Exam 8: Delocalized Electrons: Their Effect on Stability, pka, and the Products of a Reaction - Aromaticity and Electronic Effects: an Introduction to the Reactions of Benzene

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Draw the important resonance contributing forms for the structure shown below. Draw the important resonance contributing forms for the structure shown below.

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What is/are the product(s)from the following reaction? What is/are the product(s)from the following reaction?

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In the addition of HBr to conjugated dienes,is the product which results from 1,2-addition or that which results from 1,4-addition typically the product of kinetic control?

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Draw the distribution of π electrons in the molecular orbitals of cyclobutadiene. Draw the distribution of π electrons in the molecular orbitals of cyclobutadiene.

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Provide the major organic product of the following reaction. Provide the major organic product of the following reaction.

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Provide the major organic product. Provide the major organic product.

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Which of the following statements about benzene is correct?

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Rate the following molecules in decreasing order of stability. Rate the following molecules in decreasing order of stability.

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Mark the most electron-rich carbon atom in the compound below with an asterisk.

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How many benzylic hydrogens are present in the following molecule? How many benzylic hydrogens are present in the following molecule?

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Arrange the following unsaturated hydrocarbons in order of decreasing reactivity toward HBr addition. Arrange the following unsaturated hydrocarbons in order of decreasing reactivity toward HBr addition.

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The Diels-Alder reaction is a concerted reaction; this means that

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Cyclopentadiene can react with itself in a Diels-Alder reaction.Draw the endo and exo products.

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What compound results from the 1,4-addition of one equivalent of HBr to 1,3-butadiene?

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Protonation of pyridine,shown below,generates a conjugate acid that is Protonation of pyridine,shown below,generates a conjugate acid that is

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Give the major organic product for the reaction. Give the major organic product for the reaction.

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Rank the following dienes in order of increasing stability: trans-1,3-pentadiene,cis-1,3-pentadiene,1,4-pentadiene,and 1,2-pentadiene.

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What are the products from the following reaction? What are the products from the following reaction?

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In the molecular orbital representation of benzene,how many π molecular orbitals are present?

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Which of the following is a conjugated diene? Which of the following is a conjugated diene?

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