Exam 11: Solutions: Properties and Behavior

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Describe how the molar mass of a compound can be determined from data obtained in two experiments: (1) measurements of the freezing point, and (2) measurements of the boiling point of a solution of the compound.

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Identify the following statement as true or false and choose the correct explanation. "For solutions with the same reverse osmotic pressure at the same temperature, the molarity of a sodium chloride solution will always be less than the molarity of a calcium chloride solution."

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Ion interaction energies are determined by Coulomb's law: Ion interaction energies are determined by Coulomb's law:   Which of the following compounds has an interaction energy <font face=symbol></font> <font face=symbol></font>3.83 <font face=symbol></font> 10<font face=symbol><sup></sup></font><sup>18</sup> J? Which of the following compounds has an interaction energy 3.83 1018 J?

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What information is provided by the van 't Hoff factor?

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Which of the following compounds has the largest melting point?

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Which of the following solutions, assuming equal volumes and a nonvolatile solute, would have the lowest boiling point?

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A solution contains 6.50 mol water, 0.300 mol sucrose, and 0.200 mol glucose. The solutes are nonvolatile. What is the vapor pressure of the solution at 35C given that the vapor pressure of water is 42.2 torr?

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Seawater can be characterized by the following average values. What is the molal concentration of ions in seawater? Explain how you arrived at your answer. density 1.022 g/mL total mass of ions 35.17 g/kg concentration of ions 1.15 M

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Which of the following must be true if the dissolution of an ionic solid in water is exothermic?

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Cholesterol (386.7 g/mol) is a nonelectrolyte and a critical component of the cell membranes of animal cells. What would be the change in boiling point of a solution containing 1.23 g of cholesterol and 105 g of chloroform (Kb 3.63C/m)?

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Ethylene glycol is used commonly as an antifreeze in automobile radiators. Automobile temperatures in the U.S. are commonly measured in degrees Fahrenheit. What is the freezing point in F of a 50:50 mixture of ethylene glycol and water by volume? (C2H6O2, 62.07 g/mol, 1.1132 g/mL, Kf 3.35F/m).

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What is the boiling point of a 3.25 m KCl solution (Kb 0.52C/m for water)?

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Which one of the ionic compounds below would you expect to have the smallest (least negative) lattice energy?

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Which of the following will require the greatest energy input to separate the ions?

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A solution is prepared by mixing 75 g of benzene (C6H6) with 25 g of toluene (C7H8). Use the following data to determine the vapor pressure of this solution at 20C. Substance Vapor Pressure at 20C (torr) Benzene 75 Toluene 22

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What is the molality of a solution produced by dissolving 14.40 g of LiCl (42.39 g/mol) in water to make 0.104 L of solution with a density of 1.102 g/mL?

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What is the molarity of a sucrose (C12H22O11) solution that produces an osmotic pressure of 2.65 atm at 25C?

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Predict the relationship between the lattice energies (U) of KBr and CaO.

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Which statement regarding osmotic pressure is not correct? Osmotic pressure ________

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Which listing of ionic compounds is in order of increasing melting point?

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