Exam 18: Principles of Reactivity: Other Aspects of Aqueous Equilibria

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What is the effect of adding NaOH(aq)to an aqueous solution of ammonia? 1)The pH of the solution will increase. 2)The concentration of NH4+(aq)will decrease. 3)The concentration of NH3(aq)will increase.

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What is the solubility product expression for Fe(OH)3?

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What is the molar solubility of silver(I)bromide at 25°C? The solubility product constant for silver(I)bromide is 5.0 ×\times 10-13 at 25°C.

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Suppose 50.00 mL of 2.0 ×\times 10-6 M Fe(NO3)3 is added to 50.00 mL of 2.0 ×\times 10-4 M KIO3.Which of the following statements is true? For Fe(IO3)3,Ksp = 1.0 ×\times 10-14.

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What is the minimum mass of Cs2CO3 (molar mass = 325.821 g/mol)that must be added to 54.8 mL of a 5.0 ×\times 10-4 M AgNO3 solution in order for precipitation to occur? The Ksp of Ag2CO3 is 8.6 ×\times 10-12.Assume no volume change occurs upon addition of Cs2CO3.

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Given the following equilibrium constants, Cd(IO3)2 Ksp = Given the following equilibrium constants, Cd(IO<sub>3</sub>)<sub>2</sub> K<sub>sp</sub> =   Cd(NH<sub>3</sub>)<sub>4</sub><sup>2+ </sup>K<sub>f</sub><sub> </sub> =   Determine K for the dissolution of the sparingly soluble salt Cd(IO<sub>3</sub>)<sub>2</sub> in aqueous ammonia (shown below).Cd(IO<sub>3</sub>)<sub>2</sub>(s)+ 4NH<sub>3</sub>(aq)   Cd(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup>(aq)+ 2IO<sub>3</sub><sup>-</sup>(aq) Cd(NH3)42+ Kf = Given the following equilibrium constants, Cd(IO<sub>3</sub>)<sub>2</sub> K<sub>sp</sub> =   Cd(NH<sub>3</sub>)<sub>4</sub><sup>2+ </sup>K<sub>f</sub><sub> </sub> =   Determine K for the dissolution of the sparingly soluble salt Cd(IO<sub>3</sub>)<sub>2</sub> in aqueous ammonia (shown below).Cd(IO<sub>3</sub>)<sub>2</sub>(s)+ 4NH<sub>3</sub>(aq)   Cd(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup>(aq)+ 2IO<sub>3</sub><sup>-</sup>(aq) Determine K for the dissolution of the sparingly soluble salt Cd(IO3)2 in aqueous ammonia (shown below).Cd(IO3)2(s)+ 4NH3(aq) Given the following equilibrium constants, Cd(IO<sub>3</sub>)<sub>2</sub> K<sub>sp</sub> =   Cd(NH<sub>3</sub>)<sub>4</sub><sup>2+ </sup>K<sub>f</sub><sub> </sub> =   Determine K for the dissolution of the sparingly soluble salt Cd(IO<sub>3</sub>)<sub>2</sub> in aqueous ammonia (shown below).Cd(IO<sub>3</sub>)<sub>2</sub>(s)+ 4NH<sub>3</sub>(aq)   Cd(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup>(aq)+ 2IO<sub>3</sub><sup>-</sup>(aq) Cd(NH3)42+(aq)+ 2IO3-(aq)

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An aqueous solution contains 0.010 M Br- and 0.010 M I-.If Ag+ is added until AgBr(s)just begins to precipitate,what are the concentrations of Ag+ and I-? (Ksp of AgBr = 5.4 ×\times 10-13,Ksp of AgI = 8.5 ×\times 10-17)

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A 25.00-mL sample of propionic acid,HC3H5O2,of unknown concentration was titrated with 0.143 M KOH.The equivalence point was reached when 43.76 mL of base had been added.What was the original concentration of the propionic acid?

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The Ksp of BaSO4 is 1.1 ×\times 10-10 at 25 \circ C.What mass of BaSO4 (molar mass = 233.4 g/mol)will dissolve in 1.0 L of water at 25 \circ C?

