Exam 8: Delocalized Electrons: Their Effect on Stability, pka, and the Products of a Reaction - Aromaticity and Electronic Effects: an Introduction to the Reactions of Benzene

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Aromatic molecules contain ________ π electrons.

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Show the missing reagents A and the compound B. Show the missing reagents A and the compound B.

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What diene and dienophile should be used to synthesize the compound below? What diene and dienophile should be used to synthesize the compound below?

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Which of the following is the strongest acid? Which of the following is the strongest acid?

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Provide the structure of the major organic product in the following reaction. Provide the structure of the major organic product in the following reaction.

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Does the following structures represent different compounds or resonance contributors? Does the following structures represent different compounds or resonance contributors?

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Which of the following is the strongest acid? Which of the following is the strongest acid?

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Due to electron delocalization,one would predict that the carbon-oxygen bond in acetamide,CH3CONH2

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Consider the hydrogenation reaction of each compound listed and rank the compounds in order of increasing ΔH° of this reaction.The most negative ΔH° should be listed first. 2,5-dimethyl-1,3-cycloheptadiene, 1,4-dimethyl-1,3-cycloheptadiene,and 3,6-dimethyl-1,4-cycloheptadiene

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Provide the major organic product. Provide the major organic product.

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The delocalized π system of benzene is located

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Which of the following is aromatic? Which of the following is aromatic?

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When 1,3-butadiene reacts with CH2 When 1,3-butadiene reacts with CH<sub>2</sub> <sub> </sub>   CHCN,which of the terms below best describes the product mixture? CHCN,which of the terms below best describes the product mixture?

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What is the most acidic hydrogen on cyclopentadiene? What is the most acidic hydrogen on cyclopentadiene?

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Excluding the horizontal node which is coincident with the molecular plane,how many nodes are present in Ψ4 of the 1,3,5-hexatriene π system?

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Provide the structure of the major organic product in the following reaction. Provide the structure of the major organic product in the following reaction.

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Which of the following is the most stable cation? Which of the following is the most stable cation?

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Identify the most stable carbocation.

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Which of the following statements concerning resonance contributors and resonance hybrids is not correct?

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Classify the compound below as aromatic,antiaromatic,or nonaromatic.Assume planarity of the π network. Classify the compound below as aromatic,antiaromatic,or nonaromatic.Assume planarity of the π network.

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