 mole of NaOH and diluted with water to 1.00 L? (The acid dissociation constants of phosphoric acid are Ka1 = 7.5 ×\times 10-3,Ka2 = 6.2 ×\times 10-8,and Ka3 = 3.6 ×\times 10-13)

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You have 75.0 mL of 0.11 M HA.After adding 30.0 mL of 0.10 M NaOH,the pH is 5.50.What is the Ka value of HA?

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If 30 mL of 0.10 M NaOH is added to 40 mL of 0.20 M HC2H3O2,what is the pH of the resulting solution at 25°C? Ka for HC2H3O2 is 1.8 ×\times 10-5 at 25°C.

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What is the pH of an aqueous solution composed of 0.64 M NH4+ and 0.20 M NH3? (Ka of NH4+ = 5.6 ×\times 10-10)

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What is the pH of the buffer that results when 12.0 g of NaH2PO4 and 8.00 g of Na2HPO4 are diluted with water to a volume of 0.50 L? (Ka of H2PO4- = 6.2 ×\times 10-8,the molar masses of NaH2PO4 and Na2HPO4 are 120.0 g/mol and 142.0 mol,respectively)

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A certain weak base B has a base-ionization constant Kb of 7.3 ×\times 10-4 at 25°C.If strong acid is added to a solution of B,at what pH will [B] = [BH+]?

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Which of the following mathematical expressions is the Henderson-Hasselbalch equation?

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What is the maximum hydroxide-ion concentration that a 0.027 M MgCl2 solution could have without causing the precipitation of Mg(OH)2? For Mg(OH)2,Ksp = 1.8 ×\times 10-11.

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Two important biological buffer systems control pH in the range between 6.9 and 7.4.These buffer systems are H2CO3/HCO3- and ________.

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