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What is the molar solubility of Mn(OH)2(s)in a solution that is buffered at pH 8.00 at 25 \circ C? The Ksp of Mn(OH)2 is 1.9 ×\times 10-13 at 25 \circ C.

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What is the concentration of silver(I)ion in a saturated solution of silver(I)carbonate containing 0.0024 M Na2CO3? For Ag2CO3,Ksp = 8.6 ×\times 10-12.

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What is the pH of a buffer that results when 0.40 mol NaHCO2 is mixed with 100.0 mL of 2.00 M HCl(aq)and diluted with water to 250 mL? (Ka of HCO2H = 1.8 ×\times 10-4)

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What is the minimum concentration of Cu2+ required to begin precipitating Cu(OH)2(s)in a solution buffered at pH 10.63? The Ksp of Cu(OH)2 is 2.6 ×\times 10-19 and Kw = 1.01 ×\times 10-14.

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Which acid-base combination is depicted by this titration curve? The dot on the curve is located at the titrant volume where the titration solution pH equals 7. Which acid-base combination is depicted by this titration curve? The dot on the curve is located at the titrant volume where the titration solution pH equals 7.

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To make a buffer with a pH of 8.00,you should use a weak acid with a Ka close to _______.

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An impure sample of sodium carbonate,Na2CO3,is titrated with 0.113 M HCl according to the reaction below. 2 HCl(aq)+ Na2CO3(aq) An impure sample of sodium carbonate,Na<sub>2</sub>CO<sub>3</sub>,is titrated with 0.113 M HCl according to the reaction below. 2 HCl(aq)+ Na<sub>2</sub>CO<sub>3</sub>(aq)   CO<sub>2</sub>(g)+ H<sub>2</sub>O(   )+ 2 NaCl(aq) What is the percent of Na<sub>2</sub>CO<sub>3</sub> in a 0.613 g sample if the titration requires 26.14 mL of HCl? The molar mass of Na<sub>2</sub>CO<sub>3</sub> is 106.0 g/mol. CO2(g)+ H2O( An impure sample of sodium carbonate,Na<sub>2</sub>CO<sub>3</sub>,is titrated with 0.113 M HCl according to the reaction below. 2 HCl(aq)+ Na<sub>2</sub>CO<sub>3</sub>(aq)   CO<sub>2</sub>(g)+ H<sub>2</sub>O(   )+ 2 NaCl(aq) What is the percent of Na<sub>2</sub>CO<sub>3</sub> in a 0.613 g sample if the titration requires 26.14 mL of HCl? The molar mass of Na<sub>2</sub>CO<sub>3</sub> is 106.0 g/mol. )+ 2 NaCl(aq) What is the percent of Na2CO3 in a 0.613 g sample if the titration requires 26.14 mL of HCl? The molar mass of Na2CO3 is 106.0 g/mol.

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How many moles of solid NaF would have to be added to 1.0 L of 2.39 M HF solution to achieve a buffer of pH 3.35? Assume there is no volume change.(Ka for HF = 7.2 ×\times 10-4)

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A 50.00-mL solution of 0.0729 M chloroacetic acid (Ka = 1.4 ×\times 10-3)is titrated with a 0.0181 M solution of NaOH as the titrant.What is the pH of at the equivalence point? (Kw = 1.00 ×\times 10-14)

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What is the pH of a solution made by combining 175 mL of 0.33 M NaC2H3O2 with 126 mL of 0.48 M HC2H3O2? The Ka of acetic acid is 1.75 ×\times 10-5.

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An acid-base equilibrium system is created by dissolving 0.50 mol CH3CO2H in water to a volume of 1.0 L.What is the effect of adding 0.50 mol CH3CO2-(aq)to this solution? 1)The pH of the solution will equal 7.00 because equal concentrations of a weak acid and its conjugate base are present. 2)Some CH3CO2H(aq)will ionize,increasing the concentration of CH3CO2-(aq)and increasing the pH. 3)Some CH3CO2-(aq)will react with H3O+,increasing the concentration of CH3CO2H(aq)and reestablishing the solution equilibrium.

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