Exam 20: Principles of Reactivity: Electron Transfer Reactions

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Gold and platinum are commonly used as inert electrodes in laboratory experiments.In commercial applications,such as batteries,________ is more commonly used for inert electrodes because it is far less expensive.

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Given: 2H+(aq)+ 2e- \to H2(g); 0.00 V Rb+(aq)+ e- \to Rb(s); -2.98 V F2(g)+ 2e- \to 2F-(aq); 2.87 V Al3+(aq)+ 3e- \to Al(s); -1.66 V Pb2+(aq)+ 2e- \to Pb(s); -0.13 V Under standard-state conditions,which is the strongest reducing agent?

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Calculate the standard reduction potential for the following reaction at 25 \circ C, AuCl4-(aq)+ 3 e- \to Au(s)+ 4 Cl-(aq) Given the following thermodynamic information. Au3+(aq)+ 3 e- \to Au(s)         ~~~~~~~~        ~~~~~~~~      ~~~~ ~~ E \circ = +1.50 V Au3+(aq)+ 4 Cl-(aq) \to AuCl4-(aq)         ~~~~~~~~ Kf = 2.3 ×\times 1025

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When a secondary battery provides electrical energy,it is acting as a voltaic cell.When the battery is recharging,it is operating as a(n)________ cell.

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What mass of chromium could be deposited by electrolysis of an aqueous solution of Cr2(SO4)3 for 160 min using a constant current of 15.0 A? Assume 100% current efficiency.(F = 96485 C/mol)

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A Faraday,F,is defined as

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